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Chemical Reaction Engineering (CRE) is the field that studies the rates and mechanisms of chemical reactions and the design of the reactors in which they take place. Lecture 2 1
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Lecture 2 – Tuesday 1/10/2011 Review of Lecture 1 Definition of Conversion, X Develop the Design Equations in Terms of X Size CSTRs and PFRs given –r A = f(X) Conversion for Reactors in Series Review the Fall of the Tower of CRE 2
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ReactorDifferentialAlgebraicIntegral CSTR Batch NANA t PFR FAFA V 3
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4 Liquid phase Given the following information, Find V
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(1) Mole Balance: (2) Rate Law: (3) Stoichiometry: 5
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(4) Combine: (5) Evaluate: 6
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Consider the generic reaction 7
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Integrating The necessary t to achieve conversion X. 9
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Steady State 10 Well Mixed
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CSTR volume necessary to achieve conversion X. 11
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Steady State 12
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PFR volume necessary to achieve conversion X. Integrating 13
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ReactorDifferentialAlgebraicIntegral CSTR PFR Batch X t PBR X W 14
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Reactor Sizing Given –r A as a function of conversion, -r A = f(X), one can size any type of reactor. We do this by constructing a Levenspiel plot. Here we plot either (F A0 /-r A ) or (1/-r A ) as a function of X. For (F A0 /-r A ) vs. X, the volume of a CSTR and the volume of a PFR can be represented as the shaded areas in the Levenspiel Plots shown as: 15
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F A 0 r A Area = Volume of CSTR X 1 17
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Numerical Evaluations of Integrals The integral to calculate the PFR volume can be evaluated using method as Simpson’s One-Third Rule: (See Appendix A.4) 20 Other numerical methods are: Trapezoidal Rule (uses two data points) Simpson’s Three-Eight’s Rule (uses four data points) Five-Point Quadrature Formula
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Given: r A as a function of conversion, one can also design any sequence of reactors in series by defining X: Only valid if there are no side streams. Molar Flow rate of species A at point i: 21
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Reactor 1: V1V1 23
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Reactor 2: V2V2 24
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Reactor 3: V3V3 25
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Space time τ is the time necessary to process 1 reactor volume of fluid at entrance conditions. 27
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KEEPING UP The tower of CRE, is it stable? 28
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Reaction Engineering Mole BalanceRate LawsStoichiometry These topics build upon one another. 29
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Mole Balance Rate Laws Stoichiometry Isothermal Design Heat Effects 30 CRE Algorithm
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Mole Balance 31 Be careful not to cut corners on any of the CRE building blocks while learning this material! Rate Laws
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Mole Balance Rate Laws Stoichiometry Isothermal Design Heat Effects 32 Otherwise, your Algorithm becomes unstable.
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End of Lecture 2 33
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