1. Ions and Ionic Bonding-Part II Compounds and Their Bonds Objectives: Writing Ionic Compounds Naming Ionic Formulas

2. Ionic Compounds Formed by the attraction between cations and anions Electrons transfer from metals to nonmetals

3. Formulas of Ionic Compounds Formulas of ionic compounds are determined from the charges on the ions  new compounds are NEUTRAL atoms ions     – Na  +  F :  Na + : F :  NaF     sodium fluorine sodium fluoride formula Charge balance: 1+ 1- = 0

4. Writing a Formula Write the formula for the ionic compound that will form between Ba 2+ and Cl . Solution: 1. Identify the charge of the ions 2. Write the positive ion and the negative ion until the charges equal zero Ba 2+ Cl  Cl  3. Write the number of ions needed as subscripts in the chemical formulaBaCl 2

5. Learning Check Write the correct formula for the compounds containing the following ions: A. Na +, S 2- 1) NaS 2) Na 2 S3) NaS 2 B. Al 3+, Cl - 1) AlCl 3 2) AlCl 3) Al 3 Cl C. Mg 2+, N 3- 1) MgN 2) Mg 2 N 3 3) Mg 3 N 2

6. Solution A. Na +, S 2- 2) Na 2 S B. Al 3+, Cl - 1) AlCl 3 C. Mg 2+, N 3- 3) Mg 3 N 2 Al 3+ O 2– Al 2 O 3

7. Naming Binary Ionic Compounds Name the metal first (standard element name) Name the nonmetal, using the suffix –ide to replace the last vowel of the nonmetal element name Ex: Chlorine  Chloride Nitrogen  Nitride Examples: NaClsodium chloride ZnI 2 zinc iodide Al 2 O 3 aluminum oxide

8. Learning Check Complete the names of the following binary compounds: Na 3 Nsodium ________________ KBrpotassium________________ Al 2 O 3 aluminum ________________ MgS_________________________

9. Solution Complete the names of the following binary compounds: Na 3 Nsodium nitride KBrpotassium bromide Al 2 O 3 aluminum oxide MgSmagnesium sulfide

11. Transition Metals Many form 2 or more positive ions 1+ 2+ 1+ or 2+ 2+ or 3+ Ag + Cd 2+ Cu +, Cu 2+ Fe 2+, Fe 3+ silver cadmium copper(I) ion iron(II) ion ion ion copper (II) ion iron(III) ion

12. Learning Check A. The formula for the ionic compound of Na + and O 2- is 1) NaO2) Na 2 O3) NaO 2 B. The formula of a compound of aluminum and chlorine is 1) Al 3 Cl2) AlCl 2 3) AlCl 3 C. The formula of Fe 3+ and O 2- is 1) Fe 3 O 2 2) FeO 3 3) Fe 2 O 3

13. Solution A. The formula for the ionic compound of Na + and O 2- is 2) Na 2 O B. The formula of a compound of aluminum and chlorine is 3) AlCl 3 C. The formula of Fe 3+ and O 2- is 3) Fe 2 O 3

14. Names of Variable Ions Use a roman number after the name of a metal that forms two or more ions Transition metals and the metals in groups 4A and 5A FeCl 3 (Fe 3+ ) iron (III) chloride CuCl (Cu + ) copper (I) chloride SnF 4 (Sn 4+ ) tin (IV) fluoride PbCl 2 (Pb 2+ )lead (II) chloride Fe 2 S 3 (Fe 3+ ) iron (III) sulfide

15. Learning Check Complete the names of the following binary compounds with variable metal ions: FeBr 2 iron (_____) bromide Cu 2 Ocopper (_____) oxide SnCl 4 ___(_____ ) ______________ Fe 2 O 3 ________________________ CuS________________________

16. Solution Complete the names of the following binary compounds with variable metal ions: FeBr 2 iron ( II ) bromide Cu 2 Ocopper ( I ) oxide SnCl 4 tin (IV) chloride Fe 2 O 3 iron (III) oxide CuScopper (II) sulfide

17. Learning Check Name the following compounds: A. CaO 1) calcium oxide2) calcium(I) oxide 3) calcium (II) oxide B. SnCl 4 1) tin tetrachloride2) tin(II) chloride 3) tin(IV) chloride C. Co 2 O 3 1) cobalt oxide 2) cobalt (III) oxide 3) cobalt trioxide

18. Solution Name the following compounds: A. CaO1) calcium oxide B. SnCl 4 3) tin(IV) chloride C.Co 2 O 3 2) cobalt (III) oxide