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Published byBrendan Bridges Modified over 9 years ago
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Resources Crude Oil is a finite resource – fuels are obtained from it by Fractional distillation. We use it to get the small molecules that are synthesised (built up) to give us CONSUMER PRODUCTS. Consumer Products – Plastics, cosmetics,agricultural products and dyes etc. Crude Oil gives is fuels and consumer products. We use a lot of aromatic compounds to make consumer products. ( e.g. – aspirin, TCP )
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Esters and Carboxylic Acids Esters can used used to give characteristics smells to substances, they are also very good non polar solvents. Other uses – perfumes, flavourings, nail varnish remover( ethyl ethanoate)and paint thinner. Carboxylic acids – vinegar ( ethanoic acid), benzoic acid is used as a food preservative.
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Halogenalkanes Trichlormethane – chloroform – used as an anaesthetic. However it is toxic and can cause liver damage. Halothane (2 – bromo-2-chloro-1,1,1-triflouroethane) is a modern replacement. CFC’s – Chloroflourocarbons – unreactive, low toxicity. Uses – aerosol propellants, refrigerants, cleaning solvents. Problem – They break up O 3 in the ozone layer – more UV radiation gets to the earth. This can cause – skin cancer, eye cataracts, effect growth of organisms, the global temperature etc.
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Polymers Revision Standard Grade Plastics are long chain molecules made when small monomer units join. The monomers are repeated along the polymer chain. There are 2 types of polymerisations: addition and condensation.
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Addition Polymerisation The monomer must be an unsaturated molecule. The double bond opens up along the monomers to join. MonomerPolymer EthenePoly (ethene) PropenePoly (propene) StyrenePoly (Styrene) Vinyl chloridePoly ( vinyl chloride)
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Example Monomer – Propene Polymer – Poly(propene) CH 3 H CH 3 H CH 3 H CH 3 H I I I I I I I I C = C - C – C – C – C – C – C – I I I I I I I I H H H H H H H H repeating unit
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Condensation Polymerisation When 2 monomers join the elements which make up 1 molecule of water are released. Examples Starch, Proteins, polyesters. Starch is made when glucose monomers join HO – –OH + HO – – OH + HO –- O - O - - O - - O - - + H 2 O + H 2 O
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Polyester Polyesters are formed in condensation reactions. They are made from monomers that have2 functional groups in their molecule i.e. di ols and di acids. Example HO - - OH HOOC– Δ – COOH Alcohol Acid Part of polyester O II HO - - O – C – Δ – COOH + H 2 O
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Uses of Polyesters They can be manufactures as textile fibres – Terylene. The long polyester chains have a linear structure and fibres can be spun together to make strong, flexible fibres. These are used to make clothes. They can also be used to make resins. The unsaturated molecules form cross –links across to other fibres – producing a network. This is called CURING. Polyester resins (thermosetting) can be mixed with glass fibre to produce GRP – glass reinforced plastic. The resin is brushed on to the glass fibre and cured. It can be used in boats, car bodies etc.
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Amines Amines are a homologous series that contain the functional group – amine NH 2 ( amino) They start with the normal prefix and end in amine Example Methyl amine CH 3 NH 2 Ethyl amineCH 3 CH 2 NH 2
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