1. Alkenes and Alkynes Nanoplasmonic Research Group Organic Chemistry Chapter 3

2. Unsaturated hydrocarbons: Alkenes & Alkynes Nanoplasmonic Research Group Degree of Unsaturation from Molecular Formula How to name it !! Chemical Reactions

3. Calculating the Degrees of Unsaturation from a Molecular Forumula: Isomers Matter!!! Degrees of Unsaturation ->Number of Rings and/or Multiple Bonds 1 Degrees of Unsaturation ->1 Ring or 1 Double Bond 2 Degrees of Unsaturation ->2 Double Bonds, 2 Rings, 1 Ring + 1 Double Bonds, or 1 Triple Bond

4. Example: C 6 H 10 (fully saturated would be C 6 H 14 ) 14 H – 10 H = 4 hydrogen atoms = 2 H 2 (pairs of hydrogen atoms) = 2 degrees of unsaturation If molecular formular contains – Halogen (F, Cl, Br, I) – Add number of halogens to number of hydrogen atoms -> C 4 H 6 Br 2 is equivalent to C 4 H 8, degrees of unsaturation = 1 –Oxygen – Ignore it -> C 5 H 8 O is equivalent to C 5 H 8, degrees of unsaturation = 2 –Nitrogen – Subtract number of nitrogen atoms from number of hydrogen atoms -> C 5 H 9 N is equivalent to C 5 H 8, degrees of unsaturation = 2

5. Naming Alkenes Straight-chain alkenes 1.Find parent (longest chain containing a double bond) 2.Number the chain 3.Write the full name Cycloalkenes Start the end nearest the double bond If double bonds are equidistant from both ends, start at the end with the nearest branch point Place the number corresponding to the double bond before the parent name Number so that the double bonds is between C1 and C2 and that the 1 st substituent has the lowest number possible

6. Examples (alkenes)

8. Naming Alkynes 1.Follow alkene rules, but use –yne as suffix 2.If more than one triple bond is present, use – diyne, triyne,… 3.If both double and triple bonds are present - Use –enyne as suffix - Number from side with nearest multiple bond (either double or triple) - If a double and triple bond is equidistant, make the double bond the lower number

9. Examples (alkynes)