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Jenna Mandel and Shela Wu AP Chemistry - 7. Intermolecular Intramolecular VS BETWEEN MOLECULESKEEPS MOLECULE TOGETHER When something undergoes a phase.

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Presentation on theme: "Jenna Mandel and Shela Wu AP Chemistry - 7. Intermolecular Intramolecular VS BETWEEN MOLECULESKEEPS MOLECULE TOGETHER When something undergoes a phase."— Presentation transcript:

1 Jenna Mandel and Shela Wu AP Chemistry - 7

2 Intermolecular Intramolecular VS BETWEEN MOLECULESKEEPS MOLECULE TOGETHER When something undergoes a phase change, the changes occur in the intermolecular forces.

3 Occurs between two polar molecules HYDROGEN BONDING Strong form of dipole-dipole attractions Occurs in molecules with hydrogen that is bonded with an element with a high E.N. High difference in electronegativity & small size contributes to its great strength

4 L o n d o n D i s p e r s i o n F o r c e s OCCURS BETWEEN 2 NON-POLAR MOLECULES INSTANT- ANEOUS DIPOLES IN LARGE ATOMS, CAN BE MORE SIGNIFICANT THAN DIPOLE- DIPOLE FORCES

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6 measure of liquid’s resistance to flow surface tension the resistance of a liquid to an increase in its surface area capillary action spontaneous rising of a liquid in a narrow tube a result of adhesion and cohesion Concave shape of meniscus shows adhesive > cohesive Viscosity: adhesive versus cohesive liquid particles attracted to themselves force between liquid and surrounding

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8 describes the locations of the pieces in a crystalline solid LATTICE UNIT CELL smallest repeating unit of the lattice as apposed to amorphous solids…

9 ions at lattice points

10 small molecules at lattice points

11 atoms at lattice points Metallic Solids Positively charged & held together by neutrons. Delocalized electron sea theory

12 atoms at lattice points Network Solids Atoms bond covalently in a continuous network. Strong Bonds -> High mp & bp Do not conduct electricity

13 atoms at lattice points Group 8A Solids Noble gases bonded with London Dispersion Forces Occur at very low temperatures!

14 It’s ductile! It’s malleable! strong & nondirectional ELECTRON SEA MODEL metal cations in valence e - conduct heat and electricity malleable and ductile

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16 VERSUS Hardest naturally occurring substance sp 3 hybridization large gap between filled and empty levels in energy diagram carbon surrounded by a tetrahedral Slippery, black, & a conductor Layers of carbon atoms in 6 member rings sp 2 hybridization weak bonding between layers accounts for slippery texture

17 PHASE CHANGES Heat of Vaporization ENERGY NEEDED TO VAPORIZE A MOLE OF LIQUID When does a liquid boil? its vapor pressure EQUALS pressure of the environment

18 ΔH vap = enthalpy of vaporization R = 8.3145 J/K·mol T = temperature (kelvin) C=constant Determine heat of vaporization, and can also be used to find P vap

19 Rate of evaporation remains constant while rate of condensation increases as number of molecules in vapor phase increases, until they become equal, and thus reach equilibrium.

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