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Chapter 3 Matter
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3.1 Matter 3.2 Physical and Chemical Properties and Changes 3.3 Elements and Compounds 3.4 Mixtures and Pure Substances 3.5 Separation of Mixtures
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Anything occupying space and having mass.
Matter Anything occupying space and having mass. Matter exists in three states. Solid Liquid Gas
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The Three States of Water
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Has a fixed volume and shape. Examples: Ice cube, diamond, iron bar
Solid Rigid Has a fixed volume and shape. Examples: Ice cube, diamond, iron bar
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Has a definite volume but no specific shape.
Liquid Has a definite volume but no specific shape. Assumes shape of container. Examples: Gasoline, water, alcohol, blood
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Liquid Water Takes the Shape of Its Container
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Has no fixed volume or shape.
Gas Has no fixed volume or shape. Takes the shape and volume of its container. Examples: Air, helium, natural gas, oxygen
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Physical Properties The characteristics of matter that can be changed without changing its composition or doesn’t involve changing its composition. It’s an adjective. Characteristics that are directly observable. Examples: Odor, color, volume, state (s, l, or g), density, melting point, and boiling point
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A substance’s ability to form new substances.
Chemical Properties A substance’s ability to form new substances. The characteristics that determine how the composition of matter changes as a result of contact with other matter or the influence of energy. It’s an adjective. Characteristics that describe the behavior of matter. Examples: Flammability, steel will rust, and Food will digest
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Ethyl alcohol will boil at 78°C Hardness of a diamond
Concept Check Classify each of the following as a physical or chemical property. Ethyl alcohol will boil at 78°C Hardness of a diamond Sugar will ferment to form ethyl alcohol physical chemical Ethyl alcohol boiling at 78°C Physical property: boiling point is associated with a phase change. It describes an inherent characteristic of alcohol. Hardness of a diamond. Physical property: describes an inherent characteristic of diamond – hardness. Sugar fermenting to form ethyl alcohol. Chemical property: describes behavior of sugar – forming a new substance (ethyl alcohol) through a chemical reaction.
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Boiling or freezing water
Physical Change Change in the form of a substance, not in its chemical composition. It’s a verb. Example: Boiling or freezing water
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Chemical Change A given substance becomes a new substance or substances with different properties and different composition. It’s a verb. Example: Bunsen burner (methane reacts with oxygen to form carbon dioxide and water)
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Electrolysis of Water Burning of Wood
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Water decomposes to hydrogen and oxygen gases.
Electrolysis of Water Water decomposes to hydrogen and oxygen gases.
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Pulverizing (crushing) rock salt Burning of wood
Concept Check How many of the following are examples of a chemical change? Pulverizing (crushing) rock salt Burning of wood Dissolving of sugar in water Melting a popsicle on a warm summer day 1 (burning of wood) Copyright © Cengage Learning. All rights reserved
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Matter Pure Substances Mixtures Classification of Matter
1 Separate by Chemical Processes -burning -fermentation -rusting Separate by Physical Processes -filtering -distillation -centrifuging Classification of Matter Matter Pure Substances Mixtures Elements (atoms) Compounds (molecules) Homogeneous (solutions) Heterogeneous (most things) Air Sodas Ocean Water Alcoholic drinks Granite Sand Wood Orange Juice Hydrogen Oxygen Copper Zinc Water Alcohol Sugar Salt
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Sugar fermenting to form ethyl alcohol Iron metal melting
Concept Check Classify each of the following as a physical or chemical change. Sugar fermenting to form ethyl alcohol Iron metal melting Iron combining with oxygen to form rust chemical physical Sugar fermenting to form ethyl alcohol. Chemical change: describes how sugar forms a new substance (ethyl alcohol) via a chemical reaction. Iron metal melting. Physical change: describes a state change, but the material is still iron. Iron combining with oxygen to form rust. Chemical change: describes how iron and oxygen react to make a new substance, rust. Copyright © Cengage Learning. All rights reserved
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Iron (Fe), aluminum (Al), oxygen (O2), and hydrogen (H2)
Element A substance that cannot be broken down into other substances by chemical methods. Examples: Iron (Fe), aluminum (Al), oxygen (O2), and hydrogen (H2) All of the matter in the world around us contains elements. Copyright © Cengage Learning. All rights reserved
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Always have the same composition and are formed by chemical processes.
Pure Substances Always have the same composition and are formed by chemical processes. Either elements or compounds. Examples: Pure water (H2O), carbon dioxide (CO2), hydrogen (H2), gold (Au) Copyright © Cengage Learning. All rights reserved
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Water (H2O), carbon dioxide (CO2), table sugar (C12H22O11)
Compound A substance composed of a given combination of elements that can be broken down into those elements by chemical methods. Examples: Water (H2O), carbon dioxide (CO2), table sugar (C12H22O11) A compound always contains atoms of different elements. A compound always has the same composition (same combination of atoms). Copyright © Cengage Learning. All rights reserved
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How many of the following are compounds? H2O, N2, NaOH, MnO2, H2
Concept Check How many of the following are compounds? H2O, N2, NaOH, MnO2, H2 Three – H2O, NaOH, MnO2 Five – All of the substances are compounds. Compounds always contain atoms of different elements. Copyright © Cengage Learning. All rights reserved
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Have variable composition. Examples Wood, wine, coffee, granite
Mixtures Have variable composition. Examples Wood, wine, coffee, granite Can be separated into pure substances: elements and/or compounds using physical processes.
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Having visibly indistinguishable parts. A solution.
Homogeneous Mixture Same throughout. Having visibly indistinguishable parts. A solution. Does not vary in composition from one region to another. Apple Juice Cranberry Juice Orange Juice
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Homogeneous Mixture – Examples
Air around you Brass Table salt stirred into water
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Heterogeneous Mixture
Having visibly distinguishable parts. Contains regions that have different properties from those of other regions.
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Heterogeneous Mixture – Examples
Oil and vinegar dressing Sand stirred into water Copyright © Cengage Learning. All rights reserved
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Pure water Gasoline Jar of jelly beans Soil Copper metal Concept Check
Which of the following is a homogeneous mixture? Pure water Gasoline Jar of jelly beans Soil Copper metal gasoline Copyright © Cengage Learning. All rights reserved
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Different Physical Property
Mixtures can be separated based on different physical properties of the components. Evaporation Volatility Chromatography Adherence to a surface Filtration State of matter (solid/liquid/gas) Distillation Boiling point Technique Different Physical Property Copyright © Cengage Learning. All rights reserved
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Distillation of a Solution Consisting of Salt Dissolved in Water
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No chemical change occurs when salt water is distilled.
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The Organization of Matter
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Filtration Reverse Osmosis Separates a liquid from a solid.
Separates a liquid from a solution. See Chapter 15.
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Supercritical Carbon Dioxide Extraction
Maxwell House decaffeinates its coffee using pure water and natural effervescence. (1978) See Chapter 15. A method of making reduced oil content in food chip products, such as potato chips and corn chips, includes circulating liquid carbon dioxide, over the food chip products to extract oil. Reduction of oil content to less than 50% of its initial value, including reductions to 25%, may be achieved while retaining flavor and texture comparable to conventional deep fried chips having an oil content of 30% to 40%. The oil which is recovered from the liquid carbon dioxide used for extraction has an appearance and quality which are substantially the same as virgin frying oil and may be reused to deep fry chips. SCF unit
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