1. CH3Br, 121209 1)Comparison of 1D-CH3-REMPI spectra and ab initio potential curves (from C. Escure et al., JCP, 130, 244306 (2009)) 2)Comparison of 1D-CH3-REMPI spectra and absorption spectra (from R.Locht et al., CP, 317, 87, (05)) 3)Comparison of 1D-CH3-REMPI spectra and absorption spectra (from From G.C. Causley,..,JCP, 62(3), 848, (75)) Agust, www,....Dec09/PPT-121209ak.ppt Agust, heima,....Dec09/CH3Br-Overall +mass-1112109km-121209ak.pxp

2. Agust, heima,....Dec09/CH3Br-Overall +mass-1112109km-121209ak.pxp :

5. 5s 5p a1

6. 5s Agust, heima,....Dec09/CH3Br-Overall +mass-1112109km-121209ak.pxp :

7. 5s Potentials shifted(1) with respect to the observed spectra:

8. 5s Potentials shifted (2) with respect to the observed spectra:

9. From R.Locht et al., CP, 317, 87, (05): see fig. 1 (b) and Table 3: Agust, heima,....Dec09/CH3Br-Overall +mass-1112109km-121209ak.pxp : 66503 66020 67274 68675 68879 69944 70943 No assignm.! (0-0) 5p e. 0-0, 5p a1 3v 5 (5p a1 ) Combination of bands Both 5p a1 & 5p e Our data:

10. Agust, heima,....Dec09/CH3Br-Overall +mass-1112109km-121209ak.pxp :

11. 66503 66020 67274 68675 68879( 145.18 nm ) 69944 ( 142.97 nm ) 70943( 140.95 nm ) Our data: From G.C. Causley,..,JCP, 62(3), 848, (75): ?

12. agust, heima,...Sept09/CH3Br-Overall-021009km-201009ak.pxp 68877.6 6727366502 66020 68661 nm See also: http://www3.hi.is/~agust/rannsoknir/rempi/ch3br/Sept09/PPT-201009ak.ppt: http://www3.hi.is/~agust/rannsoknir/rempi/ch3br/Sept09/PPT-201009ak.ppt