1. WHMIS

2. WHMIS stands for: W WORKPLACE H HAZARDOUS M MATERIALS I INFORMATION S SYSTEM

3. Purpose of WHMIS To keep all Canadian workers safe in the workplace…

4. Responsibilities Under WHMIS Duties of the Supplier – –Classify Product – –Apply Supplier Label – –Provide Material Safety Data Sheet (MSDS)

5. Responsibilities Under WHMIS Duties of the Employer – –Conduct Workplace Inventory – –Ensure Proper Labeling is Used – –Maintain and Make Available MSDS’s – –Train Workers

6. Responsibilities Under WHMIS Duties of a Worker – –Participate in Training – –Apply Knowledge and Training – –KEEP YOURSELF SAFE!!

7. “Right to Know” Workers have Access to Information through their Employer Don’t be a “yes” employee…

8. Supplier Label Product Identifier Hazard Symbols Risk Phrases and Precautions First Aid, Supplier Information Precautions Safe Handling Precautions Reference to MSDS

9. What has a WHMIS label? Only materials that are deemed hazardous and are found in the workplace require WHMIS labelsOnly materials that are deemed hazardous and are found in the workplace require WHMIS labels Your nail polish remover, bathroom cleaner, etc. at home are covered separatelyYour nail polish remover, bathroom cleaner, etc. at home are covered separately

10. WHMIS Hazard Classifications

11. Compressed Gas – –Any Hazardous Material that is contained under pressure including compressed gas, dissolved gas, or liquefied gas

12. Compressed Gas Cylinders store and transport with safety cap, because… comply with storage restrictions, because… DO NOT store fuel gas with oxygen, because… secure in an upright position, because… use in a well ventilated area, because… use the proper type of regulator and know its history, because…

13. Fun with compressed gas cylinders http://www.youtube.com/watch?v=ejEJG NLTo84http://www.youtube.com/watch?v=ejEJG NLTo84http://www.youtube.com/watch?v=ejEJG NLTo84http://www.youtube.com/watch?v=ejEJG NLTo84

14. Flammable and Combustible Material – –Any material which can catch fire or combust when placed near another material – –Includes solids, liquids and gases

15. Flammable Materials Store liquids in Flammable Storage Cabinet Pour larger quantities in fume hood NEVER store with oxidizers Keep away from heat, ignition sources, and direct sunlight

16. Oxidizing Material – –Any Hazardous Material which causes or contributes to the combustion of another material by giving it oxygen – –Eg. Pool & spa test strips, ozone, bleach…

17. Oxidizers Easily oxidize metal powders, organic materials Store away from other materials, such as organic solvents Wear personal protective equipment (PPE)

18. Poisonous & Infectious Materials (Class 1) – –“poisonous” – –Causes immediate and serious effects

19. Poisonous & Infectious Materials (Class 2) – Toxic Materials – –“toxic” (looks like a capital T) – –Material causing other chronic or long term effects (cancer, birth defects, etc.)

20. Poisonous & Infectious Materials (Class 3)- Biohazards – –Materials which may cause disease in humans and animals, such as viruses, bacteria, and fungi; may also include cultures and diagnostic specimens such as blood, urine, and body tissue.

21. Corrosive Material – –Material which may corrode aluminum and steel or human flesh – –Can be liquid or gases

22. Corrosives at Home http://www.youtube.com/watch?v=TfDV LsBXYcMhttp://www.youtube.com/watch?v=TfDV LsBXYcMhttp://www.youtube.com/watch?v=TfDV LsBXYcMhttp://www.youtube.com/watch?v=TfDV LsBXYcM From “Fight Club”From “Fight Club”

23. Dangerously Reactive Material – –Materials which become self-reactive under conditions of shock, or increased temperature or pressure – –Materials which react vigorously with water to produce a very toxic gas

24. General Dry Chemicals Relatively innocuous or unreactiveRelatively innocuous or unreactive No special storage requirementsNo special storage requirements Relatively innocuous or unreactiveRelatively innocuous or unreactive No special storage requirementsNo special storage requirements

25. Quiz time!

26. WHMIS “Name that Symbol” Poisonous Biohazard

27. WHMIS “Name that Symbol” Flammable Corrosive

28. WHMIS “Name that Symbol” Dangerously Reactive Toxic

29. WHMIS “Name that Symbol” Oxidizers Compressed Gas

30. WHMIS Labels

31. Workplace Label Product Identifier Safe Handling Precautions Reference to MSDS

32. Typical Workplace Labels

33. MSDS Contents Hazardous Ingredients Preparation Information Fire & Explosion Hazard Toxicological Properties First Aid Measures Product Information Physical Data Reactivity Data Preventative Measures

34. Product Information Product Identifier Manufacturer’s/Supplier’s Name and Address Emergency Telephone Number Product Use

35. Physical Data Odour Threshold Vapour Pressure Coefficient of Water/Oil Distribution Boiling Point ( o C) and Freezing Point ( o C) Evaporation Rate (Butyl Acetate=1) Physical State Odour & Appearance Specific Gravity (Water=1) Vapour Density (Air=1) pH Percent Volatile (by volume)

36. Fire & Explosion Hazard Conditions of Flammability Means of Extinction Sensitivity to Mechanical Impact Sensitivity to Static Discharge Flashpoint ( o C) and Method Upper and Lower Flammable Limits (%) Autoignition Temperature ( o C) Hazardous Combustion Products

37. It’s all about a safe workplace!

38. Spot the Hazards

40. Work time! Fill in the blanks using the MSDS sheet that you have been givenFill in the blanks using the MSDS sheet that you have been given