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Chapter 16 Section 1 Molecular Compounds -generally have low melting and boiling points -most are gases or liquids at room temp -do not conduct an electric current when dissolved in water -made up or two or more non-metals
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Covalent Bonding -electrons are shared between atoms -each element still is trying to achieve octet *except hydrogen* -hydrogen only needs 2 valence e- single covalent bond- two atoms share a pair of electrons -bonds (pair of e-) are represented as dashes (─)
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Ex- H· + H· H:H H-H H 2 simple formula- shows # and type of atoms ex- H 2 structural formula- shows arrangement of atoms in a molecule ex- H-H
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-combos of atoms of the nonmetallic elements in Groups 4-7 are likely to form molecules *also hydrogen bonding pairs/shared pairs- pair of e- shared between two atoms lone pairs/unshared pairs- electrons not involved in bonding ex- Cℓ 2
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double covalent bond- bond that involves two shared pairs of e- (═) triple covalent bond- bond that involves three shared pairs of e- (≡)
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resonance structures- two or more valid Lewis structures example: **Write resonance structures for sulfur dioxide
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-Lewis structures make it seem as though e- are shared equally between the elements of covalent bonds -this is not the case Ex- HF -H has a slight positive charge and F has a slight negative charge
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these bonds are said to be polar- having a slightly + and slightly – pole polar covalent bond- intermediate in nature between a pure covalent and an ionic bond -the degree of polarity in bonds depends on electronegativity difference (∆EN) between the elements -table 14.2 page 405
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Effect of ∆EN on Bond Type: ∆ENBond Type Example 0-0.4 Nonpolar Covalent Cℓ 2 0.4-2.0Polar Covalent HCℓ ≥ 2.0Ionic NaCℓ Page 462 Sample Problem 16-4
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