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Introduction to microfabrication, chapter 1
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Dimension in microworld
Fig. 1.12
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Materials Thin films: 10-1000 nm; SiO2 (insulator) Al (conductor)
substrate thin film 1 thin film 2 surface interface 2 interface 1 Thin films: nm; SiO2 (insulator) Al (conductor) Substrate: thick piece of materials (0.5 mm = 500 µm) Silicon most often
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Microfabrication vs. Nanofabrication ?
Fig. 1.3: Electron beam lithography defined gold-palladium nanobridge Fig. 24.4: Focussed ion beam patterned Aalto vase
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Fig. 1.1: Microtechnology subfield evolution from 1960’s onwards.
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Silicon microelectronics
0.5 µm CMOS in SEM micrograph 65 nm CMOS in TEM micrograph
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MOS transistor Fig. 1.18: Schematic of a MOS transistor: gate, source (S) and drain (D) in an active area defined by thick isolation oxide.
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Patterning process: optical lithography and etching
Fig. 9.1
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Photoresist application
Surface preparation for adhesion improvement Spin coating Resist dispensing Acceleration Final spinning 5000 rpm (a few milliliters) (resist expelled) (partial drying via evaporation)
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Photoresist exposure Positive AZ resist:
Positive resist: exposed parts become soluble Negative resist: exposed parts cross-linked and insoluble
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Lithography test structures
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Contact/proximity lithography
gap λ = 436 nm d = 1 µm (standard resist) Linewidth min ≈ 0.5 µm g = 0 (contact) Linewidth min ≈2 µm g = 10 µm (proximity)
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Contact/proximity resolution
Vacuum contact Hard contact Soft contact 20 µm proximity gap
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Linewidth and pitch The goal of lithography is to make lines and spaces small (only this will increase device packing density). Linewidth on previous slide was actually half-pitch: the resolving power of optical systems was divided half and half for line and space. In making microprocessor gates, line is smaller than space, e.g. 100 nm pitch results in 30 nm gate and 70 nm space.
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After lithography ion implantation (Ch 15) wet etching (Ch 11)
b c d e f ion implantation (Ch 15) wet etching (Ch 11) moulding (Ch 18) plasma etching (Ch 11) electroplating (Ch 29) lift-off (Ch 23)
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Imprinting/embossing
Press 3D master into softened polymer Remove after cooling below Tg Apply photofilm Press together Stamp release Residue clearing
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Nanoimprinted Photonic Crystal Devices
Silicon stamp: High lateral resolution Protrusion height ~ 100 nm Anders Kristensen
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UV nanoimprinting Use light to harden the polymer
Apply polymer Stamp+UV Stamp release Residue clearing
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Superhydrophobic biomimetic surfaces by UV-NIL
Nanotech 2006, Boston
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Alignment Microdevices are build layer-by-layer.
Alignment is needed to make those structures coincide. Mask and wafer are aligned before exposure Mask with second level structrures Wafer with first level structures
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Resistor alignment Resistor material patterned Insulation deposited
#2 contactsholes #3 metallization Resistor material patterned Insulation deposited Contach hole lithography & etching Metal deposition
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Silicon wafers Fig. 1.4: 100 mm diameter silicon wafer
scribe lines for chip dicing wafer flat for orientation checking alignment marks for lithography edge exclusion Fig. 1.4: 100 mm diameter silicon wafer Fig Real estate allocation on a wafer
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Silicon strengths silicon is a good mechanical material
silicon is good thermal conductor silicon is transparent in infrared silicon is a semiconductor silicon is optically smooth and flat silicon is known inside out consider silicon first, alternatives then
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Single crystalline silicon (a.k.a. monocrystalline)
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Polycrystalline and amorphous materials
Fig. 1.6
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Other substrates Glass amorphous SiO2 + Na2O + CaO +…
Quartz amorphous or crystalline SiO2 Sapphire crystalline Al2O3 Alumina amorphous Al2O3 klk GaAs crystalline GaN crystalline SiC crystalline Steel multicrystalline Nickel multicrystalline AlN multicrystalline ZnO amorphous (“glass”) PCB polymer LTCC ceramic
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High temperature processes
T > ~ 900oC Thermal oxidation Si + O2 SiO2 Diffusion
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Arrhenius processes 3.5eV 2.2 eV
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Optoelectronics Fig. 1.14: Silicon solar cell
Fig. 6.2: GaAs multiple quantum well solar cell
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MOEMS (Micro Opto Electro Mechanical Systems)
Fig. 21.4: variable optical attenator Fig. 1.2: Micromirror made of silicon, 1 mm diameter, is supported by 1.2 µm wide, 4 µm thick torsion bars (detail figure), from ref. Greywall.
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Micro-optics Fig. 1.7: Aluminum oxide and titanium oxide thin films deposited over silicon waveguide ridges, courtesy Tapani Alasaarela. Fig. 7.13: Refractive index SiO2/SiOxNy/SiO2 waveguide: nf 1.46/1.52/1.46. From ref. Hilleringmann.
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MEMS: Micro Electro Mechanical Systems
Fig : Microgears, courtsey Sandia National Labs. Fig. 21.3: comb-drive actuator
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Power MEMS Fabricated by bonding together 5 silicon wafers.
Fig. 1.17: Microturbine
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Microfluidics and BioMEMS
Fig. 1.13: silicon microneedle Fig. 1.11: Oxy-hydrogen burner flame ionization detector
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Cleanroom
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Yield 50 step MEMS process Y0 = 0.999 95%
Yield of a total process is a product of yield of individual process steps 50 step MEMS process Y0 = 95% 500 step DRAM process, Y0 = 61%
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Yield (2) D = 0.01 mm-2 (= 1/cm2) A= 10 mm2 Y = 90%
Yield depends on chip area (A) and defect density (D) D = 0.01 mm-2 (= 1/cm2) A= 10 mm2 Y = 90% A= 100 mm2 Y = 37%
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Industries Integrated circuits $300 B Other semiconductors $30 B
Flat panels displays $100 B Hard disks $30 B Solar cells $30 B MEMS $10 B Equipment $30 B Materials $10 B
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