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Catalysis group Department of Chemical Engineering, NTNU
Anders Edd Anders De Magnus Hilde Holmen Blekkan Chen Rønning Venvik The Catalysis group (KinCat) also encompasses approx scientists and technicians working in SINTEF, PhD candidates and 4-6 postdocs, as well as visiting students (PhD & MSc) from other laboratories. An overview of our activity is available in or Annual report.
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Catalysis group Department of Chemical Engineering, NTNU
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Geminisenter NTNU-SINTEF
SFI – inGAP (Innovative Natural Gas Processes and Products) Centre for research-based innovation In collaboration with UiO, SINTEF, Statoil, Borealis, Ineos and HTAS.
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Catalysis Tjeldbergodden methanol plant Main activities Natural Gas conversion Oil refining Hydrogen technology Energy- and environmental technology Carbon nanofibre materials Microstructured reactors Catalyst preparation Catalyst characterisation Kinetics and reaction engineering Catalyst pellets ~m Microreactor ~cm Catalyst- particle Au/C ~mm Catalysis is a broad subject, spanning from fullscale industrial plants to complex nanomaterials ~nm
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Fischer-Tropsch synthesis
Catalysts: Co, Fe, Ru Temperature: °C Pressure: 1-50 atm Natural gas/ steam Air H2 CO CO2 Raw products Oxygen production Synthesis gas production Fischer-Tropsch synthesis Separation/ upgrading Final products
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Statoil GTL Semi-commercial pilot plant in Mossel Bai, South Africa.
In operation since autumn 2004. We have had a close collaboration with StatoilHydro on this process development for > 20 years
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PARTIAL OXIDATION/ STEAM REFORMING WATER GAS SHIFT CO + H2O CO2 + H2
Advanced catalyst/reactor systems for conversion of hydrocarbons to hydrogen for fuel cells Forschungzentrum Karlsruhe SINTEF Applied Chemistry Catalysis and Kinetics Department Hydrocarbon Process Chemistry Department The Norwegian University of Science and Technology Department of Chemical Engineering SINTEF Materials Technology Department of Process Metallurgy and Ceramics International collaboration with Forschungzentrum Karlsruhe, Germany CHEMICAL HYDROGEN CARRIER FUEL CELL H2 + O2 H2O AIR ANODE GAS CATHODE GAS ELECTRICITY EVAPORATION HEAT EXCHANGE PARTIAL OXIDATION/ STEAM REFORMING WATER GAS SHIFT CO + H2O CO2 + H2 CO-REMOVAL CO + ½O2 CO2 EXHAUST (CLEAN) Finally, I will say a few words about or own project. Financed by the NRC, stretching over 5 years, we are to develop and demonstrate one or more hydrogen generating systems. Our approach is to optimize heat transport to or from the catalyst surface, and to experiment with air and steam over new catalytic systems to find a promising design. These activities are based on our research group’s long experience with research on steam reforming and catalytic partial oxidation catalysis and kinetics. The new catalyst may also give further information on kinetics, giving us even better insight to the relevant processes while we go for design Among other things, we will experiment with microstructured catalyst/reactor systems together with partners at Forschunzentrum Karlsruhe, who are in the international forefront of this technology.
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Selective synthesis of CNF/CNT
CNT/CNF as catalyst supports Pt/CNF
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4th year courses Autumn: TKP4155 Reaction kinetics and catalysis (Prof. Magnus Rønning) Definition of catalysis, elementary reactions, chain reactions and catalytic sequences. Microkinetic modeling. Catalyst preparation and characterization. Adsorption, desorption, surface area and porosity. Modern theories for surfaces and surface reactions. Internal and external mass and heat transfer in catalyst particles. The effect of diffusion on reaction kinetics. Multifunctional catalysis. Catalysis by transition metal complexes. Ziegler-Natta and single-site polymerisation catalysts. Spring: TKP4150 Petrochemistry and oil refining (Prof. II Kjell Moljord & Prof. Edd A. Blekkan) Feedstocks, Norwegian oil and gas production, energy from fossil fuels. Oil refining, oil products, refinery design and selected processes, catalytic reforming and isomerization, hydrotreating and hydrocracking, catalytic cracking, treatment of heavy oils, hydrogen balance, environmental concerns, new fuels. Examples of basic, intermediate and end products from petrochemistry. Natural gas and LPG as feedstock, synthesis gas production, preparation and use of hydrogen, methanol synthesis, Fischer-Tropsch, ammonia synthesis. Production of light olefins by steam-cracking, dehydrogenation and other routes, use of light olefins.
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TKP4515 Katalyse og petrokjemi FDE TKP4515 Catalysis and petrochemistry SC
Topics (3.75 stp) in the FDE/SC (7.50 stp): Environmental and energy catalysis Renewable energy, hydrogen technology, photocatalysis, green chemistry, NOx-removal Heterogenous catalysis, advanced course Continues from TKP4155 Reaction kinetics and catalysis, also provides training in interpreting the scientific literature, report writing and presentations Topics from other SC’s can also be chosen HES and experimental work Obligatory part of the SC, 1 week early in the SC
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Projects autumn 2009 Examples:
Preparation and characterization of Fischer-Tropsch catalysts for biomass conversion Conversion of producer gas Partial oxidation of methane New photocatalytic devices based on carbon materials In situ polymerization on aligned carbon nanotube films Characterisation of commercial methanol synthesis catalyst Advanced characterisation of Fischer-Tropsch catalysts Catalyst for DME synthesis Microchannel membrane reactor for small scale hydrogen production Characterisation of heavy oil In total 20 proposals, see the complete list on the ”Innsida” site We prefer and advice that you continue with the MSc thesis on the same subject
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PhD scholarships We have a large PhD-programme (the largest in Norway) and hope that many of you wish to continue with research work! Some recent PhD candidates, their theses and present workplace: Esther Ochoa Fernandez: CO2-acceptors for methane reforming (Statoil Trondheim) Svatopluk Chytil: Mesoporous silica as catalyst support (SINTEF) Hilde Dyrbeck: Propane dehydrogenation (Statoil Trondheim) Ingvar Kvande: Carbon nanofibre as catalyst support (SINTEF) Nina Hammer: Au/CNF as catalyst for CO removal reactions (Statoil Trondheim) Bjørn C. Enger: Hydrogen production by CH4 partial oxidation (Statoil Trondheim) Astrid L. Mejdell: Pd membranes for hydrogen separation (Statoil Trondheim)
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