Virtual sunlight: The LED screen shows the rising sun in Tiananmen Square which is shrouded with heavy smog on January 16, 2014 in Beijing, China. Beijing.

Virtual sunlight: The LED screen shows the rising sun in Tiananmen Square which is shrouded with heavy smog on January 16, 2014 in Beijing, China. Beijing Municipal Government issued a yellow smog alert this morning Read more:

Devastating effects of pollution in China 2012 (13 min)
China air pollution to America 2 min Common Air pollutants and their source (7min) Health Care and Air Pollution Intro to air pollution

This lecture will help you understand:
The Earth’s atmosphere Outdoor pollution and solutions Stratospheric ozone depletion Acidic deposition and consequences Indoor air pollution and solutions

Central Case: Charging toward cleaner air in London
London has had bad air pollution for centuries that has killed thousands Today, smog from traffic is a problem The “congestion-charging” program charges drivers to drive into central London during the week Congestion decreased, fewer accidents occurred and the air became cleaner

The atmosphere Atmosphere = the thin layer of gases that surrounds Earth Absorbs radiation and moderates climate Transports and recycles water and nutrients 78% nitrogen gas, 21% oxygen gas, 1% other gases Its four layers differ in temperature, density and composition Minute concentrations of permanent (remain at stable concentrations) and variable gases (varying concentrations) Human activity is changing the amounts of some gases

The atmosphere’s composition

The first two layers of the atmosphere
Troposphere = bottommost layer Air for breathing, weather Temperature declines with altitude Tropopause = limits mixing between troposphere and the layer above it Stratosphere = km (7-31 mi) above sea level Drier and less dense, with little vertical mixing Colder in its lower regions Contains UV radiation-blocking ozone, km (10-19 mi) above sea level

The two highest levels of the atmosphere
Mesosphere = km (31-56 mi) above sea level Extremely low air pressure Temperatures decrease with altitude Thermosphere = atmosphere’s top layer Extends upward to 500 m (300 mi)

The atmosphere’s four layers

Atmospheric properties
Atmospheric pressure = measures the force per unit area produced by a column of air Decreases with altitude Relative humidity = the ratio of water vapor a given volume of air contains to the amount it could contain at a given temperature Temperature = varies with location and time

Air masses have different atmospheric pressures
High-pressure system = air that moves away from a center of high pressure as it descends Brings fair weather Low-pressure system = air moves toward the low atmospheric pressure at the center of the system and spirals upward Clouds and precipitation

Air masses produce weather
Front = the boundary between air masses that differ in temperature, moisture, and density Warm Front = the boundary where warm moist air replaces colder, drier air Cold Front = the boundary where colder, drier air displaces warmer, moister air

The atmosphere drives weather and climate
Weather = specifies atmospheric conditions over short time periods and within a small geographic areas Climate = describes patterns of atmospheric conditions across large geographic regions over long periods of time Mark Twain said “Climate is what we expect; weather is what we get”

Solar energy heats the atmosphere
The spatial relationship between the Earth and sun determines the amount of solar energy striking the Earth Energy from the sun Heats air Moves air Creates seasons Influences weather and climate Solar radiation is highest near the equator

Solar energy creates seasons
Because the Earth is tilted Each hemisphere tilts toward the sun for half the year Results in a change of seasons Equatorial regions are unaffected by this tilt, so days average 12 hours through the year

Solar energy causes air to circulate
Air near Earth’s surface is warmer and moister than air at higher latitudes Convective circulation = less dense, warmer air rises and creates vertical currents Rising air expands and cools Cool air descends and becomes denser, replacing warm air Influences both weather and climate

The atmosphere Convective currents contribute to climatic patterns and affect moisture distribution Hadley cells = near the equator, surface air warms, rises, and expands Releases moisture and heavy rainfall near the equator Ferrel cells and polar cells = lift air Creates precipitation at 60 degrees latitude north and south Causes air to descend at 30 degrees latitude

Climate patterns and moisture distribution
Global Circulation (1:56) Hadley Cells Corriolus Effect)

Global wind patterns The atmospheric cells interact with Earth’s rotation to produce global wind patterns As Earth rotates, equatorial regions spin faster Coriolis effect = the north-south air currents of the convective cells appear to be deflected from a straight path Results in curving global wind patterns

Wind patterns Doldrums = near the equator Few winds
Trade winds = between the equator and 30 degrees latitude Blow from east to west Westerlies = from 30 to 60 degrees latitude Originate from the west and blow east People used these winds to sail their ships across the ocean

Deserts of the world and 30

Thermal inversion Usually, tropospheric air temperature decreases as altitude increases Warm air rises, causing vertical mixing Thermal inversion = a layer of cool air occurs beneath a layer of warmer air Inversion layer = the band of air in which temperature rises with altitude Denser, cooler air at the bottom of the layer resists mixing Temperature Inversion Lab Video 2:50 Inversion Layer over Bergen 1:53 Good Inversion animation 1min

Outdoor air pollution Most Polluted Cities l Air pollutants = gases and particulate material added to the atmosphere Can affect climate or harm people Air pollution = the release of pollutants Outdoor (ambient) air pollution = pollution outside Has recently decreased due to government policy and improved technologies in developed countries Developing countries and urban areas still have significant problems

Natural sources pollute: dust storms
Dust storms = Hundreds of millions of tons of dust are blown westward across the Atlantic Ocean by trade winds every year From Africa to the Americas Unsustainable farming and grazing, erosion and desertification

Natural sources pollute: volcanoes
Release large quantities of particulate matter, sulfur dioxide & other gases Can remain for months or years Aerosols = reflect sunlight back into space and cool the atmosphere and surface

Natural sources pollute: fires
Pollutes atmosphere with soot and gases Over 60 million ha of forests and grasslands burn per year Severe fires are caused by human interaction Cleared forests, harsh droughts, and climate change (El Niño)

Types of outdoor air pollution
Air pollution can come from mobile or stationary sources Point Sources = specific spots where large quantities of pollutants are discharged (power plants and factories) Nonpoint Sources = more diffuse, consisting of many small sources (automobiles) Primary Pollutants = directly harmful and can react to form harmful substances (soot and carbon dioxide) Secondary Pollutants = form when primary pollutants interact or react with constituents or components of the atmosphere (tropospheric ozone and sulfuric acid)

Differentiate between primary and secondary pollutants.
Primary pollutants are emitted into the troposphere in a form that is directly harmful. Secondary pollutants are harmful substances produced when primary pollutants interact or when they react with the normal constituents of the atmosphere.

Legislation addresses pollution
Congress passed a series of laws starting in 1955 The Clean Air Act of 1970 Sets standards for air quality, limits on emissions Provides funds for pollution-control research Allows citizens to sue parties violating the standards The Clean Air Act of 1990 Strengthens standards for auto emissions, toxic air pollutants, acidic deposition, stratospheric ozone depletion Introduced emissions trading

The EPA sets standards Environmental Protection Agency (EPA) sets nationwide standards for emissions of toxic pollutants States monitor air quality and develop, implement, and enforce regulations within their borders If a state’s plans for implementation are not adequate, the EPA can take over enforcement

History of Federal Atmospheric Pollution Regulation
Air Pollution Control Act of 1955 Money allocated to states to improve air quality Clean Air Act of 1963 Allowed states to set standards (Standards were different for different states.) Air Quality Control Act of 1967 Divided the country into Air Quality Control Regions (AQMD) and defined methods for setting standards. Only regulates stationary sources (not mobile sources)

History of Federal Atmospheric Pollution Regulation
Clean Air Act of 1970 Goals Protect Public health from air pollution Limit the effects of air pollution on the environment Established National Ambient (outdoor) Air Quality Standards (NAAQS) for six criteria pollutants Clean Air Act Revisions 1990 Addressed Acid Rain, VOC’s, CFC’s Clean Air Act Revisions 2009 Addressed Greenhouse gas emissions allowing the government to regulate automobile emissions through CAFÉ standards

Criteria pollutants: carbon monoxide
Criteria pollutants = pollutants judged to pose especially great threats to human health Carbon monoxide (CO) A colorless, odorless gas Produced primarily by incomplete combustion of fuel Binds with hemoglobin in red blood cells and blocks the uptake of Oxygen. Causes drowsiness, brain damage and death. Poses risk to humans and animals, even in small concentrations

Criteria pollutants: sulfur and nitrogen dioxide
Sulfur dioxide (SO2) = colorless gas with a strong odor Emissions from combustion of coal and petroleum in electricity generation and industry Can form acid precipitation (affects pH of lakes, streams and soil, affects soil cation exchange capacity) Nitrogen dioxide (NO2) = highly reactive, foul smelling reddish brown gas Nitrogen oxides (NOx) = nitrogen and oxygen react at high temperatures Vehicle engine and industrial combustion, electrical utilities Contributes to smog and acid precipitation

Criteria pollutants: tropospheric ozone
Tropospheric ozone (O3) = a colorless gas with a strong odor A secondary pollutant Results from interactions of sunlight, heat, nitrogen oxides, and volatile carbons (VOC’s) A major component of smog Poses a health risk as a result of its instability Reacts with animal tissues creating pain in most sensitive tissues like lungs, eyes, nose, etc. Reacts with synthetic carbon compounds like tires, plastics, and latex.

The “Urban Heat Island Effect” and Ozone
Ozone is a bigger problem in cities because the increased amount of cement and asphalt and fewer trees creates a “Heat Island” effect that increases the formation of Ozone.

Criteria pollutants: particulate matter and lead
Particulate matter = solid or liquid particles suspended in the atmosphere Primary pollutants: dust and soot Secondary pollutants: sulfates and nitrates Damages respiratory tissue when inhaled Smallest particles PM 2.5 can enter the blood directly and pass into tissues like the brain. Most is wind-blown dust Some particulates form aerosols that decrease primary productivity by limiting the availability of sunlight for plants Lead = particulate pollutant added to gas and used in industrial metal smelting Bioaccumulates and causes nervous system malfunction Banned in gasoline in developed, but not in developing countries

Take the Six Criteria Pollutant Quiz: http://www. epa

Areas in the U.S. fail air quality standards
“Non-Attainment Areas” More than 100 million people live in counties that violate EPA levels

Agencies monitor pollutants
State and local agencies also monitor, calculate, and report to the EPA the emissions of pollutants Four criteria pollutants: carbon monoxide, sulfur dioxide, particulate matter, and lead All nitrogen oxides Not tropospheric ozone (no emissions to monitor) Volatile organic compounds (VOCs) = carbon-containing chemicals used emitted by vehicle engines and industrial processes Southern California AQMD

Reasons for the decline in U.S. pollution
Cleaner-burning vehicles and catalytic converters decrease carbon monoxide Permit-trading programs and clean coal technologies reduce SO2 emissions Scrubbers = technologies that chemically convert or physically remove pollutants before they leave the smokestacks Phaseout of leaded gasoline Improved technologies and federal policies

Formation of Ozone and PANs (The role of combustion, light and VOCs)
Heat of Combustion Heat of combustion from car engines, furnaces and power plants form NO2 NO2 UV Light NO + O UV Light from sunlight will breakdown the NO2 O + O2 O3 The lone oxygen atom will react with naturally occurring oxygen to form ozone O3+ NO NO2+O2 Normally, the Ozone would react with the NO from reaction 2 and break down into Oxygen VOCs +NO PANs However, the VOCs Remove NO allowing the Ozone to accumulate and also producing toxic PANs

Formation of PANs (Peroxyacytyl nitrate)
Hydrocarbons + O2 + NO2 + light → CH3COOONO2 PANs are both toxic and irritating, as they dissolve more readily in water than ozone. They are lachrymators, causing eye irritation at concentrations of only a few parts per billion. At higher concentrations they cause extensive damage to vegetation. Both PANs and their chlorinated derivates are said to be mutagenic, as they can be a factor causing skin cancer.

Photochemical Smog devolopment

Ozone development

Catalytic Converter Required in automobile emission systems to remove Nitrous Oxides, CO and excess Hydrocarbons from the emissions. Requires Platinum

U.S. air pollution In 2006, the U.S. emitted 137 million tons of the six major pollutants

Air pollution has decreased since 1970
Total emissions of the six monitored pollutants have declined Despite increased population, energy consumption, miles traveled, and gross domestic product

Toxic substances also pollute
Toxic air pollutants = substances known to cause cancer; reproductive defects; or neurological, development, immune system, or respiratory problems Some are produced naturally: hydrogen sulfide Most are produced by humans: smelting, sewage treatment, industry Not monitored as closely as the six criteria pollutants Monitoring is improving

Recent policies have been contentious
President G.W. Bush has pushed proposals that would overturn key aspects of legislation New source reviews = old utility plants have to install the best available technology when upgrading The Bush administration proposed abolishing this requirement and dropped lawsuits against violators Clear Skies Initiative = establishes a market-based can-and-trade program for some pollutants Stopped in the Senate, because it would increase pollution The EPA had skewed its analysis to promote the legislation

Burning fossil fuels produces industrial smog
Smog = unhealthy mixtures of air pollutants over urban areas Industrial (gray air) smog = industries burn coal or oil Occurs in cooler, hilly areas Government regulations in developed countries reduced smog Coal-burning industrializing countries face significant health risks

What is the main cause of industrial smog?
Burning Fossil Fuels

Photochemical (brown air) smog
Produced by a series of reactions Hot, sunny cities surrounded by mountains Light-driven reactions of primary pollutants and normal atmospheric compounds Morning traffic exhaust releases pollutants Irritates eyes, noses, and throats Vehicle inspection programs in the U.S. have decreased smog

Industrial smog Photochemical smog 17.16

Industrial Smog vs. Photochemical Smog
Chemicals and Particulates from point sources (Factories) Burning Fossil Fuels Photochemical Smog Smog from atmospheric reactions with sunlight or UV radiation

Air quality is a rural issue, too
Airborne pesticides from farms Industrial pollutants drifting from cities, factories and powerplants Feedlots, where cattle, hogs, or chickens are raised in dense concentrations Voluminous amounts of methane, hydrogen sulfide, and ammonia People living or working nearby have high rates of respiratory problems

Industrializing nations face increasing pollution
Outdoor pollution is increasing Factories and power plants do not control emissions Citizens burn traditional fuels (wood and charcoal) China has the world’s worst air pollution 80% of Chinese cities have emissions above the safety threshold Asian brown cloud = a 2-mile thick layer of pollution that reduces sunlight, affects climate, decreases productivity, and kills thousands each year

Synthetic chemicals deplete stratospheric ozone
Ozone layer = ozone in the lower stratosphere 12 ppm concentrations effectively block incoming damaging ultraviolet radiation Chlorofluorocarbons (CFCs) = chemicals that attack ozone 1 million metric tons/year were produced Releases chlorine atoms that split ozone

The hole in the ozone Ozone hole = ozone levels over Antarctica had declined by 40-60% Depletion also in the Arctic and globally Causes skin cancer, harms crops and decreases ocean productivity

One CFC molecule can destroy 100,000 molecules of ozone.

The Montreal Protocol addressed ozone depletion
Montreal Protocol (1987) = 180 nations agreed to cut CFC production in half Follow-up agreements deepened cuts, advanced timetables and addresses other ozone-depleting chemicals Today, production and use of ozone-depleting chemicals has decreased 95% The ozone layer is beginning to recover Challenges still face us CFCs will remain in the stratosphere for a long time Nations can ask for exemptions to the ban

The Montreal Protocol is a success
Considered the biggest environmental success story Policymakers included industry in helping solve the problem Implementation of the plan allowed an adaptive management strategy that changed strategies in response to new scientific data, technological advances, and economic figures The Montreal Protocol can serve as a model for international environmental cooperation

Acid deposition is another trans-boundary issue
Acidic deposition = the deposition of acid, or acid-forming pollutants, from the atmosphere onto Earth’s surface Acid rain = precipitation of acid Atmospheric deposition = the wet or dry deposition on land of pollutants Rain with a pH lower than 5.6 is considered Acid Rain

Sources of acid deposition
Originates from burning fossil fuels that release sulfur dioxide and nitrogen oxides These compounds react with water to form sulfuric and nitric acids

Effects of acid deposition
Nutrients are leached from topsoil Soil chemistry is changed Metal ions (aluminum, zinc, etc.) are converted into soluble forms that pollute water Widespread tree mortality Affects surface water and kills fish Damages agricultural crops Erodes stone buildings, corrodes cars, erases writing on tombstones

pH of precipitation in the U.S.
Many regions of acidification are downwind of major sources of pollution

Movement of Pollutants

Acid deposition has not been greatly reduced
New technologies such as scrubbers have helped SO2 emissions are lower But, NOx emissions are higher Acid deposition’s effects are worse than predicted The Clean Air Act cannot restore ecosystems More must be done to control acid deposition

Indoor air pollution The Environmental Protection Agency estimates that indoor air can be two- to five-times more polluted than the air outdoors. And while the EPA is responsible for cracking down on outdoor pollution -- the smog, ozone and other chemicals that spew from tailpipes and smokestacks -- protecting the air indoors is largely the responsibility of homeowners. Read more: Purify Air - Surprising Sources of Indoor Air Pollution - Popular Mechanics

Indoor air pollution (2min) (2min) (5min) Indoor air contains higher concentrations of pollutants than outdoor air 6,000 people die per day from indoor air pollution The average U.S. citizen spends 90% of the time indoors Exposed to synthetic materials that have not been comprehensively tested To reduce heat loss and improve energy efficiency, building ventilation systems were sealed off ventilation and windows put in that did not open, trapping pollutants inside

Indoor air pollution in the developing world
Stems from burning Wood, charcoal, dung, crop wastes Little to no ventilation Fuel burning pollution causes an estimated 1.6 million deaths per year Soot and carbon monoxide Causes pneumonia, bronchitis, allergies, cataracts, asthma, heart disease, cancer and death

Developed World: Tobacco smoke and radon
The most dangerous indoor pollutants in the developed world Secondhand smoke from cigarettes is especially dangerous Containing over 4000 dangerous chemicals Causes eye, nose, and throat irritation Smoking has declined in developed nations Radon causes 20,000 deaths a year in the U.S. A radioactive gas resulting from natural decay of rock; soil; or water, which can seep into buildings Most homes are now radon resistant

Radon risk across the U.S.

What is the cause of indoor air pollution?
Some of the biggest problems come from dust, dander, and mites, as well as toxins given off by furniture and rugs. The two most dangerous indoor pollutants in developed nations are cigarette smoke and radon

Volatile Organic Compounds (VOCs)
The most diverse group of indoor air pollutants Released by everything from plastics and oils to perfumes and paints Most VOCs are released in very small amounts Unclear health implications due to low concentrations Also include pesticides, which are found indoors more often than outdoors due to seepage Formaldehyde, which leaks from pressed wood and insulation, irritates mucous membranes and induces skin allergies VOC paints

Sources of indoor air pollution

Sources of Indoor Air Pollution
Showers with chlorinated water Formaldehyde from carpets, furniture, foam padding, pressed wood Bacteria and molds from air ducts. CO and particulates from fireplaces, wood stoves, candles cigarette smoke Pollen and dander from flowers and pets Toxins and VOCs from cleaners, pesticides VOCs from computers and office equipment Asbestos from insulation and old floor and ceiling tiles Lead from old paint Radon from rocks under the house

Living organisms can pollute indoors
Tiny living organisms can also pollute Includes dust mites and animal dander worsen asthma Fungi, mold, mildew, airborne bacteria cause severe allergies, asthma, and other respiratory ailments Sick building syndrome = a sickness produced by indoor pollution with general and nonspecific symptoms Solved by using low-toxicity building materials and good ventilation

EPA Indicators of a “Sick Building”
When people report relief of symptoms (adverse health effects) when outside the building. When 20% or more of the occupants report some adverse health effect when inside the building. When occupants report any of the following symptoms

When occupants report any of the following symptoms
Chronic respiratory problems/irritation of mucous membranes • Sinus infection • Sore throat • Irritability • Forgetfulness • Asthma • Shortness of breath • Hypersensitivity and Pneumonitis • Humidifier fever • Depression • Nerve disorders • Kidney/Liver damage Ear infections • Reduced lung function • Onset of chest pain • Allergic reactions/responses • Muscle twitching/tingling sensation • Headaches • Rashes/skin irritation • Eye irritation • Impaired vision

Best solutions for indoor air pollution
Clean ventilation ducts Increase natural ventilation (open windows) Purchase products with low VOC’s and synthetic components (Products without formaldehyde) Prohibit smoking in your house or workplace Leave a vent space under your house Keep your pets outside Use non-toxic cleaners and pesticides Use low VOC paints and varnishes

We can reduce indoor air pollution
In developed countries: Stop Smoking Use low-toxicity material (furniture, blankets, paint) Monitor air quality Keep rooms clean (without toxic cleaners) Open windows for ventilation Limit exposure to chemicals (cleaners, candles, air fresheners) In developing countries: Dry wood before burning Cook outside Use less-polluting fuels (natural gas)

Agency Responsible for Regulation of Indoor Air Pollution in the workplace
OSHA

Conclusion Indoor air pollution is a potentially serious health threat
We can significantly minimize risks Outdoor air pollution has been addressed by government legislation and regulation in developed countries Reduction in outdoor air pollution represents some of the greatest strides in environmental protection There is still room for improvement, especially in developing countries

QUESTION: Review The major component of Earth’s atmosphere is …
Nitrogen gas Oxygen gas Argon gas Water vapor Answer: a

QUESTION: Review Ozone in the _________ is a pollutant, but in the ______ is vital for life Stratosphere, troposphere Troposphere, stratosphere Troposphere, tropopause Stratosphere, thermosphere Answer: b

QUESTION: Review _____ is defined as the ratio of water vapor in the atmosphere compared to the amount the atmosphere could contain Atmospheric pressure Ozonification Temperature Relative humidity Answer: d

QUESTION: Review If you were on a sailing ship going from Europe to the United States, you would want to be in the ________ Doldrums Trade winds Westerlies Polar cell Answer: c

QUESTION: Review The Clean Air Act does all of the following, except:
Allows higher levels of emissions of some criteria pollutants Provides funds for pollution control research Allows citizens to sue violators Sets standards for air quality Answer: a

QUESTION: Review Which criteria pollutant is colorless, odorless, and poses a risk to humans, even in small amounts? Sulfur dioxide Nitrogen dioxide Tropospheric ozone Carbon monoxide Answer: d

QUESTION: Review The Montreal Protocol addressed _______
Global warming, and was not successful Criteria pollutants, and was successful Ozone depletion, and was successful Acid deposition, and was successful Answer: c

QUESTION: Interpreting Graphs and Data
What does this graph show about the mesosphere? It contains the most ozone It is a very thin layer Temperature decreases with increasing altitude Temperature increases with increasing altitude Answer: c

QUESTION: Interpreting Graphs and Data
Which conclusion can you draw from this graph? Even though population and consumption increased, emissions have decreased Along with population decreases, emissions have decreased People have increased emissions, but only slightly All factors show major decreases Answer: a

QUESTION: Viewpoints Think of a major city near you. Do you think it should adopt congestion charging (drivers have to pay to drive downtown)? Yes, if mass transit is available Yes, but only charge people who do not live in the downtown area No; it’s my right to drive where ever I want to I don’t care, because I don’t own a car Answer: any

QUESTION: Viewpoints Should the government be able to prevent restaurants from allowing smoking, to protect people from secondhand smoke? Yes; I don’t want to be exposed to this form of pollution Yes, only if the restaurant agrees No, let the restaurant owner decide No; I want to be able to smoke in a restaurant Answer: any

Virtual sunlight: The LED screen shows the rising sun in Tiananmen Square which is shrouded with heavy smog on January 16, 2014 in Beijing, China. Beijing.

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Virtual sunlight: The LED screen shows the rising sun in Tiananmen Square which is shrouded with heavy smog on January 16, 2014 in Beijing, China. Beijing.

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Presentation on theme: "Virtual sunlight: The LED screen shows the rising sun in Tiananmen Square which is shrouded with heavy smog on January 16, 2014 in Beijing, China. Beijing."— Presentation transcript:

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