1. Institute of Chemical Engineering page 1 Achema 2012 Chemical Process Engineering Research Group Zero Emission Technologies Contact: Dipl.-Ing. Dr. Tobias Pröll tobias.proell@tuwien.ac.at

2. Institute of Chemical Engineering page 2 Achema 2012 Chemical Process Engineering Working Group Zero Emission Technologies Content Working Group Zero Emission Technologies Research Topics Project Group Chemical Looping Technologies Project Group Oxyfuel Combustion Project Group Process Simulation Links and Contact

3. Institute of Chemical Engineering page 3 Achema 2012 Chemical Process Engineering The ZET team focuses on projects from the energy technology sector with the goal to substantially reduce greenhouse gas emissions. Here, three general approaches are put forward: Energy efficiency increase in industrial processes Renewable fuels substituting fossil energy Capture of CO 2 from energy conversion processes Working Group Zero Emission Technologies

4. Institute of Chemical Engineering page 4 Achema 2012 Chemical Process Engineering Recent topics in investigation are: Fluidized bed systems for inherent CO 2 capture (Chemical Looping Combustion). Catalytic reforming in fluidized beds (Chemical Looping Reforming). Oxyfuel combustion in circulating fluidized bed regime. Analysis and optimization of industrial fluidized bed combustors. Techno-economic evaluation of fossil energy substitution in industry. Working Group Zero Emission Technologies

5. Institute of Chemical Engineering page 5 Achema 2012 Chemical Process Engineering The research focus of the project group chemical looping technologies lies on CLC and CLR. In both technologies, oxygen is selectively transported by metal oxides. Project Group Chemical Looping Technologies Air- reactor (AR) Fuel- reactor (FR) air fuel depleted air CO 2, H 2 O MeO  -1 MeO  Chemical looping reforming (CLR) Air- reactor (AR) Fuel- reactor (FR) air fuel N 2,Ar CO, H 2, CO 2, H 2 O MeO  -1 MeO  Chemical looping combustion (CLC)

6. Institute of Chemical Engineering page 6 Achema 2012 Chemical Process Engineering Project Group Chemical Looping Technologies The Dual circulating fluidized bed (DCFB) reactor system 120kW DCFB CL pilot rig

7. Institute of Chemical Engineering page 7 Achema 2012 Chemical Process Engineering Main research activities in Chemical Looping include:  Reactor hydrodynamics  Detailed reactor modelling  Process modelling  Process demonstration Project Group Chemical Looping Technologies

8. Institute of Chemical Engineering page 8 Achema 2012 Chemical Process Engineering Project Group Oxyfuel Combustion OxyFuel… is a key technology for efficient separation of CO 2 from combustion of fuels. performs combustion of fuel with pure or enriched oxygen (mixing flue gas with pure oxygen). allows improved operation for low calorific fuels thanks to the possibility of variation of O 2 content at the inlet. entails an energy penalty comparable or even less than for pre and post combustion CO 2 capture. in CFB can reduce formation of thermal NO X compared to PCC.

9. Institute of Chemical Engineering page 9 Achema 2012 Chemical Process Engineering Project Group Oxyfuel Combustion Reactor Loop seal Primary Air Conveyor Down- comer Cyclone Secondary Air Oxyfuel in circulating fluidized bed system 100kW Oxyfuel pilot rig Cyclone separator Fuel hopper Flow meters Filter box Bed material cooling Post combustion chamber Riser

10. Institute of Chemical Engineering page 10 Achema 2012 Chemical Process Engineering Project Group Process Simulation contribution of process simulation first calculations, mass & energy balances, experiments development process design &data for basic engineering support operation start, plant optimization fuel testing experimental results plant parameters operation data simulation model Process Simulation … … support the development of a production process and the scale up laboratory pilot plant in a laboratory demonstration plantcommercial production plant © m+w zander

11. Institute of Chemical Engineering page 11 Achema 2012 Chemical Process Engineering The tasks performed in the project group Process Simulation include: basic plausibility calculations mass- and energy balances for new production processes development of new process designs energy balances for new power plant concepts in Energy- and Chemical engineering. Furthermore, the focus also lies on various ‚research- tasks in the field of thermal fuel conversion, e.g. biomass gasification and municipal solid waste combustion plants. Project Group Process Simulation Plant Concept - Process Design Plant Simulation Plant Operation Figures Evaluation Business Case

12. Institute of Chemical Engineering page 12 Achema 2012 Chemical Process Engineering Contact Head of Research Group Zero Emission Technologies Dipl.-Ing. Dr. Tobias Pröll tobias.proell@tuwien.ac.at tobias.proell@tuwien.ac.at Tel. +43-1-58801-166304 Fax +43-1-58801-15999 Links  http://www.vt.tuwien.ac.at/chemical_process_engineering_and_energy_tech nology/zero_emission_technologies/EN/ http://www.vt.tuwien.ac.at/chemical_process_engineering_and_energy_tech nology/zero_emission_technologies/EN/  www.chemical-looping.at www.chemical-looping.at  www.oxyfuel.at www.oxyfuel.at Further Information