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Chemistry
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Periodic Table Group – Vertical columns on PT Period – Horizontal rows on PT
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Main-Group Elements Groups 1, 2, and 13-18
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Main-Group Elements The chemical properties of the main- group elements depends on their number of valence electrons Valence electrons are the outermost electrons involved in chemical bonding
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Valence Electrons & Chemical Properties Each group of the main-group elements has the same number of valence electrons Each element wants to be as stable as possible All main-group elements want a full shell of electrons, which is 8 valence electrons
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Valence Electrons & Chemical Properties Each group forms ions based on the easiest way to obtain this full shell Also known as the octet rule
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Family Groups Noble Gases (Group 18) Examples: Ne, Xe Description: stable, unreactive group of gases Number of Valence Electrons: 8 Forms NO ions
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Family Groups Halogens (Group 17) Examples: F, Cl Description: Highly reactive group of gases Number of Valence Electrons: 7 Forms 1- ions
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Family Groups Alkali Metals (Group 1) Examples: Na, K (not H) Description: Highly reactive group of metals Number of Valence Electrons: 1 Forms 1+ ions
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Brainiac Movie
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Family Groups Alkaline-Earth Metals (Group 2) Examples: Be, Mg Description: Slightly less reactive group than alkali metals Number of Valence Electrons: 2 Forms 2+ ions
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Family Groups Transition Metals (Group 3 – 12) Examples: Fe, Au, Ag Description: Fairly stable group of metals Forms multiple ions
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Family Groups Lanthanides & Actinides Location: Bottom 2 periods of PT Description: Heavy metals, synthetics, radioactive
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States of Matter Metals and Nonmetals (Staircase)
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SECTION NEEDS TO BE REDONE WITH THE GROUP/PERIOD TRENDS OUTLINED FIRST!!!!!!!!!!!!!!!!!!!!!
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Periodic Table Trends Atomic Size Definition: The volume occupied by the electrons around a nucleus Period Trend Caused by: Increasing Effective Nuclear Charge
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Atomic Size Effective nuclear charge is the amount of charge felt by outer electrons in an atom Group trend Caused by: Increasing electron energy levels
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Ionization Energy Definition: The amount of energy required to remove one electron Period trend Caused by: Inc. Effective Nuclear Charge
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Ionization Energy Group trend Caused by: Electron shielding Electron shielding occurs when inner electrons shield outer electrons from the pull of the nucleus
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Electron Affinity Definition: The attraction of an atom for an electron Period Trend Caused by: Inc. Eff. Nuclear Charge
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Electron Affinity Group trend Caused by: Inc. electron shielding
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Electronegativity Definition: How much an atom in a chemical bond attracts electrons Period trend Caused by: Inc. Eff. Nuclear Charge
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Electronegativity Group trend Caused by: Electron shielding/Inc. electron energy levels
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Electron shielding Electron energy levels Effective Nuclear Charge
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Filling Electron Orbitals Orbitals are the area in space where electrons are found Each individual orbital holds 2 electrons There are four main shapes which hold a different number of electrons
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Shapes of Orbitals The four shapes are s, p, d, and f
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Shapes of the Orbitals Each shape holds a different number of orbitals s has 1 orbital, p has 3 orbitals, and d has 5 orbitals www.ptable.com
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Energy Levels Each period is a new energy level Like an elevator, electrons cannot exist between energy levels!
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General Rules Aufbau Principle – Electrons fill lowest energy level first Analogy: Lazy Tenant Rule
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General Rules Pauli Exclusion Principle – Electrons must have opposite spin (up/down) when in the same orbital Analogy: Yin and Yang Rule
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General Rules Hund’s Rule – Electrons in equal energy orbits fill orbitals with parallel spin Analogy: Empty Bus Seat Rule
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Orbital Notation Specific order for filling electrons – based on periodic table Examples Beryllium Oxygen
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Orbital Notation Examples O 2- Titanium
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Electron Configuration Examples Silicon Selenium Manganese
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Shorthand Electron Config Shorter version of writing electron configurations Noble Gas Core – inner core of electrons not involved in chemical bonding
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Shorthand Electron Config
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