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Liquids and Solids Solids
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Objectives Explain the properties of solids according to the KMT.
Distinguish between amorphous and crystalline solids. Define crystal structure and unit cell.
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Solids Definite shape Definite volume
Intermolecular forces have a large effect; particles are held in fixed positions
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Properties of Solids Definite melting point
Temperature at which the particles of a solid overcome intermolecular forces that hold them in fixed positions Freezing points and melting points have the same values Amorphous do not have a definite melting point.
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Properties of Solids High Density
Particles of solid are packed close together as a result of low K.E. and high intermolecular forces. Incompressibility Particles cannot be pressed into a smaller volume. Low Rate of Diffusion Result of limited particle movement and limited space between particles
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Crystalline Solids Solids in which the particles are arranged in an orderly geometric pattern Arrangement of particles is called a crystal lattice The simplest portion of the lattice is called the unit cell
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Types of Crystalline Solids
Ionic Ionic bonds between anions and cations Covalent Network Covalent bonds between atoms. Examples: Diamond (Cx), quartz (SiO2)x, Metallic Metal cations surrounded by a see of electrons Molecular covalent Molecules held together by intermolecular forces (disperson, dipole-dipole, hydrogen bonding
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Types of Crystalline Solids
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Amorphous Solids Particles are arranged randomly
Sometimes referred to as supercooled liquids Examples include glass, rubber, plastics.
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