1. By S. Saeidi Contribution from: S. Smolentsev, S. Malang University of Los Angeles August, 2009

2. Introduction Motivation/Goals Problem Definition Mathematical model Numerical Code Test Results Conclusion and Future Investigation

3. Liquid metal, such as PbLi has so many advantages using as heat transfer fluid Corrosion behavior of ferritic steel exposed to PbLi is not well understood Maintaining acceptable limits for material loss is an important goal in blanket development For ferritic steel/PbLi, corrosion is controlled by convection, diffusion and dissolution at the solid-liquid interface Mass, heat and momentum transfer are coupled The main purpose is to develop a numerical code to access corrosion of ferritic steel in PbLi under either experimental or real blanket conditions

4. There are no commercial codes available for corrosion analysis under fusion blanket conditions Experimental data are available on ferritic steel/PbLi corrosion, but no good interpretation exists We need a code, which would help us to perform some initial corrosion analysis under blanket conditions We want to help experimentalists to understand the data, and to understand the corrosion phenomenon itself Use of code for benchmarking with more sophisticated software, which is planned to be developed in future (HIMAG)

5. Corrosion is a result of dissolution of wall material, which is then transported by the flow Transport mechanism are convection and diffusion Flow is either laminar or turbulent. MHD effects should be included We consider only one component (Fe) diffusing into PbLi We also consider deposition phenomenon, which occurs in the cold part of the loop Heat, mass and momentum transfer are coupled. The mathematical model should include energy equation, flow equations (including MHD effects), and mass transfer equation The boundary condition at the solid-liquid interface assumes saturation concentration at given wall temperature

6. Flow Heat Transfer: Mass Transfer: m=0 – plane geometry m=1 – pipe t, k t, D t =0 – laminar t, k t, D t >0 – turbulent Turbulence closures are used to calculate t, k t, D t MHD effects are included through jxB,  P/  x, t, k t, D t More equationsare used to introduce MHD effects

7. Saturation concentration equation expressed in mole fraction (percentage) Borgstedt, H.U and Rohrig, H.D:1991, Journal of Nuclear Materials 181-197 Mass diffusion coefficient plotted as a function of the wall temperature Saturation concentration C sat of iron atoms in PbLi as function of temperature

8. MODULEDESCRIPTIONSTATUS MAIN Switches between the modulesIncluded INPUT Reads input dataIncluded VELO Calculates velocity profileIncluded TEMP Solves the energy equationIncluded CONC Solves the admixture transport equationIncluded OUTPUT Prepares and organizes data outputIncluded Velocity distribution can be calculated for both laminar and turbulent flow regimes for simple geometries (pipe, rectangular duct, parallel channel) with or without a magnetic field Finite-difference computer code Non-uniform meshes with clustering points near the walls Implicit method for solving equations (Tri-diagonal solver)

9. FlowBC type Nu (calc.)Nu (theory) Plane channel, slug flow Const. T (C) 4.94 Plane channel, parabolic velocity profile Const. T (C) 3.77 Plane channel, parabolic velocity profile Const. Q4.12 Pipe, slug flowConst. T (C) 5.78 Pipe, parabolic velocity profile Const. Q3.66 Pipe, parabolic velocity profile Const. Q4.36 The comparisons have been made for a laminar flow Plot of Nusselt number along x direction in Plane channel with parabolic velocity profile

10. Flow Length: 2m Channel Width: 20cm T wall = 500  C Laminar flow= U=3 cm/s Cwall=0.01 Kg/m 3 Concentration profileTemperature profile

11. Plot of Sherwood number along the X direction: Rate of mass transfer along the X direction: Sh decreases along the x until the flow become fully developed

12. Initials steps towards a mathematical model and numerical code for modeling of corrosion/deposition processes have been performed We will keep working on the code and use it to analyze the effect of the flow regime, MHD, flow geometry, inlet conditions, etc. on corrosion/deposition of ferritic steel in PbLi under either experimental or real blanket conditions We will look for experimental data and run the code trying to reproduce the experimental data In the future, the code will be used for benchmarking with more sophisticated software (HIMAG)