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METALLURGY
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Metallurgy The extraction of metals from their ores and refining it is known as metallurgy
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ENRICHMENT OF ORE Process used for removal of the “GANGUE” GANGUE – Soil, Sand and Earthy Impurities
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Enrichment processes Hydraulic washing
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Froth Floatation
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Electromagnetic separation
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Chemical Method Dissolve ore + Hot and Conc. NaOH Al 2 O 3 + 2NaOH -> 2NaAlO 2 +H 2 O Filter it- add dil HCl NaAlO 2 + 2H 2 O + HCl - Al(OH) 3 + NaCl Filter the ppt wash,dry and Ignite 2Al(OH) 3 - Al 2 O 3 + 3H 2 O Pure Bauxite is obtained
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REDUCTION Conversion of concentrated ore into a more suitable form Roasting -- Heating the Sulphide ore in presence of air to form an Oxide ore 2ZnS+3O 2 2ZnO + 2SO 2 Calcination -- Heating the Carbonate ore in the absence of air to form an Oxide ore ZnCO 3 - ZnO + CO 2
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Reduction Low in the reactivity series ---- Heating ---- e.g..2HgS + 3O 2 2HgO +2SO 2 2HgO (S) - 2Hg + O 2 (g) Middle in the reactivity series Heating with C (Smelting) ZnO + C -- Zn + CO High up in the reactivity series Electrolytic reduction
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REFINING LIQUATION: Used for metals having low M.P. Pb,Sn Metal (low M.P.) Impurity(High M.p.) Hearth
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REFINING DISTILLATION Metals used are Volatile - Hg,Zn The impure metal is heated in a retort. The Pure metal distils over and is condensed in a receiver. The impurities are left behind in the retort
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k ELECTROLYTIC REFINING Metals used are --- Cu,Zn,Sn,Ni,Ag,Au… CuSO 4 + H 2 SO 4
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