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Published byCameron Wright Modified over 9 years ago
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Ionic Compounds and Ionic Bonds Compounds composed of cations and anions are called ionic compounds. Ionic bonds – the electrostatic force that holds ions together in ionic compounds. Notice how the ions formed have the stable electron configuration of the octet of a noble gas.
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Formula unit – The lowest whole number ratio of ions in an ionic compound The coordination number of an ion is the number of ions of opposite charge that surround the ion in a crystal.
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Properties of Ionic Compounds 1. Usually a solid crystal at room temperature 2.Generally have a high melting point (for example NaCl mp = 800 degrees C) 3. Can conduct an electric current when melted or dissolved in water
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Bonding in Metals Metals are made of closely packed cations, not neutral atoms Valence electrons of metals can be modeled as a Sea of Electrons. Metallic bonds are the attraction of the free floating valence electrons for the cations High electrical conductivity – The large number of mobile electrons explains why metals have electrical conductivity several 100 times greater than a typical nonmetal. Ag is the best conductor.
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More about metallic bonds Good conductor of heat – due to frequent collisions between the mobile electrons of metals Ductile and malleable – the sea of electrons acts like a flexible glue, holding the nuclei together, so metal crystals can be deformed without shattering Luster – most metals have a silvery white metallic color because they reflect light of all wavelengths. Because electrons are not restricted to a particular bond, they can absorb and re-emit light over a wide wavelength range.
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More metal facts No metal dissolves in water, but the only liquid metal (at room T), mercury, dissolves many metals, forming solutions called amalgams. A Ag-Sn-Hg amalgam is used in filling teeth.) Lowest melting point for metals is Hg at - 39 C, and the highest is for tungsten at 3410 C.
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Metals are crystalline Metals are arranged in very compact and orderly patterns Hexagonal close-packed arrangement
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Body-centered cubic Every atom has 8 neighbors Na, K, Fe, Cr, W Face-centered cubic Every atom has 12 neighbors Cu, Ag, Au, Al, Pb Hexagonal close-packed Every atom has 12 Neighbors Mg, Zn, Cd
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Alloys are mixtures of 2 or more elements, at least one of which is a metal.
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