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Mass Exchangers Direct-contact mass-transfer unit Utilizes a Mass Separating Agent (MSA) to selectively remove pollutants from rich streams (waste streams). The MSA should be partially or completely immiscible in the rich phase.
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Mass Exchangers Absorption, liquid solvent removes certain components from a gas. Examples: 1. Desulfurization of flue gas using alkaline solutions. 2. VOC’s recovery using light oils 3. NH 3 removal from air using water.
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Mass Exchangers Adsorption, a solid adsorbs specific components from a gaseous or liquid solution. Examples: The use of granular activated carbon 1. For the removal of benzene/toluene/xylene mixture from underground water. 2. Separation of ketones from aqueous wastes of an oil refinery. 3. Recovery of organic solvents from the exhaust of polymer manufacturing facilities.
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Mass Exchangers Extraction, employs a liquid solvent to remove components from other liquid. Examples: Wash oils are used 1. To remove phenol and polychlorinated biphenyls from aqueous wastes of synthetic-fuel plants. 2. To remove Chlorinated hydrocarbons for organic wastewater.
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Mass Exchangers Ion Exchange, cation and/or anion resins are used to replace undesirable anionic species in liquid solution with non-hazardous ions. Examples: Removal of dissolved metals, cyanides, phenols, and halides from wastewater. Cation-exchange resins may contain mobile, positive ions such as, Na + or H + which are attached to immobile acid groups, such as sulfonic or carboxylic. Anion-exchange, OH - or Cl - attached to amine.
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Mass Exchangers Leaching, selective solution of specific components of a solid mixture when brought in contact with a liquid solvent. Examples: Removal of metals from solids or sludge.
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Mass Exchangers Stripping, desorption of relatively volatile components from liquid or solid streams using a gaseous MSA. Examples: 1. Recovery of VOC’s from wastewater using air. 2. Removal of NH 3 from wastewater using steam. 3. Regeneration of spent activated carbon using steam or N 2.
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Mass-Exchange Network Synthesis Given a number N R of waste (rich) streams (sources) and a number N S of MSAs (lean streams), it is desired to synthesize undesirable species from the rich streams to the MSAs.
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