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Atomic Physics Physics 100 Chapt 24 Dimitri Mendeleev
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Periodic table of elements Elements in vertical rows have similar chemical properties Inert gasses
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Schroedinger’s Equation for multi- electron Atoms - - - - - +
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Allowed energy levels are clustered in “shells” + - -- - - - - - - - - - - - - - - - n # of states 1 2 2 8 3a 8 3b 10 4a 8 4b 10 4c 14
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Pauli exclusion principle Only one electron per quantum state Once a quantum state is occupied additional electrons are excluded Wolfgang Pauli
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Light elements +1 - +2 - - Hydrogen Helium +3 - - Lithium - +10 - -- - - - - - - - Neon 1 electron in outermost shell outermost shell is full
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Periodic table of elements Elements in vertical rows have similar chemical properties 1 e - in outer shell Filled outer shell
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Chemical properties depend upon the outermost shell configuration +8 - -- - - - - - Oxygen +16 - - - - - - - - - - - - - - - - Sulfur Outermost shells Have 2 vacancies
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Periodic table of elements 2 vacancies in outer shell
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Atoms combine to form molecules by filling outer shells +8 - -- - - - - - Oxygen +1 - Hydrogen +1 - Hydrogen Water=H 2 O
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Atoms combine to form molecules by filling outer shells +6 - -- - - - Carbon +1 - Hydrogen +1 - Hydrogen Methane=CH 4 +1 - Hydrogen +1 - Hydrogen
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Elements with full outer shells don’t form molecules +2 - - Helium +10 - - - - - - - - - - Neon +18 - - - - - - - - - - - - - - - - - - Argon Noble gasses
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Periodic table revisited Elements in vertical rows have same outer shell configurations Outer shell is full 1 elec in outer shell 2 vacancies in outer shell 4 e - in outer shell
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