1. 1 Chapter 3 Water and the Fitness of the Environment

2. 2 Importance of water Overview: The Molecule That Supports All of Life Overview: The Molecule That Supports All of Life Water is the biological medium here on Earth Water is the biological medium here on Earth All living organisms require water more than any other substance All living organisms require water more than any other substance

3. 3 Water Facts Three-quarters of the Earth’s surface is submerged in water Three-quarters of the Earth’s surface is submerged in water The abundance of water is the main reason the Earth is habitable The abundance of water is the main reason the Earth is habitable Figure 3.1

4. 4 Water Facts The polarity of water molecules results in hydrogen bonding The polarity of water molecules results in hydrogen bonding The water molecule is a polar molecule The water molecule is a polar molecule

5. 5 Water’s Polarity The polarity of water molecules The polarity of water molecules –Allows them to form hydrogen bonds with each other –Contributes to the various properties water exhibits Hydrogen bonds + + H H + +  – –  – –  – –  – – Figure 3.2

6. 6 Properties of water Six emergent properties of water contribute to Earth’s fitness for life Six emergent properties of water contribute to Earth’s fitness for life 1. Cohesion/Adhesion 2. Surface tension 3. Temperature Moderation 4. High specific heat 5. Evaporative cooling 6. Universal solvent

7. 7 Cohesion Water molecules exhibit cohesion Water molecules exhibit cohesion Cohesion Cohesion –Is the bonding of a high percentage of the molecules to neighboring water molecules –Is due to hydrogen bonding –Like molecules bonding to each other (water attracting other water molecules)

8. 8 Cohesion Cohesion Cohesion –Helps pull water up through the microscopic vessels of plants (capillarity) Water conducting cells 100 µ m Figure 3.3

9. 9 Surface Tension Surface tension Surface tension –Is a measure of how hard it is to break the surface of a liquid –Is related to cohesion Figure 3.4

10. 10 Moderation of Temperature Water moderates air temperature Water moderates air temperature By absorbing heat from air that is warmer and releasing the stored heat to air that is cooler By absorbing heat from air that is warmer and releasing the stored heat to air that is cooler

11. 11 Heat and Temperature Kinetic energy Kinetic energy –Is the energy of motion Heat Heat –Is a measure of the total amount of kinetic energy due to molecular motion Temperature Temperature –Measures the intensity of heat

12. 12 Water’s High Specific Heat The specific heat of a substance The specific heat of a substance –Is the amount of heat that must be absorbed or lost for 1 gram of that substance to change its temperature by 1ºC

13. 13 Specific Heat Water has a high specific heat which allows it to minimize temperature fluctuations to within limits that permit life Water has a high specific heat which allows it to minimize temperature fluctuations to within limits that permit life –Heat is absorbed when hydrogen bonds break –Heat is released when hydrogen bonds form

14. 14 Evaporative Cooling Evaporation Evaporation –Is the transformation of a substance from a liquid to a gas –Requires energy Heat of vaporization Heat of vaporization –Is the quantity of heat a liquid must absorb for 1 gram of it to be converted from a liquid to a gas –100 o C steam has MORE HEAT than 100 o C boiling water (540 calories)

15. 15 Evaporative Cooling Is due to water’s high heat of vaporization Is due to water’s high heat of vaporization Allows water to cool a surface Allows water to cool a surface Sweating cools the body as heat energy from the body changes sweat into a gas Sweating cools the body as heat energy from the body changes sweat into a gas

16. 16 Insulation of Bodies of Water by Floating Ice Solid water, or ice Solid water, or ice –Is less dense than liquid water –Floats in liquid water –Insulates water & organisms below ice layer

17. 17 Insulation of Bodies of Water by Floating Ice The hydrogen bonds in ice The hydrogen bonds in ice –Are more “ordered” than in liquid water, making ice less dense (crystal lattice) Liquid water Hydrogen bonds constantly break and re-form Ice Hydrogen bonds are stable Hydrogen bond Figure 3.5

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19. 19 Insulation of Bodies of Water by Floating Ice Since ice floats in water Since ice floats in water –Life can exist under the frozen surfaces of lakes and polar seas

20. 20 The Solvent of Life Water is a versatile solvent due to its polarity Water is a versatile solvent due to its polarity It can form aqueous solutions It can form aqueous solutions Called the universal solvent because so many substances dissolve in water Called the universal solvent because so many substances dissolve in water

21. 21 The different regions of the polar water molecule can interact with ionic compounds called solutes and dissolve them The different regions of the polar water molecule can interact with ionic compounds called solutes and dissolve them Negative oxygen regions of polar water molecules are attracted to sodium cations (Na + ). + + + + Cl – – – – – Na + Positive hydrogen regions of water molecules cling to chloride anions (Cl – ). + + + + – – – – – – Na + Cl – Figure 3.6

22. 22 Water can also interact with polar molecules such as proteins Water can also interact with polar molecules such as proteins This oxygen is attracted to a slight positive charge on the lysozyme molecule. This oxygen is attracted to a slight negative charge on the lysozyme molecule. (a) Lysozyme molecule in a nonaqueous environment (b) Lysozyme molecule (purple) in an aqueous environment such as tears or saliva (c) Ionic and polar regions on the protein’s Surface attract water molecules. ++ –– Figure 3.7

23. 23 Hydrophilic and Hydrophobic Substances A hydrophobic substance A hydrophobic substance –Does not have an affinity for water –Nonpolar –lipids A hydrophilic substance A hydrophilic substance –Has an affinity for water –Polar or ionic –Carbohydrates, salts

24. 24 Solute Concentration in Aqueous Solutions Since most biochemical reactions occur in water inside cells (aqueous environments) Since most biochemical reactions occur in water inside cells (aqueous environments) –It is important to learn to calculate the concentration of solutes in an aqueous solution

25. 25 Moles and Molarity A mole A mole –Represents an exact number of molecules of a substance in a given mass Molarity Molarity –Is the number of moles of solute per liter of solution

26. 26 Acids and Bases Dissociation of water molecules leads to acidic and basic conditions that affect living organisms Dissociation of water molecules leads to acidic and basic conditions that affect living organisms Organisms must maintain homeostasis in the pH of their internal and external environments Organisms must maintain homeostasis in the pH of their internal and external environments

27. 27 Water can dissociate Into hydronium ions (H+ or H 3 O+) and hydroxide (OH-) ions Water can dissociate Into hydronium ions (H+ or H 3 O+) and hydroxide (OH-) ions Changes in the concentration of these ions Can have a great affect on pH in living organisms Changes in the concentration of these ions Can have a great affect on pH in living organisms H Hydronium ion (H 3 O + ) H Hydroxide ion (OH – ) H H H H H H + – + Figure on p. 53 of water dissociating Effects of Changes in pH

28. 28 Acids and Bases An acid An acid –Is any substance that increases the hydrogen ion concentration of a solution A base A base –Is any substance that reduces the hydrogen ion concentration of a solution (more OH- ions)

29. 29 The pH Scale Scale goes from 0-14 with 7 neutral Scale goes from 0-14 with 7 neutral The pH of a solution Is determined by the relative concentration of hydrogen ions The pH of a solution Is determined by the relative concentration of hydrogen ions Difference of 10X in hydrogen ion concentration between any two pH values Difference of 10X in hydrogen ion concentration between any two pH values Acids have a higher number of H+ ions than a base Acids have a higher number of H+ ions than a base Acids produce H+ ion in solution Acids produce H+ ion in solution Bases produce OH- ions in solution Bases produce OH- ions in solution

30. 30 The pH scale and pH values of various aqueous solutions Increasingly Acidic [H + ] > [OH – ] Increasingly Basic [H + ] < [OH – ] Neutral [H + ] = [OH – ] Oven cleaner 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 pH Scale Battery acid Digestive (stomach) juice, lemon juice Vinegar, beer, wine, cola Tomato juice Black coffee Rainwater Urine Pure water Human blood Seawater Milk of magnesia Household ammonia Household bleach Figure 3.8

31. 31 Buffers The internal pH of most living cells The internal pH of most living cells –Must remain close to pH 7 Buffers Buffers –Are substances that minimize changes in the concentrations of hydrogen and hydroxide ions in a solution –Consist of an acid-base pair that reversibly combines with hydrogen ions –Made by organisms

32. 32 Carbonic Acid Buffering system CO 2 + H 2 0  H 2 CO 3  H + CO 3 - + H + Carbonic Acid bicarbonate Carbonic Acid bicarbonate Reaction can go in the opposite direction AlkalosisAcidosis

33. 33 The Threat of Acid Precipitation Acid precipitation Acid precipitation –Refers to rain, snow, or fog with a pH lower than pH 5.6 –Is caused primarily by the mixing of different pollutants with water in the air

34. 34 Acid precipitation Acid precipitation –Can damage life in Earth’s ecosystems 0101 2323 4545 6767 8989 10 11 12 13 14 More acidic Acid rain Normal rain More basic Figure 3.9

35. Hard water is any water containing an appreciable quantity of dissolved minerals. Soft water is treated water in which the only cation is sodium. The minerals in water give it a characteristic taste. Some natural mineral waters are highly sought for their flavor and the health benefits they may confer. Soft water, on the other hand, may taste salty and may not be suitable for drinking. 35

36. Soap is less effective in hard water because its reacts to form the calcium or magnesium salt of the organic acid of the soap. These salts are insoluble and form grayish soap scum, but no cleansing lather. Detergents, on the other hand, lather in both hard and soft water. Calcium and magnesium salts of the detergent's organic acids form, but these salts are soluble in water. 36

37. The fructose, or fruit sugar, reduces the rate of water absorption so cells don't get hydrated very quickly. 37