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Unit One
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Notes One Unit One Two Classes of Elements Periodic Table Info?
What Are Stable Elements? Stabilizing Sodium Stabilizing Oxygen Sodium Loses electrons to Oxygen Oxidation Numbers Key Elements and Examples
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Two Classes of Elements
What are the Two Main Classes of Elements? Metals and Nonmetals (Stair-Step)
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What information doe the Periodic Table give us?
Atomic Number # Protons = # of Electrons Electron structure Mass Number = # P + # N
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What Makes Elements Stable?
Which orbitals? Eight Electrons…… Highest S and P…… Noble Gases (electronically stable) He, Ne, Ar, Kr, Xe, and Rn Lose or Gain to get 8e-1 (to become stable) Do metals Lose or Gain electrons? Do nonmetals Lose or Gain electrons? Which Family? (Lose) (Gain)
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Stabilizing Sodium How many electrons does sodium have? 11Na
What is Sodium’s Short-Hand Element? 10Ne How many Valence Electrons for Sodium? 1e-1 What is the shorthand electron configuration? Sodium loses/gain how many electrons? Na Na+1 + e Oxidation or reduction? (protons) + (electrons)=charge 1 [10Ne] 3s (+11) (-10) +1
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Stabilizing Oxygen How many electrons does oxygen have? 8O
What is oxygen’s Short-Hand Element? 2He How many Valence Electrons for oxygen? 6e-1 What is the shorthand electron configuration? Oxygen loses/gains how many electrons? 2e-1 O + 2e-1 O Oxidation or reduction? (protons) + (electrons)=charge [2He] 2s 2 2p 4 (+8) (-10) -2
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Sodium Loses electrons to Oxygen
Na Na+1 + e-1 (Stable Like Neon) Ox or Red? O + 2e-1 O (Stable Like Neon) Ox or Red? How many sodium atoms are needed to satisfy oxygen’s electron hunger? 2e-1 means How many oxygen atoms are needed to satisfy sodium’s electron loss? Na2O High Electronegativity two Na Low Electronegativity One O
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Oxidation Numbers Fe+2 Fe+3 S-2 S+4 S+6 All elements Lose or Gain e-1.
Some have multiple loss or gain possibilities. Fe+2 Fe+3 S-2 S+4 S+6
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Key Elements (99%) H+1 H-1 (99%)O-2 O-1
(Always) Li+1, Na+1, K+1, Rb+1, Cs+1, Fr+1 (Always) Be+2, Mg+2, Ca+2, Ba+2, Sr+2, Ra+2 (Always) Al+3 (with only a metal) F-1, Cl-1, Br-1, I-1 (NO3-1) ion is always +5 (SO4-2) ion is always +6
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Example One Find the oxidation numbers. Al2S3 Algebra is useful!
Al+3 key element 2(+3) + 3(S)=0 S= -2 2(Al) + 3(S)=
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Example Two Find the oxidation numbers. Ca(NO3)2 Algebra is useful !
Ca+2 and O-2 key elements (+2)+2(N)+6(-2)=0 (+2)+2(N)+(-12)=0 2(N)+(-10)=0 2(N)=10 N= +5 (Ca)+ 2(N)+ 6(O)=
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Finding Oxidation #’s for Compounds
+1 -2 +1 +4 -2 H2O H2CO3 +1 +5 -2 -3 +1 +4 -2 H3PO4 (NH4)2CO3 +2 +5 -2 +1 +5 -2 Ca3(AsO4)2 HNO3 +1 +6 -2 +3 +6 -2 H2SO4 Fe2(SO4)3 +1 +6 -2 +2 +7 -2 Hg2SO4 Ba(ClO4)2 +3 +4 -2 +1 +6 -2 Na2Cr2O7 Al2(CO3)3
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Now it is time for class work !!!
A101: paper practice (Work Together) CA101 : computer assignment Both will be due at beginning of class next time Ready Set Break !!!
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Notes Two Unit One Naming Inorganic Salts Example One
Example One Thinking Example Two Computer Assignment One
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Naming Inorganic Salts
TWO parts to the name 1) Cation 2) Anion Cation Examples Ca+2 Al+3 Fe+2 Na+1 Anion Examples Cl-1 NO3-1 SO4-2 N-3 Positive Negative
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Example One Iron(II) Fe+2 Iron(III) Fe+3 Name the formula Fe2(CrO4)3
Step #1 Find The + Ion(s). Iron(II) Fe+2 Iron(III) Fe+3
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Example One Step #2 Find The - Ion(s) Chromate CrO4-2
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Example One Fe2(CrO4)3 Fe+2 Iron(II) Fe+3 Iron(III) CrO4-2 Chromate
(+2) + Y (-2) = X (+3) + Y (-2) = X=1 Y=1 X=2 Y=3 1 (+2) + 1 (-2) = 2 (+3) + 3 (-2) = Fe CrO4 Fe2(CrO4)3
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Example Two Al2(CO3)3 Al+3 Aluminum CO3-2 Carbonate Aluminum Carbonate
(+3) + Y (-2) = X=2 Y=3 2 (+3) + 3 (-2) = Al2(CO3)3
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Computer Assignment One/Two
NAMING IONIC COMPOUNDS LEVELs ONE AND TWO
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Writing a Formula From a Name
(Cation+?)X(Anion-?)Y X (+?) + Y (-?) = If X or Y is 2 or greater... Lowest Whole Number Ratio and the ion is polyatomic. Ba+2 Cr2O Hg Pb+4 ( )_( )_ Lithium Nitrate Li+1 1 NO3-1 1 LiNO3 ( )_( )_ Hydrogen Phosphate H+1 3 PO4-3 1 H3PO4 ( )_( )_ Ammonium carbonate NH4+1 2 CO3-2 1 (NH4)2CO3 ( )_( )_ Calcium Arsenate Ca+2 3 AsO4-3 2 Ca3(AsO4)2 ( )_( )_ Iron(III) periodate Fe+3 1 IO4-1 3 Fe(IO4)3 ( )_( )_ Mercury(I) Sulfate Hg2+2 2 SO4-2 2 Hg2SO4 ( )_( )_ Barium Perchlorate Ba+2 1 ClO4-1 2 Ba(ClO4)2 ( )_( )_ Sodium Dichromate Na+1 2 Cr2O7-2 1 Na2Cr2O7 ( )_( )_ Lead(IV) Sulfate Pb+4 2 SO4-2 4 Pb(SO4)2
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Notes Three Unit One Standard Amounts One Gopher One Mole Formula mass
Percent Composition Empirical Formula
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Standard Amounts How many dollars is… A) 120 pennies? 1.2 dollars
B) 2 quarters? 0.5 dollars C) 15 nickels? 0.75 dollars How many dozens is… D) 48 eggs? 4 dozen E)18 apple fritters 1.5 dozen
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One Gopher One Gopher equals 12 items
What is the mass of one gopher of… A) white beads? 2.81g/G B) blue beads? 0.50g/G C) orange Beads? 1.67g/G
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Seven Rows Eight Rows
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One Gopher(12 items) In Six groups
(1) How many gophers of beads are in… (2) How many beads are in… A) ___g B) ___g C) ___g D) ___g E) ___g F) ___g 2.00 48 beads 4.00G 3.49 15 beads 1.24G 2.51 18 beads 1.50G 27 beads 3.75 2.25G 1.75 3.50G 42 beads 5.82 2.07G 25 beads
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One Mole N O C One mole is 6.022x10+23 items.
Each element on the period table has a mass per mole. N 14.0g 6.022x10+23atoms O 16.0g 6.022x10+23atoms C 12.0g 6.022x10+23atoms How many moles are in each? How many atoms are in each? N 7.0g ÷14.0g/m =0.50m x6.022x10+23atoms/m =3.01x10+23atoms O 4.0g ÷16.0g/m =0.25m x6.022x10+23atoms/m =1.51x10+23atoms C 18.0g ÷12.0g/m =1.50m x6.022x10+23atoms/m =9.03x10+23atoms
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Calculations Bases on Chemical Formulas
Formula mass (Molecular Mass or Gram-Formula Mass) Empirical Formula Percent Composition
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Rounding Atomic Mass C 12.011 12.0 Fe 55.847 55.8 O 15.9994 16.0 Bi
209.0 K 39.1 Au 197.0 Os 190.23 190.2 Mg 24.3 Na 23.0
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Formula Mass Example One
Calculate the formula mass for 1 mole of C6H12O6. E # Mass C 6 x 12.0 = 72.0 12.011 H 12 x 1.0 = 12.0 1.0079 O 6 x 16.0 = 96.0 180.0g/mol How many molecules of C6H12O6 is 180.0g/mol? 6.022x10+23 molecules
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Empirical Formula Example One
What is the empirical (simplest) formula containing 36.8% N, 63.2% O? 1) Calculate moles of each element. E Q Mass Mass N 36.8 g ÷ 14.0 = 2.63 mol N O 63.2 g ÷ 16.0 = 3.95 mol O 2) Calculate the lowest ratio. E Moles Lowest Ratio N 2.63 mol N ÷ 2.63 mol = 1.00 O 3.95 mol O ÷ 2.63 mol = 1.50 3) Write the formula X by 2 to get whole numbers N2O3
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Percent Composition Example One
Calculate the percentage composition of H2O. 1)Calculate the formula mass for 1 mole of H2O E # Mass H 2 x 1.0 = 2.0 1.0079 O 1 x 16.0 = 16.0 18.0g/mol 2) Divide each contribution by the total mass. H 2.0 ÷ 18.0 = ( x 100) = 11% 0.11 Answer O 16.0 ÷ 18.0 = 0.889 ( x 100) = 88.9% 3) Add the percentages to check work. 11% 88.9% 100.%
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Empirical Formula Example Two
What is the empirical (simplest) formula containing 69.58% Ba, 6.090% C, 24.32% O? 1) Calculate moles of each element. E Q Mass Mass Ba 69.58 g ÷ = mol Ba C 6.090 g ÷ = mol C O 24.32 g ÷ = mol O 2) Calculate the lowest ratio. E Moles Lowest Ratio Ba mol ÷ mol = 1.000 C mol ÷ mol = 1.001 O mol ÷ mol = 3.00 3) Write the formula X by 1 to get whole numbers BaCO3
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Percent Composition Example Two
Calculate the percentage composition of Fe(ClO4)3. 1)Calculate the formula mass for 1 mole of Fe(ClO4)3. E # Mass 55.847 Fe 1 x 55.8 = 55.8 35.453 Cl 3 x 35.5 = 106.5 O 12 x 16.0 = 192.0 354.3g/mol 2) Divide the each contribution by the total mass. Fe 55.8 ÷ = ( x 100) = 15.8% 0.1575 Cl 106.5 ÷ = ( x 100) = 30.06% 0.3006 Answer O 192.0 ÷ = ( x 100) = 54.19% 0.5419 3) Add the percentages to check work. 15.8 % 30.1 % 54.2 % 100.1%
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Formula Mass Example Three
Calculate the formula mass for 1 mole of Al2O3 E # Mass Al 2 x 27.0 = 54.0 O 3 x 16.0 = 48.0 102.0g/mol How many molecules of Al2O3 is102.0g/mol? 6.022x10+23 molecules
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Formula Mass Example Two
Calculate the formula mass for 1 mole of CaCO3. E # Mass 40.078 Ca 1 x 40.1 = 40.1 12.011 C 1 x 12.0 = 12.0 O 3 x 16.0 = 48.0 100.1g/mol How many molecules of CaCO3 is100.1g/mol? 6.022x10+23 molecules
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