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Published byAileen Price Modified over 9 years ago
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Copper (Cu) FCC 0.128 nm atomic radii Silver (Ag) FCC 0.144 nm atomic radii Mix 50% Ag + 50% Cu, gives two solid phases ( and ) (saturated - mostly Cu with some Ag) (saturated - mostly Ag with some Cu) Not this! Binary eutectic system (example, silver-copper) The two constituents are not completely soluble in each other
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Eutectic composition liquid Liquid, L + L + L + Eutectic temperature Eutectic composition Eutectic reaction: One liquid phase becomes two distinct solid phases upon cooling L + cooling
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Crystal of one phase forms (via diffusion in the liquid) Local area becomes “depleted” of one constituent. The depleted area near the solidification pushes the local composition into a solid forming range on the phase diagram. This causes the second solid phase to form adjacent to the first phase. Eutectic reaction Liquid, L + L + L + Eutectic Reaction (at eutectic temperature and composition)
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Second solid phase forms Local area becomes Depleted in the second phase constituent Eutectic reaction Liquid, L + L + L +
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The 2 phases grow side-by-side creating a laminated microstructure Eutectic reaction Liquid, L + L + L +
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Eutectic reaction: Characteristic microstructure: laminates of each of the 2 phases Eutectic reaction Liquid, L + L + L +
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