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Acids and Bases Chapter 6.3 & 6.4
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Mini-Project Organize the following formulas into two groups with four formulas in each group: HNO3, NaOH, H2SO4, H2CO3, Ca(OH) 2, KOH, H8PO4, Mg(OH) 2 One way to organize them into groups is: Group One Group Two HNO3 NaOH H2SO4 Ca(OH) 2 H2CO3 KOH H8PO4 Mg(OH) 2 Group One formulas represent acids. Group Two formulas represent bases.
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ACIDS Taste sour (lemon, vinegar) React with metal (corrosion)
React with carbonates (makes bubbles of CO2 Turns blue litmus RED In Water forms Hydrogen ION HCl H+ + Cl- Water
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BASES Taste Bitter (soap, tonic water) Feel Slippery (soap)
Turns Red Litmus Blue In water, forms HYDROXIDE (OH-) ion React with Acids to make water NaOH Na+ + OH- Water
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Indicators An Indicator is a chemical that turns colors under certain conditions. Litmus paper is paper with the indicator litmus on it. Litmus turns blue when in contact with a base Litmus turns red when in contact with an acid There are many different indicators Bromthymol blue, universal, malachite green, etc.
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Why are Some Solutions Acid & Others Base?
Acid solutions contain more H+ ions than OH- ions. Base solutions contain more OH- ions than H+ ions. Water is the standard for Acid/Base and is defined as NEUTRAL Water has equal amounts of H+ and OH- ions
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Arrhenius Model of Acids/Bases
Substance is an acid if it contains hydrogen and dissociation causes hydrogen ions to form in solution Substance is a base if it contains a hydroxide and dissociates to produce hydroxide ions in solution
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Bronsted-Lowry Model Acid is a hydrogen ion donor
Base is a hydrogen ion receptor This is a broader definition than Arrhenius model because there are substances that cause donation or reception without having hydrogen in them.
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Electrolytes Acids and Bases are ELECTROLYTES They ionize in water
They conduct electricity
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Strong vs. Weak Weak Acids/Bases vs. Strong Acids/Bases
Strong acids/bases ionize completely Weak acids/bases only partly ionize Strong Bases are just as dangerous as Strong Acids They react with most things they touch
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More Concentrated vs. Dilute
Concentrated means lots of acid/base in a little bit of water Dilute means a little bit of acid/base in a lot of water Concentrated Acids and Bases are VERY Dangerous They react quickly with many substances
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Common Acids
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Common Bases
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Acid Rain Acid rain comes from rain collecting gasses from the air to create acids: Carbon Dioxide = carbonic acid Sulfur oxides = sulfuric acid Nitrogen oxides = nitric acid Damages statues, buildings, kills forests, kills fish
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pH Scale
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pH pH stands for ‘per hydrion’
It measures the amount of hydrogen ions in solution Water is defined as ‘neutral’ Water has one H+ and one OH- equal numbers The concentration of H+ in water is 1.0 x 10-7 The pH of water is 7 A lower pH means MORE Hydrogen ions (Acid) 10-6 is Larger than 10-7 A higher pH means LESS hydrogen ions (Base) 10-8 is Smaller than 10-7 pH scale is a way of showing this relationship of hydrogen ions
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pOH In water concentration of H+ = concentration of OH-
So [H+] = [OH-] = 1.0 x 10-7 Think about it: H2O is the same as H-O-H which is H+ + OH- So pOH of water is also 7 pH + pOH always equals 14, so pH scale goes from 1 to 14
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Common Items on the pH Scale
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Neutralization Reactions
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Acid-Base Reactions HCl + NaOH H2O + Na+ + Cl-
Neutralization reaction is a reaction between an acid and a base Makes Water + Salt Solution becomes Neutral (not acid or base) NOTE: salt is a ‘category’ of chemicals, not always sodium chloride HCl + NaOH H2O + Na+ + Cl-
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Acid-Base Reactions Mg(OH)2 + 2 HCl → MgCl2 + 2H2O Note:
Cation from base (Mg) is combined with anion from acid (Cl) The salt is MgCl2 The H+ and OH- always combine to form water
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Acid-Base Titration Acid/Base Titration is the stoichiometry of acid/base reactions. Titration is a method for determining the concentration of a solution by using another solution of known concentration Uses an INDICATOR to show when the acid/base reaction is complete (neutral) Indicator is a chemical that changes color as determined by acid or base conditions There are many indicators with different pH points.
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Acid/Base Titration Curve
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pH Indicators Name Acid Color pH Range of Color Change Base Color
Methyl violet Yellow Blue Thymol blue Red Methyl orange Bromocresol green Methyl red Litmus Bromothymol blue Phenolphthalein Colorless Pink Thymolphthalein Alizarin yellow R
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