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pH In the Laboratory
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Ionization of Water
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Equllibrium Constant, K eq
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Ion Product of Water, K W
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pH
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Acidity
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Measuring pH Indicater Dyes; Methyl Red, Phenol Red, etc. pH Paper (Litmus Paper) pH Meter
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Voltmeter with electrode Measures electrical potential difference across electrode due to protons 1 pH unit = 60 mV pH also dependent on temperature
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pH Electrode Filled with reference solution (4 M KCl, sat. AgCl) Glass semi permable (protons cannot cross) Glass protected by plastic sleeve Some are sensitive to Tris buffer
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pH Standards Color coded 4, 7, and 10 Potassium Hydrogen Pthalate Standardize everyday Bracket pH range
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pH of Strong Acids HCl H + + Cl - Assume complete dissociation 1 M HCl, pH = -log [H + ] = -log 1 = ? 0.5 M HCl, pH = -log 0.5 = ? 6 M HCl, pH = -log 6 = ?
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pH of Strong Bases NaOH Na + + OH - Assume complete dissociation pK W = pH + pOH = 14 pH = 14 – (-log [OH - ]) 1 M NaOH, pH = 14 – (-log 1) = ? 0.01 M NaOH, pH = 14 – (-log 0.01) = ? 6 M NaOH, pH = 14 – (-log 6) = ?
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pH of a Weak Acid
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