1. 1 st year meeting SPLIT, Croatia 17-18 June 2014 REPORT ON ATLANTIC AREA With IFREMER, RIHMI-WDC, IHPT and IEO contributions

2. 1 st year meeting – SPLIT 17-18 June 2014 2/44 Inventory, progress since one year Plan for next year Aggregated dataset of nutrients – Quality checks – Data coverage – Product SUMMARY

3. 1 st year meeting – SPLIT 17-18 June 2014 3/44 MFSD ATLANTIC AREAS Bay of Biscay Iberian coast Macaronesia

4. WP 1 : Atlantic Sea Data inventory - IEO Mussels Sediments Parameter GroupMatrixNumber of stations antifoulantsSediment 70 antifoulantsBiota 40 chlorophyllWater column134 heavy metalsBiota 40 heavy metalsSediment 59 hydrocarbonsBiota 40 hydrocarbonsSediment 70 nutrients and fertilisersWater column 134 pesticides and biocidesBiota 40 pesticides and biocidesSediment 70 Restricted Access (SDN policy)

5. WP 1 : Atlantic Sea Data inventory – RIHMI-WDC - Atlantic Sea – 5484 russian (f. USSR) cruises, 647600 stations - Data coverage for oceanographic stations of Atlantic Ocean http://portal.esimo.ru/dataview/viewresource?resourceId=RU_RIHMI-WDC_2359

6. WP 1 : Atlantic Sea Data inventory - IHPT Sediment samples Water samples

7. WP 1 : Atlantic Sea Number of CDIs for Atlantic per Partner PartnerNumber of DataSets 2014 IEO/Spanish Oceanographic Institute 11575 IFREMER 8194 All-Russia Research Institute of Hydrometeorological Information - World Data Centre (RIHMI-WDC) 5300 IHPT, Hydrographic Institute 1390

8. WP 1 : Atlantic Sea GroupDatasets Coverage Fertilizers (with silicates)14 Portuguese West Atlantic Coast (10), Moroccan Platform (1), Macaronesia-Madeira Island (2); Macaronesia-Azores Archipelago (1) Chlorophyll1 Macaronesia-Azores Archipelago (1) Heavy Metals(in progress) Data inventory - IHPT Number of CDIs added during the first year: 15 datasets (seawater) Planned for next year: -Parameters in Seawater (2 projects, 75 time series stations), -Parameters in Sediment (6 projects, 379 stations) Group Fertilizers ( # ) Chlorophyll Heavy Metals Synthetic Compounds Hydrocarbons

9. WP 1 : Atlantic Sea Data inventory - IFREMER 2 sources: -Cruises data (SISMER) -Coastal monitoring networks (Quadrige) – 1 nm from shoreline at maximun Public access Few data on radionucleids and pharmaceuticals

10. WP 1 : Atlantic Sea New Data available Parameter GroupMatrix CDI available (data qualified) Water column temperature and salinity Water column 1103 chlorophyllWater column 864 dissolved gasesWater column 987 heavy metalsBiota 292 hydrocarbonsBiota 130 nutrients and fertilisersWater column 864 pesticides and biocidesBiota 213 silicatesWater column 783 Data from Monitoring Networks (Quadrige²) – Coastal data for France Work done during the 1st phase of Emodnet – Number of CDIs created per parameter group

11. WP 1 : Atlantic Sea New Data available Parameter GroupMatrix CDI available (data qualified) Water column temperature and salinity Water column 602 chlorophyllWater column 449 dissolved gasesWater column 530 heavy metalsBiota 168 hydrocarbonsBiota 66 nutrients and fertilisersWater column 438 pesticides and biocidesBiota 111 silicatesWater column 414 Data from Monitoring Networks (Quadrige²) – Coastal data for Atlantic Work done during the 1st phase of Emodnet – Number of CDIs created per parameter group

12. WP 1 : Atlantic Sea

15. Time series examples

16. WP 1 : Atlantic Sea Time series examples

17. WP 1 : Atlantic Sea

19. For next year -Temporal series: focus on sediment, Update for existing CDIs -New cruises collected by SISMER (PELGAS 2004 – 2011) -Finalize CDIs integration and data QC for partners -Products generation

20. 1 st year meeting – SPLIT 17-18 June 2014 20/44 Data received in two separated sets – Data collected by MARIS robot (8 757 CDIs) 8 489 stations of vertical profiles, 268 time series – Additional Spanish data which were not available when the robot run (2 780 CDIs, vertical profiles) DATA INVENTORY (1) Potential duplicates!

21. 1 st year meeting – SPLIT 17-18 June 2014 21/44 DATA INVENTORY (2) EDMO CodeNameCountryNb of CDIs 353IEOSpain5 518 486IFREMERFrance2 358 590IHPTPortugal1 143 612IMRNorway11 681RIHMIRussian Federation2 507 Total11 537

22. 1 st year meeting – SPLIT 17-18 June 2014 22/44 Deletion of empty stations (No measurements on all levels for the parameter) Deletion of empty lines in a station : some levels with no measurements for the parameter Search for duplicates (linked to the 2 distinct datasets) QC using ODV – Search for out of range values with Flag = 1 – Set a QC for all measurements with Flag=0 – Set default values with Flag=0 or Flag=1 to Flag=9 Write a report on QC and send results to data providers QUALITY CHECKS

23. 1 st year meeting – SPLIT 17-18 June 2014 23/44 Nitrate and Nitrite Ammonium Phosphate Silicate NUTRIENTS PARAMETERS

24. 1 st year meeting – SPLIT 17-18 June 2014 24/44 Parameters Nb stations Nb measurements NTRI+NTRA (µmol/l)15397973 NTRI (µmol/l)578135748 NTRA (µmol/l)566343531 NTAW (µmol/kg)78998 NTIW (µmol/kg)78826 Nitrite (µg/l)1461109 Nitrate (µg/l)78225 Total1026890140 NO2 – NO3 DATA, BEFORE QC (1) 10 268 vertical profiles, received as

25. 1 st year meeting – SPLIT 17-18 June 2014 25/44 Output parameter for product = – NOx = Nitrite+Nitrate [µmol/l] Assumptions – When only Nitrate available  assumption that it is Nitrate+Nitrite – When only Nitrite measurements : data not kept Conversions – Conversion from µmol/kg  µmol/l: using ODV conversion Any µmol/kg to Any µmol/l – Conversions from µg/l  µmol/l: NO2+NO3/14.00670 NO2 – NO3 DATA, BEFORE QC (2)

26. 1 st year meeting – SPLIT 17-18 June 2014 26/44 NO2-NO3 DATA, AFTER QC (1) 7 272 vertical profiles

27. 1 st year meeting – SPLIT 17-18 June 2014 27/44 NO2-NO3 BEFORE AND AFTER QC

28. 1 st year meeting – SPLIT 17-18 June 2014 28/44 NO2 – NO3 DATA, AFTER QC (2) 7 272 vertical profiles Flag value NOx (Nitrate+Nitrite) [µmol/l] 0 (No QC)0 1 (Good)46 188 3 (Doubtful)222 4 (Bad)251 5 (Changed)5 6 (below detection limit)924 Total47 590 3 detection limits 0.24 µmol/l 0.5 0.7

29. 1 st year meeting – SPLIT 17-18 June 2014 29/44 Parameters Nb stations Nb measurements AMON (µmol/l) 5 25527 511 AMOW (µmol/kg)77783 Ammonium (µg/l)120 Total5 33328 314 AMMONIUM DATA, BEFORE QC (1) 5 333 vertical profiles, received as

30. 1 st year meeting – SPLIT 17-18 June 2014 30/44 Output parameter for product = – Ammonium [µmol/l] Conversions – Conversion from µmol/kg  µmol/l: using ODV conversion Any µmol/kg to Any µmol/l – Conversion from µg/l  µmol/l: Ammonium/14.00670 assuming it is N µg/l AMMONIUM DATA, BEFORE QC (2)

31. 1 st year meeting – SPLIT 17-18 June 2014 31/44 AMMONIUM DATA, AFTER QC (1) 4 994 vertical profiles

32. 1 st year meeting – SPLIT 17-18 June 2014 32/44 AMMONIUM BEFORE AND AFTER QC

33. 1 st year meeting – SPLIT 17-18 June 2014 33/44 AMMONIUM DATA, AFTER QC (2) 4 994vertical profiles Flag value AMON [µmol/l] 0 (No QC)0 1 (Good)23 119 3 (Doubtful)97 4 (Bad)507 6 (below detection limit)2 223 Total25 946 3 detection limits 0.7 µmol/l 0.96 1.0

34. 1 st year meeting – SPLIT 17-18 June 2014 34/44 Parameters Nb stations Nb measurements PHOS (µmol/l) 6 59440 196 PHOW (µmol/kg)78998 Phosphate (µg/l)250138328 Total9 17379 522 PHOSPHATE DATA, BEFORE QC (1) 9173 vertical profiles, received as

35. 1 st year meeting – SPLIT 17-18 June 2014 35/44 Output parameter for product – Phosphate [µmol/l] Conversions – Conversion from µmol/kg  µmol/l: using ODV conversion Any µmol/kg to Any µmol/l – Conversion from µg/l: Phosphate/30.97376 assuming it is P in µg/l PHOSPHATE DATA, BEFORE QC (2)

36. 1 st year meeting – SPLIT 17-18 June 2014 36/44 PHOSPHATE DATA, AFTER QC (1) 8 832 vertical profiles

37. 1 st year meeting – SPLIT 17-18 June 2014 37/44 PHOSPHATE BEFORE AND AFTER QC

38. 1 st year meeting – SPLIT 17-18 June 2014 38/44 PHOSPHATE DATA, AFTER QC (2) 8 832 vertical profiles Flag value PHOS [µmol/l] 0 (No QC)0 1 (Good)76 170 3 (Doubtful)88 4 (Bad)307 6 (below detection limit)361 Total26 143 3 detection limits 0.03 µmol/l 0.07 0.2

39. 1 st year meeting – SPLIT 17-18 June 2014 39/44 Parameters Nb stations Nb measurements SLCA (µmol/l) 7 19549 950 SLCW (µmol/kg) 78992 Silicate (µg/l) 3383 932 Total7 61154 874 SILICATE DATA, BEFORE QC (1) 7 611 vertical profiles, received as

40. 1 st year meeting – SPLIT 17-18 June 2014 40/44 Output parameter for product – Silicate [µmol/l] Conversions – Conversion from µmol/kg  µmol/l: using ODV conversion Any µmol/kg to Any µmol/l – Conversion from µg/l  µmol/l : Silicate/28.08550 assuming it is Si in µg/l SILICATE DATA, BEFORE QC (2)

41. 1 st year meeting – SPLIT 17-18 June 2014 41/44 SILICATE DATA, AFTER QC (1) 7 071 vertical profiles

42. 1 st year meeting – SPLIT 17-18 June 2014 42/44 SILICATE BEFORE AND AFTER QC

43. 1 st year meeting – SPLIT 17-18 June 2014 43/44 SILICATE DATA, AFTER QC (2) 7 071 vertical profiles Flag value SLCA [µmol/l] 0 (No QC)0 1 (Good)48 251 3 (Doubtful)639 4 (Bad)1 246 6 (below detection limit)47 Total50 183 2 detection limits 0.1 µmol/l 0.3

44. 1 st year meeting – SPLIT 17-18 June 2014 44/44 Data coverage: for Ammonium, Silicate, Nitrate – What is a « reasonable » coverage for a product? – How to make the mask? New topography or masked area? Data with QF=6 (value below detection): how to deel with? – put value to limit – put value to 0 How to deal with estuaries? DIVA PRODUCTS – PROBLEMS FACED

45. WP 1 : Atlantic Sea For next year -Temporal series: focus on sediment, Update for existing CDIs -New cruises collected by SISMER (PELGAS 2004 – 2011) -Finalize CDIs integration and data QC for partners -Products generation