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Published byDelphia Allison Modified over 9 years ago
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METALLIC BOND bond found in metals; holds metal atoms together very strongly
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Metallic Bond Formed between atoms of metallic elements Electron cloud around atoms Good conductors at all states, lustrous, very high melting points Examples; Na, Fe, Al, Au, Co
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Ionic Bond, A Sea of Electrons
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Metals Form Alloys Metals do not combine with metals. They form Alloys which is a solution of a metal in a metal. Examples are steel, brass, bronze and pewter.
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C. Johannesson NH 4 + 1 N × 5e - = 5e - 4 H × 1e - = 4e - 9e - H H N H H - 1e - 8e - - 8e - 0e - C. Polyatomic Ions
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C. Johannesson D. Resonance Structures Molecules that can’t be correctly represented by a single Lewis diagram. Actual structure is an average of all the possibilities. Show possible structures separated by a double-headed arrow.
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C. Johannesson D. Resonance Structures O O S O O O S O O O S O n SO 3
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Exceptions to the Octet Rule Molecules containing atoms of Group 3A elements, particularly boron and aluminum Aluminum chloride : : : FB F F ClAl Cl Cl 6 electrons in the valence shells of boron and aluminum Boron trifluoride :: :: :: : : : : : : : : :
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Exceptions to the Octet Rule Atoms of third-period elements have 3d orbitals and may expand their valence shells to contain more than 8 electrons – phosphorus may have up to 10
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Exceptions to the Octet Rule – sulfur, another third-period element, forms compounds in which its valence shell contains 8, 10, or 12 electrons
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C. Johannesson A. VSEPR Theory Valence Shell Electron Pair Repulsion Theory Electron pairs orient themselves in order to minimize repulsive forces.
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C. Johannesson A. VSEPR Theory Types of e - Pairs – Bonding pairs - form bonds – Lone pairs - nonbonding e - Lone pairs repel more strongly than bonding pairs!!!
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C. Johannesson A. VSEPR Theory Lone pairs reduce the bond angle between atoms. Bond Angle
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C. Johannesson Draw the Lewis Diagram. Tally up e - pairs on central atom. – double/triple bonds = ONE pair Shape is determined by the # of bonding pairs and lone pairs. Know the 8 common shapes & their bond angles! B. Determining Molecular Shape
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C. Johannesson C. Common Molecular Shapes 2 total 2 bond 0 lone LINEAR 180° BeH 2
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C. Johannesson 3 total 3 bond 0 lone TRIGONAL PLANAR 120° BF 3 C. Common Molecular Shapes
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C. Johannesson C. Common Molecular Shapes 3 total 2 bond 1 lone BENT <120° SO 2
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C. Johannesson 4 total 4 bond 0 lone TETRAHEDRAL 109.5° CH 4 C. Common Molecular Shapes
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C. Johannesson 4 total 3 bond 1 lone TRIGONAL PYRAMIDAL 107° NH 3 C. Common Molecular Shapes
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C. Johannesson 4 total 2 bond 2 lone BENT 104.5° H2OH2O C. Common Molecular Shapes
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C. Johannesson 5 total 5 bond 0 lone TRIGONAL BIPYRAMIDAL 120°/90° PCl 5 C. Common Molecular Shapes
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C. Johannesson 6 total 6 bond 0 lone OCTAHEDRAL 90° SF 6 C. Common Molecular Shapes
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C. Johannesson PF 3 4 total 3 bond 1 lone TRIGONAL PYRAMIDAL 107° D. Examples
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C. Johannesson CO 2 2 total 2 bond 0 lone LINEAR 180° D. Examples
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