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A strategy towards enhanced bio-energy production from cane biomass MSIRI April 2006 LJC Autrey KTKF Kong Win Chang AF Lau
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Land area (Thousand hectares) Roadmap 2015
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PART I Bio-energy potential based on current technologies and cane varieties Bio-energy potential based on current technologies and cane varieties
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Electricity
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Electricity output in Mauritius (GWh) Island Sugar Industry Bag 301 Coal 534 2015 3000
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Electricity output in Mauritius (GWh) Island Sugar Industry 2015 3000 Savannah 2 x 42 MW in 2007 Bag 301 Coal 534 Assumption: 5.5 million tonnes cane 130 kWh/t cane 65% total by coal Bag 400 Coal 740 Bag 465 Coal 860 2007/08 1325 1140 Savannah 3 x 42 MW in 2008
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Savannah power plant under construction 2 x 42 MW in 2007 3 x 42 MW in 2008
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Electricity output in Mauritius (GWh) Island Sugar Industry 2015 3000 F.U.E.L Bag 301 Coal 534 Bag 400 Coal 740 Bag 465 Coal 860 2009 1720 Bag 600 Coal 1120 Assumption: 5.5 million tonnes cane 130 kWh/t cane 65% total by coal
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Electricity output in Mauritius (GWh) Island Sugar Industry 2015 3000 Medine Bag 301 Coal 534 Bag 400 Coal 740 Bag 465 Coal 860 2012 2000 Bag 700 Coal 1300 Assumption: 5.5 million tonnes cane 130 kWh/t cane 65% total by coal Bag 600 Coal 1120
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Factory no. 82 bar boiler Projected electricity export from bagasse (kWh/t cane) The potential that will be exploited between 2007 & 2012 ? Belle Vue Target by 2012 A minimum of 130 kWh/t cane 4 co-generation plants instead of 10
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Projected electricity export from bagasse (GWh) In spite of a reduction of land area for cane cultivation, electricity production will rise to 700 GWh using current technologies and existing cane varieties. 700 2012
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Ethanol
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Ethanol is currently produced with molasses Maximum 33 000 tonnes Blending with gasoline to start soon Alcodis Mauritius
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PART II Strategic Research to Enhance Bio-energy potential N ew T echnologies & N ew C ane V arieties Strategic Research to Enhance Bio-energy potential N ew T echnologies & N ew C ane V arieties
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Strategic Research in Mauritius To enhance bio-energy production Strategic Research in Mauritius To enhance bio-energy production 1. Breeding for more biomass 2. Collecting maximum trash from the fields 3. Ethanol from bagasse 4. Bagasse gasification technologies 1. Breeding for more biomass 2. Collecting maximum trash from the fields 3. Ethanol from bagasse 4. Bagasse gasification technologies
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1. Breeding for more biomass 1. Breeding for more biomass Strategic Research in Mauritius To enhance bio- energy production
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Intensification of interspecific programme with available wild species in germplasm collection for: Evaluation of Interspecific crosses 1980’s 1.Genetic base-broadening 2.Windfall gain for enhancement of fibre 1.Genetic base-broadening 2.Windfall gain for enhancement of fibre
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470 (F1, BC1, BC2) new parent varieties available in collection for high fibre cane 1990’s
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2005 - 2007 Evaluation of 65 promising parent varieties (interspecific derived) in the collection for biomass, fibre and pol
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What cane variety for bio-energy ? Different Scenarii Breeding for more biomass in Mauritius New variety development initiative to meet future challenges 40 S. Spontaneum clones imported from Barbados in 2004 released from quarantine in 2006
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M 1672/90 A new promising variety with enhanced fibre content M 1672/90 A new promising variety with enhanced fibre content
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What cane variety for bio-energy ? Current variety Fibre 10 - 12 % Sugar Bagasse for electricity & ethanol High quality Pol 17 - 22 % More Sugar More bagasse for electricity & ethanol High fibre Fibre 20 - 30 % Less Sugar Much more bagasse for electricity & ethanol Energy cane Fibre > 30 % Small amount of sugar for ethanol/rum Much more bagasse for electricity & ethanol Different Scenarii High fibre Fibre 20 - 30 % Less Sugar Much more bagasse for electricity & ethanol Current variety Fibre 10 – 12 % Sugar Bagasse for electricity & ethanol High quality Pol 17 - 22 % More Sugar More bagasse for electricity & ethanol
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High quality cane Barbados Bx % CP % CF % C WI 9994019.817.918.4 WI 9691221.419.917.5 MauritiusM52/7815.714.310.4 Barbados
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High quality cane tested in Mauritius Promising varieties from Barbados Brix % Juice WI 9990122.422.2 WI 9691125.021.8 Field Barbados Glasshouse Mauritius WI 9690426.021.0 WI 9690226.222.1
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Energy Content (ktoe) All sugar into ethanol Normal High quality High fibre Energy cane Ethanol 216 445 222 55 Million tonnes CO 2 offset 1.5 2.5 2.6 M1672/90 3212231.7 Bagasse 264 371 580 781
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2. Maximize trash recovery from the fields 2. Maximize trash recovery from the fields Strategic Research in Mauritius To enhance bio-energy production Strategic Research in Mauritius To enhance bio-energy production
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Impact of fibre on electricity export kWh/t cane Fibre % Cane Boiler 82 bar 525 o C = 11 kWh/t cane Trash recovery increases fibre content in cane
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Method of trash recovery – The DCCP concept Sugar Cane + Maximum Trash sent to factory DCCP Chopped Trash Clean Cane Factory Bagasse Quality Sugar
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World bank and GEF funded research on DCCP or trash recovery system A commercial system to be installed at Savannah World bank and GEF funded research on DCCP or trash recovery system A commercial system to be installed at Savannah Source: Union St Aubin
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Additional trash (offset coal) + 250 Assuming 400 000 tonnes recovered – Conventional steam cycle 2000 700 2012 2005 4 1300 35 % bag 65 % coal 301 534 835 2015
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Cellulases and hemicellulases produced by micro-organisms to hydrolyse hemicellulose and cellulose Strategic Research in Mauritius To enhance bio-energy production 3. Ethanol from bagasse
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Ethanol and Bioplastic from Bagasse 1. Lignin removal from bagasse Lignin 19.6 Ash 6.3 Hemicellulose 28.4 Cellulose 40.6 Sugar 3.1 2. Convert hemicellulose and cellulose into simple sugars 3 Steps 3. Convert simple sugars into ethanol and bioplastic
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Lignin Amorphous polymer 2 nd most abundant biopolymer in nature Binds hemicellulose/cellulose It gives rigidity to plants Lignin can be used as fuel Can be converted into dispersing agents and additives
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Hemicellulose Low calorific sugar Hydrolysis Furfural Ethanol Xylose Hemicellulose H H O O H H OH HO H H OH H H CH 2 OH
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Most abundant biopolymer in nature Used as pulp/paper and clothing Cellulose is hydrolyzed by acids and enzymes to produce glucose Glucose can be fermented into ethanol Cellulose
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Removal of lignin Two method were used on bagasse:- 1. Sodium hydroxide 2. Potassium hydroxide 1. Sodium hydroxide 2. Potassium hydroxide Preliminary conclusions:- Potassium hydroxide costs three times as much as sodium hydroxide but it has a major advantage: It can be recovered as potassium nitrate by the addition of nitric acid, and thus can be used as fertilizer Preliminary conclusions:- Potassium hydroxide costs three times as much as sodium hydroxide but it has a major advantage: It can be recovered as potassium nitrate by the addition of nitric acid, and thus can be used as fertilizer
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Method 1 – Enzymatic hydrolysis Cellulases and hemicellulases produced by micro-organisms to hydrolyse hemicellulose and cellulose Preliminary results:- At present stage the efficiency is around 10-15 %. Hence, we are currently optimizing the enzymatic hydrolysis process. Hydrolysis of hemicellulose and cellulose into simple sugars
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Method 2 – Acid hydrolysis Preliminary results:- Presence of reducing sugars. Preliminary results:- Presence of reducing sugars. Picture shows newly acquired reactor. Some tests on pre-treated bagasse were carried out at 200 o C. Hydrolysis of hemicellulose and cellulose into simple sugars
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Strategic Research in Mauritius To enhance bio-energy production Strategic Research in Mauritius To enhance bio-energy production 4. Bagasse gasification technologies
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Steam cycle GWh Potential electricity export with bagasse as fuel Comparing conventional steam cycle with BIG-CC Current varieties 700 BIG-CC GWh High quality cane 8952110 High fibre cane 15353390 Energy cane 21604640 M1672/90 7851830 1630 Projected island electricity demand in 2015 3000 GWh
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Bagasse gasification technologies To enhance bio-energy production Bagasse gasification technologies To enhance bio-energy production The MSIRI is seeking collaboration with a strategic partner to re-start bagasse gasification project. The ISSCT is setting up an International Sugarcane Biomass Utilization Consortium (ISBUC). The launching is planned for 11 July 2006 in Durban. The mode of functioning will be on the same line as the International Consortium for Sugarcane Biotechnology (ICSB). Bagasse gasification technologies will probably be one of the key issues that will be addressed.
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Final Target To make bio-refinery concept a reality
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Cane biomass Effluents from bioplastics Biotechnology tools Solar energy Biofertilizers co 2 Value-added molecules Cane and trash Biofertilizers Vinasse Ethanol distillery Ethanol Liquors, etc. Cane juice Molasses Steam & electricity co 2 Sugar factory Sugar exports Cogen plants Bagasse and trash Steam & electricity Sugar Food products co 2 Leaves & trash Solvents Bioplastic factory Steam and electricity co 2 Sugar Bioplastics Effluents The bio-refinery concept
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Back to Earth In Mauritius, currently the revenue from bio- energy is still low compared to sugar Photosource: http://www.nickyee.com/photoshop/earth-atlantic-1600.jpg
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Sugar Electricity Ethanol 17.7% 100% @ US $ 560/tonne 100% 29.0% @ US$ 350/tonne Current revenue from sugar and by-products ASSUMPTIONS 1 tonne sugar = MUR 16,900 1 tonne cane @ 10% IRSC = 100 kg = MUR 1690 Electricity @ MUR 1.75 kWh = MUR 202 Ethanol @ 0.44 USD / litre = MUR 97
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Dancing naked in the mind field Dr Kary Mullis “ There is a very important rule in evolution. Don’t trouble yourself with details that do not matter for survival. Who ever can do something more efficiently, survives.” Page 157
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Thank you for your attention
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