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Published byOphelia Tate Modified over 9 years ago
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Final material
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What different pathways have we talked about that are new? Halogenalkane to nitrile or amine. Nitrile to amine. Amine and carboxylic acid to amide Alcohol and carboxylic acid to ester. Alkene to poly(alkene)
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What are stereoisomers? These are isomers based on their 3D shape.
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What are geometric isomers? Geometric isomers become stuck in space and have 2 different 3D shapes. These are caused by rigid structures. 2 common structures are double bonds and cyclic structures.
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What different qualities does this give the molecule? Polarity and symmetry are effected by shape.
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What are optical isomers? These isomers are rotated around a chiral carbon. A chiral carbon has 4 different groups or atoms attached to it.
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What is an enantiomer? These are 2 non-superimposable forms of a molecule. Equal mixtures of 2 enantiomers are said to be racemic.
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What properties do optical isomers have? They show optical activity and reactivity with other chiral molecules. Optical activity is the ability of the different isomers to rotate light in specific directions. Racemic mixtures cancel each other out.
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What is resolution? When a racemic mixture is combined with another enantiomer, they form different products that can be separated easily. The difference in chirality can change the reactivity/activity of the molecule. Something helpful becomes dangerous or ineffective by rotating the chiral carbon.
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