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Published byNicholas Carpenter Modified over 9 years ago
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Acids were first recognized as a distinct class of compounds because of the common properties of their aqueous solutions. Aqueous solutions have a sour taste (many are corrosive and poisons). Acids change the color of acid-base indicators. Some acids react with active metals to release hydrogen gas, H 2.
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Acids react with bases to produce salts and water. Some acids conduct an electric current. Used in petroleum refining, automobile batteries, and used as a water-removing agent (can cause serious burns).
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Used in making explosives (stains skin and causes serious burns). Used for manufacturing fertilizers and animal feed and for flavoring beverages.
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Used in food processing. Used in the manufacture of plastics and as a fungicide.
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Aqueous solutions of bases have a bitter taste. Bases change the color of acid-base indicators. Dilute aqueous solutions of bases feel slippery. Bases react with acids to produce salts and water. Bases conduct electric current.
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An Arrhenius acid is a chemical compound that increases the concentration of hydrogen ions, H +, in aqueous solution. Examples: HCl, H 2 SO 4, HI, HF
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An Arrhenius base is a substance that increases the concentration of hydroxide, OH -, in aqueous solution. Examples: NaOH, LiOH, Ca(OH) 2
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A Brønsted-Lowry acid is a molecule or ion that is a proton donor (H + ). A Brønsted-Lowry base is a molecule or ion, that is a proton acceptor. In a Brønsted-Lowry acid-base reaction, protons are transferred from one reactant (the acid) to another (the base). HCO 3 + HOH → H 2 CO 3 + OH - Base Acid
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A Lewis acid is an atom, ion, or molecule that accepts an electron pair to form a covalent bond. A Lewis base is an atom, ion, or molecule that donates an electron pair to form a covalent bond. A Lewis acid-base reaction is the formation of one or more covalent bonds between an electron-pair donor and an electron-pair acceptor.
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Pure water is a weak electrolyte and undergoes self-ionization as seen below. Remember ionization is the process of adding or removing electrons from an atom or molecule, which gives the atom or molecule a net charge. In the self-ionization of water, two water molecules produce a hydronium ion and a hydroxide ion by transfer of a proton. hydronium ionhydroxide ion (Acid)(Base)
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Concentrations of hydronium ion (H 3 O + ) and hydroxide ion (OH - ) are 1.0 x 10 -7 mol/L in water at 25 o C. The product of [H 3 O + ][OH - ] = 1.0 x 10 -14 and the product is called the ionization constant of water, K w. Note: [ ] means molar concentration (mol/L).
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Any solution in which [H 3 O + ] = [OH - ] is neutral. Any solution in which [H 3 O + ] is greater than [OH - ] is acidic. Remember acids increase the concentration of H 3 O + in aqueous solutions. Any solution in which [OH - ] is greater than [H 3 O + ] is basic. Remember bases increase the concentration of OH - in aqueous solutions.
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Instead of expressing acidity or basicity in terms of the concentration of H 3 O + or OH -, a quantity called pH is used.
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The pH scale commonly has values from 0 to 14 with a pH value of 7 considered neutral. pH values less than 7 are acidic and pH value greater than 7 are basic.
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pH indicates the hydronium ion (H 3 O + ) concentration of a solution. The pH of a solution is defined as the negative of the common logarithm of the hydronium ion concentration. pH = -log[H 3 O + ] or pH = [H + ] pOH (hydroxide ion concentration) pOH = -log[OH - ] pH + pOH = 14.0
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