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Drill: 5.3 kg of sodium carbonate is heated strongly. Determine products Balance reaction Calculate the volume of gas produced when calculated at STP
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Drill: Calculate the mass of (NH 4 ) 2 SO 4 produced when 11.2 mL NH 3 gas reacts is excess H 2 SO 4 in the following rxn: NH 3 + H 2 SO 4 (NH 4 ) 2 SO 4
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Homework AP Read Ch 5 Work problems: 11, 13, 15, 29, 31, 33, 41, 43, 51, & 69
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Chm II Homework Read Ch 12 Look over PP-11 attached on the Poly website.
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Kinetic Theory
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All matter is made up of tiny particles The particles are in constant motion All collisions are elastic
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Drill: Calculate the volume at STP of CO 2 released when 23.4 g of aluminum carbonate is decomposed 75 % through heat
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AP Test Changes No Choices in Problems Only 3 reactions with predicting products –Balance rxns –No choices –Explain rxns
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Pressure
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Force per unit area Caused by collisions against a surface Gas measured in pressure
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Units of Pressure kPa: kilopascal (Std Unit) Pascal: newton/sq. meter Atmosphere (Atm): mm Hg:
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Standard Pressure 101.3 kPa (to be changed) 1.00 Atm 760 mm Hg or Torrs 30.0 inches Hg 1013 millibars
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Gas Laws
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State the Following Laws Boyle’s Law Charles’ Law Gay Lussac’s Law Dalton’s Law Graham’s Law
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Boyle’s Law
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The pressure & volume of a gas at constant temperature are inversely proportioned P 1 V 1 = P 2 V 2 = K
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Charles’ Law
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The volume and temperature of a gas at constant pressure are directly proportioned V 1 /T 1 = V 2 /T 2 = K
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Guy Lussac’s Law
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The Pressure and temperature of a gas at constant volume are directly proportioned P 1 /T 1 = P 2 /T 2 = K
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Combined Gas Law
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Combination of the three formulas P 1 V 1 /T 1 = P 2 V 2 /T 2
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Chm II Homework Read Ch 12 Work problems: 31, 32, & 33 on page 477
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Calculate the new volume of 5.0 L of gas when its pressure is doubled and its temperature is tripled:
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Common Sense The volume of a gas is directly proportioned to the number of moles of gas V 1 /n 1 = V 2 /n 2 = K
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New Combination P 1 V 1 /n 1 T 1 = P 2 V 2 /n 2 T 2 = K
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Ideal Gas Law PV = nRT
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Drill: Calculate the volume of 3.0 moles of gas at -23 o C under 83.1 kPa pressure.
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3 Calculate the number of moles of gas occupying 831 mL under 250 kPa at 227 o C
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Calculate the number of moles of gas occupying 831 mL under 80.0 kPa at 127 o C
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Calculate the mass of CO 2 occupying 83.1 L under 25 GPa at 227 o C
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Drill: Calculate the volume in mL of 4.0 g bromine gas at 127 o C under 83.1 kPa pressure.
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Ideal Gas Law PV = nRT
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Related Formulas m V m/n D or = MW =
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Calculate the molecular mass of 5.0 g of gas occupying 831 L under 250 MPa at 227 o C
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Chm II Homework Read Ch 12 Work problems: 46, 47, & 51 on page 478
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Drill: Calculate the density of carbon dioxide at 27 o C under 83.1 kPa pressure
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Dalton’s Law
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The total pressure = the sum of the partial pressures P T = P 1 + P 2 + etc
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The total pressure of a system is 120.0 kPa. The partial pressure of gas A is 112.0 kPa. Determine the pressure of gas B
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Graham’s Law
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The velocities of particles are inversely proportioned to the square root of their masses v 1 /v 2 = M 2 / M 1
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Chm II Homework Read Ch 12 Work problems: 51, & 58 on page 478
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Drill: Calculate the ratio of the velocities of He gas to HCl gas:
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Calculate the volume of a gas at STP when it occupies 80.0 mL at 127 o C under 303.9 kPa pressure:
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Calculate the mass of 831 mL of CO 2 at 27 o C under 150 kPa pressure:
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Drill:Calculate the volume of 4.0 moles of gas under 83.1 kPa pressure at 127 o C:
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Calculate the volume of a gas at STP when it occupies 80.0 mL at 127 o C under 303.9 kPa pressure:
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5 Calculate the volume of 4.0 moles of gas under 83.1 kPa pressure at 127 o C:
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Calculate the molecular mass of 50 g of gas occupying 831 L under 250 MPa at 227 o C
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Calculate the mass of 831 mL of CO 2 at 167 o C under 150 kPa pressure:
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The total pressure of a system is 120.0 kPa. The partial pressure of gas A is 112.0 kPa. Determine the pressure of gas B
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The total pressure of a system is 150.0 kPa. The system contains 50 % A, 30 % B, & 20 % C. Determine the pressure of each gas.
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Drill: Calculate the mass of CO 2 occupying 83.1 L under 25 MPa at 477 o C
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Calculate the density of carbon dioxide at 27 o C under 83.1 kPa pressure
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Calculate the ratio of the velocities of He gas to HCl gas:
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Calculate the velocity HBr when the velocity Be is 270 m/s:
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Calculate the final volume that 3.0 L of gas will obtain when the absolute temperature is tripled & the pressure is halved.
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Calculate the mass of CO occupying 831 kL at 227 o C under 2.50 Mpa pressure.
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Calculate the volume of H 2 formed at 27 o C under 150 kPa when 6.8 mg NH 3 decomposes making N 2 & H 2.
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