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Magnesium Research Joe Robson University of Manchester

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1 Magnesium Research Joe Robson University of Manchester joseph.robson@manchester.ac.uk

2 Key Application Areas Increased future role for Mg in transport (33% lighter than Al) Future vehicle concepts assume greatly increased application of Mg as part of multi-material structure Challenges Making complex shapes using Mg Reducing anisotropy/asymmetry of properties Joining Mg to Al and steel, joining cast Mg alloys Corrosion control (coatings/protection systems) SuperLight Car Magnesium

3 Mg Research – Current Hot Topics Based on a survey of recent conference proceedings, top research areas for Mg are – Improving low temperature formability (texture control, rare-earth additions etc.) – Alternative production routes (e.g. twin roll casting, advanced casting processes) – Bio-resorbable magnesium alloys for implants – Corrosion control (alloy design and coatings) – Improving strengthening response (improving precipitation hardening...)

4 International Picture China, Germany, Canada, Australia and US all have major Mg research activities China – National Engineering Research Centre for Magnesium Alloys, Chongqing ~80 academics Germany – Magnesium Innovation Centre (MagIC) ~50 scientists Canada – MagNET. 20 academics from 5 partner universities

5 UK Picture UK Mg research activity is comparatively small (handful of academics “part time” on Mg) but maintains wide coverage and internationally recognized position Mg research in UK receives ~ 5% of light metals funding Significant Mg activity within: – LATEST 2 programme – Towards Affordable, Closed-Loop Recyclable Future Low Carbon Vehicle Structures (TARF-LCV) – Centre for Innovative Manufacture in Liquid Metal Engineering (LiME) – Doctoral Training Centre in Advanced Metallic Systems (DTC) Most UK Mg research involves collaboration with industry - Magnesium Elektron

6 Reducing Temperature for Forming Unlike steel/Al magnesium cannot be formed at room temperature (hcp crystal structure) Reducing temperature required to form Mg is critical to economics for automotive sheet – Alloy design, e.g. dilute rare-earth additions – Fundamental understanding of formability in Mg – Alternative processes, e.g. superplastic forming Relevant UK research – Alloy design and fundamentals [Manchester] – Forming trials and alternative processes [Imperial/Warwick] Improved formability with dilute rare-earth additions

7 Alternative Process Routes Reducing cost of Mg requires using lower cost production route Twin roll casting (TRC) attractive option – Avoids need for large rolling reduction (difficult with Mg) – Potential to maintain randomized (cast) texture in sheet product – Potential to directly form TRC sheet (e.g. with superplastic forming) Research needed to improve consistency, microstructure and properties of TRC-Mg UK active through TRC optimization LiME [Brunel], microstructure and corrosion performance [Manchester] TRC sheet Light further warm rolling Warm forming Direct superplastic forming of TRC sheet

8 Bio-resorbable Mg Alloys Potential of Mg for bio-resorbable implants has attracted massive new research interest in past ~10 years Magnesium Elektron developed Synermag – first commercial Mg alloy designed for biological applications UK research – Mg alloy optimization and biological performance [Manchester] – Magnesium Elektron in-house activities Magnesium alloy stent

9 Corrosion Control and Coatings Corrosion control is critical for Mg use Mg corrosion is highly sensitive to impurities (e.g. Fe) – Key concern for recyclability Mg corrodes rapidly in contact with other metals – must be electrically isolated UK research – Fundamentals of corrosion in Mg alloys [Manchester] – Coating and protection systems for dissimilar joints [Manchester] – Effect of recycling/impurities on corrosion [Brunel, Manchester] Corrosion of ZE41 with PEO coating [Manchester] time

10 Improving Strengthening Response of Mg Highest strength Mg alloys only ~ ½ strength of strongest Al alloy Strongest Mg alloys are precipitation hardened (as with Al) Requires improving effectiveness of precipitates in Mg to provide strength – Fundamentals of strengthening in alloy systems that twin [Manchester] – New alloy systems – Micro-alloying to promote precipitation (as in Al) – Computer based alloy design (ICME) [Manchester]

11 Other Research Topics Recent/ongoing UK research in – Dissimilar metal joining of Mg to steel, Al structures [Manchester, Warwick] – Magnesium based carbon reinforced composites [Manchester] – Friction stir welding of magnesium [Manchester/Sheffield]


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