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ATOMIC STRUCTURE
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ESSENTIAL QUESTION….. How can you identify an element and/or isotope based on its subatomic particles?
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What is an atom composed of?
COMPOSED OF THREE SUBATOMIC PARTICLES: PROTON (POSITIVELY CHARGED) NEUTRON (NO CHARGE) ELECTRON (NEGATIVELY CHARGED) BOTH IN THE NUCLEUS ALL FOUND OUTSIDE THE NUCLEUS (ELECTRON CLOUD)
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ABOUT THE PARTICLES….. PROTONS (p+) NEUTRONS (n0) ELECTRONS (e-)
Proton is nearly 2000 times more massive than the electron, but equal in charge and opposite in sign to the electron Number of protons in the nucleus is electrically balanced by an equal number of electrons NEUTRONS (n0) Mass almost exactly equal to that of the proton ELECTRONS (e-) Mass of electron much less than the mass of a proton and neutron Equal number of protons and electrons = NEUTRAL ATOM
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Properties of Subatomic Particles
Symbol Location Charge Relative mass Actual mass (g) Electron e- Around nucleus 1– 1 1840 9.11×10-28 Proton p+ Nucleus 1+ 1.673×10-24 Neutron n0 nucleus 1.675×10-24
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Na 11 ATOMIC NUMBER 22.990 Sodium
REPRESENTS THE NUMBER OF PROTONS IN AN ATOM ELEMENTS ARRANGED BY INCREASING ATOMIC NUMBER UNIQUE TO A GIVEN ELEMENT SINCE ALL ATOMS ARE NEUTRAL, ATOMIC NUMBER ALSO TELLS US THE NUMBER OF ELECTRONS IN AN ATOM USUALLY FOUND AT THE TOP OF THE ELEMENT’S SYMBOL 11 Na 22.990 Sodium
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Learning Check 1 State the number of protons for atoms of each of the following: A. Nitrogen (N) 1) 5 protons 2) 7 protons 3) 14 protons B. Sulfur (S) 1) 32 protons 2) 16 protons 3) 6 protons C. Barium (Ba) 1) 137 protons 2) 81 protons 3) 56 protons LecturePLUS Timberlake
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MASS NUMBER THE TOTAL NUMBER OF PROTONS AND NEUTRONS IN THE NUCLEUS OF AN ATOM MASS NUMBER – ATOMIC NUMBER = # NEUTRONS ROUND THIS NUMBER TO THE NEXT WHOLE NUMBER TO DETERMINE THE MASS NUMBER 11 Na 22.990 Sodium Example: Sodium (Na) Mass Number = 23 Atomic Number = 11 ______ 12 neutrons -
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Practice From the Periodic Table
Complete the following chart: Name Symbol Mass Number # protons # neutrons # electrons Lithium Mg 26 16
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ISOTOPES DALTON THOUGHT THAT…..
Atoms could not be divided(indivisible)….atoms can be divided All atoms of an element are IDENTICAL….not really!! Atoms of an element have same number of p+ and e-, but the number of n0 may be different
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ISOTOPES ISOTOPES ARE…
Atoms of the same element with the same number of protons, but different numbers of neutrons. Atoms of the same element (same atomic number) with different mass numbers
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THE ISOTOPES OF HYDROGEN
All atoms have the same number of protons (p+=1)……. ….but different number of neutrons in the nucleus (which means these isotopes will have different mass numbers!!)
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Z X ISOTOPIC NOTATION A (the total number of protons + neutrons)
A = mass number (the total number of protons + neutrons) Z = atomic number (the total number of protons) X = element symbol
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READING ISOTOPIC NOTATION
46 21 Sc 46 = mass number (the total number of protons (21) + neutrons (25)) 21 = atomic number (the total number of protons (21)) Sc = element symbol (In a neutral atom, the number of electrons (21) is equal to the number of protons)
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Another way of writing an isotope
46 21 Sc or Scandium-46 Name of the element followed by the mass number (This format does not include the atomic number)
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16 31 65 8 15 30 Practice O P Zn 8 p+ 15 p+ 30 p+ 8 n 16 n 35 n
O P Zn 8 p p p+ 8 n 16 n 35 n 8 e e e- LecturePLUS Timberlake
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practice An atom has 14 protons and 20 neutrons.
A. Its atomic number is 1) ) ) 34 B. Its mass number is C. The element is 1) Si 2) Ca 3) Se D. Another isotope of this element is 1) 34X 2) 34X 3) 36X LecturePLUS Timberlake
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Isotopes Most elements found as a mixture of isotopes
Relative abundance of each isotope is constant Example: Potassium in bananas 93.25% of K atoms have 20 n0 6.7302% of K atoms have 22 n0 0.0117% of K atoms have 21 n0 LecturePLUS Timberlake
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Isotopes Isotopes of an element differ in mass
The more neutrons in an isotope, the greater the mass Still, isotopes of an element have the same chemical behavior Why? Chemical behavior depends on the number of e-, not n0 or p+ LecturePLUS Timberlake
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Calculating Atomic Mass
Percent abundance of isotopes Mass of each isotope of that element Average Atomic Mass= mass isotope1(percent abundance1) + mass isotope2(percent abundance2) + … LecturePLUS Timberlake
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Atomic Mass of Magnesium
Isotopes Mass of Isotope Abundance 24Mg = 24.0 amu % 25Mg = amu % 26Mg = amu % Average atomic mass of Mg = 24.3 amu Mg 24.3 LecturePLUS Timberlake
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Learning Check AT7 Gallium is a metallic element found in small lasers used in compact disc players. In a sample of gallium, there is 60.2% of gallium-69 (68.9 amu) atoms and 39.8% of gallium-71 (70.9 amu) atoms. What is the atomic mass of gallium? LecturePLUS Timberlake
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Solution AT7 68.9 amu x 60.2 = 41.5 amu for Gallium-69 100
Atomic mass Ga = amu LecturePLUS Timberlake
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