1. Marine Ozone and Radiation Experiment Giandomenico Pace 1, David Mateos 3, Claudia di Biagio 1,4, Giampietro Casasanta 2, Nicoletta di Genova 2, Irene Mavilia 1,5, Lorenzo De Silvestri 1, Wolfgang Junkermann 6, Alcide di Sarra 1, Sandro Finardi 7, Marco Cacciani 2, Giuseppe Cremona 1 1 Italian National Agency for New Technologies, Energy and Sustainable Economic Development 2 University of Rome La Sapienza 3 University of Valladolid 4 University of Siena 5 University of Rome 3 6 Karlsruhe Institute of Technology 7 ARIANET s.r.l.

3. Aircraft data TimeGPS_LATGPS_LONALTITUDE Meteorological Data PRESSURETEMPERATUREDEWPOINTWIND Radiation data J1D_DN_UPPhotolysis frequency(s -1) (J1D_DN, Before 1606B flight data uncertain.) JNO2_DN_UP Photolysis frequency(s -1 ) RAD_DN_DNShortwave (W/m2) ( RAD_UP, Not working properly during the campaign) TOT_EXCOTotal extinction, (km -1 ) SKR_DN_UP Sky Radiation at 400 nm, 550 nm, 660 nm, 996nnm (bandwidth 10 nm, W/m2 ) Aerosol data CNC3010Total particles number > 10 nm and < 300 nm in diameter, numbers in #/cm3 GR_03 Total particles number > 300 nm in diameter, numbers in #/cm3 GRIMMSize distribution (particles number for size class in diameter, numbers in #/cm3) Gas data O3_AVG ppm Surface data SSTSea surface temperature (°C)

4. Umidità relativa nei primi 10 km di quota.Coefficiente di backscattering volumetrico First flight 12/06/2010 15:52-16:34 Second flight 13/06/2010 13:12-15:25 Third flight 15/06/2010 7:21-7:46 Fourth flight 16/06/2010 7:25-8:34 Fifth flight 16/06/2010 14:41-16:08 Sixth flight 17/06/2010 6:58-8:21 Seventh flight 17/06/2010 14:36-16:03 Eighth flight 19/06/2010 6:21-7:45 IV Periodo, 11- 20 giugno Temperatura nei primi 2 km di quota.

5. First flight 12/06/2010 15:52-16:34 Second flight 13/06/2010 13:12-15:25 Third flight 15/06/2010 7:21-7:46 Fourth flight 16/06/2010 7:25-8:34 Fifth flight 16/06/2010 14:41-16:08 Sixth flight 17/06/2010 6:58-8:21 Seventh flight 17/06/2010 14:36-16:03 Eighth flight 19/06/2010 6:21-7:45 IV Periodo, 11- 20 giugno Dati radiometrici.Dati anemometro sonico.

6. Ninth Flight 21-06-2010 6:32-7:09 Tenth Flight 25-06-2010 14:25-15:47 Eleventh Flight 26-06-2010 6:27-8:02 Twelfth Flight, 26-06-2010 14:46-16:15 V Periodo, 21 Giugno - 1 Luglio Temperatura nei primi 2 km di quota. Umidità relativa nei primi 10 km di quota.Coefficiente di backscattering volumetrico

7. Dati radiometrici.Dati anemometro sonico. Ninth Flight 21-06-2010 6:32-7:09 Tenth Flight 25-06-2010 14:25-15:47 Eleventh Flight 26-06-2010 6:27-8:02 Twelfth Flight, 26-06-2010 14:46-16:15 V Periodo, 21 Giugno - 1 Luglio Alto ozono del 21 giungo Lamina o abbassamento Tropopausa?

8. Flight day and time (UT)Thermal PBL behaviourAereosol load at 1020 nm. Max particles number with 10nm<D<3.0 μm (number/cm3) Max particles number with D>0.3 μm (number/cm3) Max ozone concentration (ppm) First flight 12/06/2010 15:52-16:34 T inversion (~5 K), max T at 600m AOD 1020 ~0.7 (Desert dust) 90006550 Second flight 13/06/2010 13:12-15:25 T inversion (~3 K), max T at 450m AOD 1020 ~0.2 (Desert dust) 15000>10095 Third flight 15/06/2010 7:21-7:46 T ~constant between 200 and 600 m AOD 1020 ~0.3 (Desert dust) 4000>10075 Fourth flight 16/06/2010 7:25-8:34 T ~constant between 200 and 500 AOD 1020 ~0.6 (Desert dust) 8000>10050 Fifth flight 16/06/2010 14:41-16:08 T inversion (~0.7 K), max T at 300m AOD 1020 ~0.4 (Desert dust) 60008065 Sixth flight 17/06/2010 6:58-8:21 T ~constant (decreasing) between 200 and 500 m AOD 1020 ~0.1120006067 Seventh flight 17/06/2010 14:36-16:03 AOD 1020 ~0.15 80003580 Eighth flight 19/06/2010 6:21-7:45 T decreasing (~7.5 K /km, first km) AOD 1020 ~0.3 (Desert dust) 70003065 Ninth Flight 21-06-2010 6:32-7:09 T decreasing (~9.5 K /km, first km) AOD 1020 ~0.08 20001550 Tenth Flight 25-06-2010 14:25-15:47 T decreasing (~8.5 K /km) above 600 m, super adiabatic below 100 m AOD 1020 ~0.09 110002070 Eleventh Flight 26-06-2010 6:27-8:02 T decreasing (8.5 K /km, first km) AOD 1020 ~0.150003060 Twelfth Flight, 26-06-2010 14:46-16:15 T decreasing (9.5 K/km above 800 m), T decreasing (6K /km above 800 m) AOD 1020 ~0.15 #4075

9. Flight altitude restriction!! Summarizing the campaign was characterized by two main meteorological situations. The first part of the campaign, from the beginning (12/06) to the eighth flight (17/06), was characterized by stable conditions, a well developed sea breeze regime and the presence of also considerable amount of desert dust. After the 17/06 there was a change in the general circulation inducing northerly wind regime that, from the 21/06 to the 25/06 stopped the flights, because the occurrence of rain or too strong wind conditions. The last two days of flights the 25th and 26th of June were both characterized by a continuous air flow from north. Particularly interesting for the objectives of the campaign was the afternoon flight of 16th when a synoptically southerly advection reinforce the sea breeze feature allowing to study air masses more influenced by the sea environment.

10. 16/06/2011Pomeriggio Desertico Rinforzo sinottico da sud ci si aspetta aria marina Pennacchio?

11. Complessità data da - orografia locale (vento) - evoluzione temporale (profili temperatura sul mare salita 1 rosso, salita 2 blu chiaro, discesa 4 blu scuro ). Inoltre ci sono le diverse sorgenti locali…

14. Esempio complessità indotta da orografia, per interpretazione modellistica meteorologia cè bisogno di alta risoluzione……