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IIIIII III. Periodic Trends (p. 187-194) Ch. 6 - The Periodic Table
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A. Periodic Law zWhen elements are arranged in order of increasing atomic #, elements with similar properties appear at regular intervals.
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B. Chemical Reactivity zFamilies ySimilar valence e - within a group result in similar chemical properties
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zAtomic Radius ysize of atom © 1998 LOGAL zIonization Energy yEnergy required to remove an e - from a neutral atom © 1998 LOGAL zElectronegativity C. Other Properties
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zAtomic Radius = ½ the distance between two identical bonded atoms 1. Atomic Radius
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zAtomic Radius yIncreases to the LEFT and DOWN 1. Atomic Radius
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zWhy larger going down? yHigher energy levels have larger orbitals yShielding - core e - block the attraction between the nucleus and the valence e - zWhy smaller to the right? yIncreased nuclear charge without additional shielding pulls e - in tighter 1. Atomic Radius
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zFirst Ionization Energy = Energy required to remove one e - from a neutral atom. 2. Ionization Energy K Na Li Ar Ne He
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zFirst Ionization Energy yIncreases UP and to the RIGHT 2. Ionization Energy
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zWhy opposite of atomic radius? yIn small atoms, e - are close to the nucleus where the attraction is stronger zWhy small jumps within each group? yStable e - configurations dont want to lose e - 2. Ionization Energy
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zSuccessive Ionization Energies yMg1st I.E.736 kJ 2nd I.E.1,445 kJ Core e - 3rd I.E.7,730 kJ yLarge jump in I.E. occurs when a CORE e - is removed. 2. Ionization Energy
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yAl1st I.E.577 kJ 2nd I.E.1,815 kJ 3rd I.E.2,740 kJ Core e - 4th I.E.11,600 kJ zSuccessive Ionization Energies yLarge jump in I.E. occurs when a CORE e - is removed. 2. Ionization Energy
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3. Electronegativity zThe measure of the ability of an atom in a chemical compound to attract electrons zGiven a value between 0 and 4, 4 being the highest
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zWhy increase as you move right? yMore valence electrons, need less to fill outer shell zWhy increase as you move up? ySmaller electron cloud, more pull by + nucleus 3. Electronegativity
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zWhich atom has the larger radius? yBe orBa yCa orBr Examples
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zWhich atom has the higher 1st I.E.? yNorBi yBa orNe Examples
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zWhich element has the higher electronegativity? yCl or F yBe or Ca Examples
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