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Modern Chemistry Chapter 5 The Periodic Law
Sections 1-3 History of the Periodic Table Electron Configurations and the Periodic Table Electron Configurations and Periodic Properties Chapter 5 Section 1 History of the Periodic Table pages
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Electron Configurations and periodic properties
Section 3 Electron Configurations and periodic properties Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Section 3 Vocabulary Atomic radius Ion Ionization Ionization Energy
Electron affinity Cation Anion Valence electrons Electronegativity Section 3 Vocabulary Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Atomic Radii One half the distance between the nuclei of identical atoms bonded together p. 150 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Atomic Radii Period Trend Atomic radii decreases across a period
Electrons are added to the s and p in the same energy level Protons are added to the nucleus The nucleus is stronger and pulls in the electrons making the atom smaller Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Atomic Radii Group Trend Practice on page 152
Atomic radii increases down a group Exeption Al to Ga in group 13 Electrons exist in higher energy levels further from the nucleus Practice on page 152 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Atomic radius image p. 151* Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionization: any process that results in the formation of an ion
Ionization Energy Ion: an atom or group of bonded atoms that has a positive or negative charge Ionization: any process that results in the formation of an ion Ionization energy: The energy required to remove one electron from a neutral atom. Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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ion animation Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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First ionization energy = IE1 (energy to remove one electron)
Diagram on Page 153 and 154 A + energy A+ + e- Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionizaiton Energy Comic
p. ## Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionization energy animation
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionization energy vs. atomic number graph
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionization Energy Period Trend IE increases across a period
Increased nuclear charge holds e- thighter Elements with low IE lose e- easily Elements with high IE do not lose e- Generally nonmetals have higher IE than metals Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionization Energy Group Trend IE decreases down a group
An electron is removed from higher energy levels further from the nucleus In elements with many electron, the inner electrons in lower energy levels shield the outer electrons in the higher energy levels from the attraction of the nucleus Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionization energy image
p. 153* Decrease Increase Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Removing electrons from positive ions
Ionization Energy Removing electrons from positive ions More than one electron can be removed from an atom Second ionization energy = IE2 IE2 is higher than IE1 Because few electrons remain to shield the outer electrons from the nucleus Table on page 155 Practice page 156 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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1st- 5th Ionization energy chart
p. 55 Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Electron Affinity The energy change that occurs when an electron is acquired by a neutral atom A + e- A- + energy or A + e- + energy A- Positive or less negative EA won’t likely gain electrons More negative EA will gain electrons easily Energy is released negative number Energy is absorbed positive number Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Electron Affinity animation
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Electron affinity Period Trend
EA increases across the period (more neg.) Exception between group 14 and 16 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Electron affinity Group Trend EA decreases down a group (less neg.)
An increase in protons increases EA but an increase in radius decreases EA Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Electron Affinity image
p. 157* Decrease Increase Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Adding electrons to negative ions
Electron affinity Adding electrons to negative ions More difficult to add a second eletron All second EA are positive Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionic Radii Positive Ions Cation Loss of electron
Smaller electron cloud; loss of highest energy level Electrons are drawn closer to the nucleus Na Na+ Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionic Radii Negative ion Anions Gaining of electrons
The electron cloud spreads out because of the repeling of electrons Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Cation - positive Anion - negative
ions Cation - positive Anion - negative Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionic Radii Period Trend Ionic radii decreases across a period
As protons increase the electrons are pulled in Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionic Radii Group Trend Ionic Radii increases down a group
More electrons in higher energy levels Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Ionic RADIUS Image p. 159* Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Located in the incompletely filled main energy level
Valence electrons Electrons available to be lost, gained or shared in the formation of compounds. Located in the incompletely filled main energy level For main group elements – outer s & p sublevels Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Valence electrons animation
p. ## Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Linus Pauling devised a scale from 0-4.
electronegativity A measure of an atom in a compound to attract electrons from another atom in the compound Linus Pauling devised a scale from 0-4. Fluorine is the most electronegative EN = 4.0 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Electronegativities p.161
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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electronegativity animation
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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electronegativity Period Trend EN increases across a period
There are exceptions. Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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electronegativity Group Trend Practice Page 162
EN decreases down a group Practice Page 162 Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Electronegativity Electronegativity Decrease Increase p. 160*
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Periodic Properties of the d and F block elements
Many exceptions in atomic radii, IE, and EN Most d block elements from 2+ ions Group 3 from 3+ ions Copper forms 1+ and 2+ ions Iron forms 2+ and 3+ ions Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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Summary of trends Image
Chapter 5 Section 1 History of the Periodic Table pages Chapter 5 Section 1 History of the Periodic Table pages
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Section 3 Homework Chapter 5 Section 3 Periodic Properties pages Chapter 5 Section 1 History of the Periodic Table pages
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