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- acid formation(?). = HCl Water / H 2 O = i.e.: H 3 O +..... Cl - (aq) HCl + H 2 O(l)

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Presentation on theme: "- acid formation(?). = HCl Water / H 2 O = i.e.: H 3 O +..... Cl - (aq) HCl + H 2 O(l)"— Presentation transcript:

1 - acid formation(?)

2 = HCl Water / H 2 O = i.e.: H 3 O +..... Cl - (aq) HCl + H 2 O(l)

3 H 3 O +..... Cl - (aq) HCl + H 2 O(l) Energy +

4 = HCl(g) =  H + Cl -  (g) Energy r(HCl) HCl H + Cl  H + Cl -  H + + Cl -

5 HCl (2+1)REMPI Spectrum 20850209002095021050 /cm -1 Energy r(HCl) HCl H + Cl  H + Cl -  H + + Cl -

6 HCl (2+1)REMPI Spectrum 20850209002095021050 LASER /cm -1 Energy r(HCl) HCl H + Cl  H + Cl -  V 1  + H + + Cl - E  2 x 21000= 42000 cm -1 v =11 0

7 HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H + + Cl - H 3 O +... Cl - (nxH 2 O) + n x H 2 O

8 HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H 3 O +... Cl - (nxH 2 O)  H + Cl -    + H 2 O ::::::::::  H + Cl -      H + Cl -     n  (Castlemann et al., 2002)

9 HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H 3 O +... Cl - (nxH 2 O) + H 2 O ::::::::::  H + Cl -    

10

11 Nozzle Pump Focus lens MCP Detector +HV HCl(g) H 2 O(l) Cooling vessel....... H 2 O(g) HCl/H 2 O(g) HCl    i  H + Cl -    i  h H 3 O +  Cl - ((i-1)xH 2 O)(?) HCl    i  nh  H + Cl -    i ; +

12 HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H 3 O +... Cl - (nxH 2 O) +3 H 2 O ::::::::::  H + Cl -     +


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