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Lecture Notes V Oxygen sensors based on oxygen ion conductors.

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Presentation on theme: "Lecture Notes V Oxygen sensors based on oxygen ion conductors."— Presentation transcript:

1 Lecture Notes V Oxygen sensors based on oxygen ion conductors

2 Dependence of domain boundaries on oxygen pressure and temperature PpPp PpPp PnPn PnPn Ionic domains p-cond. n-cond

3 Function / 4F Porous Pt electrodes – reactions takes place in triple points 1

4 Calibration curve Short circuit due to electronic conduction

5 High temperature oxygen sensors Temperature range: 600 - 1500ºC Pressure range becomes smaller with increasing temperature. Good resistance toward corrosive atmospheres. Good temperature shock resistance. It is the equilibrium oxygen pressure which is measured!

6 In-situ measurements Examples: - Combustion control in gas- and coal fired furnaces; -Atmosphere control in sintering and heat treatment furnaces. - Combustion of waste;

7 In-situ oxygen control in molten steel. Electrolyte, Belgium

8 - sensor Catalytic emission-control Engine Exhaust Control unit

9 Cross section of λ-sensor

10 Extractive control of welding gases TIG- tungsten inert gas welding Argon Gas on backside must be controlled. Welding of stainless steel.

11 Extractive control of welding gases TIG- tungsten inert gas welding Argon PBI-Dansensor

12 Atmosphere control Fluid N 2 850 m 3 /h Nitrogen freeze dryer

13 Extractive quality control Packed meat and vegetables. PBI-Dansensor

14 Repetition How function an oxygen sensor? Typical applications of oxygen sensors.


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