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Chapter 4: Aromatic Compounds

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1 Chapter 4: Aromatic Compounds
Bitter almonds are the source of the aromatic compound benzaldehyde

2 Sources of Benzene

3 Some Facts About Benzene
Reacts mainly by substitution

4 Friedrich August Kekule’

5 The Orbital Model for Benzene
Symbols for Benzene

6 Nomenclature of Aromatic Compounds
Monosubstituted benzenes with common names

7 Monosubstituted benzenes that do not have common names

8 When two substituents are present, we use prefixes ortho-, meta-, and para-, usually abbreviated as o-, m-, and p-, respectively.

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10 For more than two substituents, their positions are designated by numbering the ring.

11 Aromatic hydrocarbons, as a class called Arenes (Ar) the aryl groups are therefore aromatic substituents.

12 The symbol Ph is sometimes used as an abbreviation for phenyl group

13 Name the following structures

14 Electrophilic Aromatic Substitution

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18 The Mechanisms of Electrophilic Substitutions

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23 Nitration

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25 sulfonation

26 Alkylation and Acylation (Friedel-Crafts reaction)

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28 Ring-Activating and ring-Deactivating Substituents

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30 Ortho, Para-Directing and Meta-Directing Groups

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32 Ortho, Para-Directing Groups

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40 Importance of Directing Effects in Synthesis

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42 Polycyclic Aromatic Hydrocarbons

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44 Fused polycyclic hydrocarbons

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