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Ch 2 Scientific Measurement

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1 Ch 2 Scientific Measurement
Chemistry is a lot of math!

2 Warm up Name 3 tools used for measurement. What is a unit?
Give an example of a unit. Why are units important.

3 Example: Cookie Monster is Blue
Making Measurements Ch 2.2 Qualitative measurements: Give results in a descriptive and non-numerical form Example: Cookie Monster is Blue Quantitative measurements: Give results in a definite form – usually as numbers and units Example: Cookie Monster ate 1 kg of cookies

4 Qualitative or Quantitative?
The Big Mac is $2.29. The Pop Rocks are blue. The coffee is hot. The slurpee is 0 degrees Celsius.

5 Measurement—a quantity that has both a number and a unit.
For example… I weigh 90! I make 1000 an hour! There are 72 in this class. Numbers with NO units mean NOTHING…and will be marked WRONG on HW/Tests, etc. Measurements are fundamental to the experimental science.

6

7 International System of Units

8 SI Units (Systeme Internationale)
Quantity Unit Symbol tool Length Meter m Ruler, meter stick Mass Gram g Scale/ balance Not the same as weight Temperature Kelvin/ Celsius K / C Thermometer K=C+273 Time Seconds s Stopwatch Volume Liter or cm3 L or cm3 Graduated cylinder 1mL=1cm3 Density Mass/Vol g/mL Scale & cylinder Derived unit Energy Joule J coulometer Can also use calorie Amount Mole Mol

9 SI Units (Systeme Internationale)
Meter (m) for length Use a meterstick to measure Kilogram (kg) for mass (1 kg = 2.2 lbs) Weight is NOT the same thing as mass! Use a scale to measure Kelvin (K) for temperature K = oC + 273 0 K = absolute zero Use a thermometer to measure oC is another option, but not Fahrenheit (in the metric system) Second (s) for time Use a stopwatch to measure Mole for the amount of substance We will talk about mole later Liter (L) or m3 for volume Use a graduated cylinder to measure 1L = 1m3 joule or calorie for energy We don’t discuss this much in this class…

10 Mass vs Weight Mass: amount of matter - Gravity does not affect mass Weight: measure of gravitational pull

11 Derived Units: it is a combination of units
Volume: cm3 amount of space occupied by an object Density: D= m/v Ratio of mass to volume mL=cm3 Speed: meters/ second

12 milli- (1/1000x), centi-(1/100x),
Metric prefixes: The metric system utilizes prefixes based on powers of 10. Prefixes you need to memorize… milli- (1/1000x), centi-(1/100x), kilo-(1000x)

13 100 cm = 1 m Prefixes you need to memorize…
Metric Prefixes Prefixes you need to memorize… milli- (1/1000), centi-(1/100), kilo-(1000x) Adding prefixes, gives us a range of size measurements. Based on a system of 10’s (decimal system) NOTE that the bigger number goes with the smaller unit. 100 cm = 1 m

14 All metric units increase or decrease by a power of 10.

15 Conversion factors: a ratio of equal proportions, expressed as a fraction
Values can often be expressed in more than one form $1 = 4 quarters = 10 dimes = 20 nickels = 100 pennies 1 meter = 100cm = 1000mm = 0.001km equal values can be shown as a ratio equal to 1; such ratios are called conversion factors… conversion factors are useful for solving problems in which given measurements must be expressed in some other unit.

16 Example 1: conversions a. convert 20 meters to millimeters 1. which is smaller? 2. how many of the smaller are in the larger? 3. create a conversion factor 1000 mm in 1m 1000mm/1m 20,000mm

17 Example 2: conversions b. Convert 20 meters to kilometers 0.02 km

18 3. 600 g = __________ kg 4. 8900 mm = __________ m
More examples g = __________ kg mm = __________ m s = ___________ms kg = __________ mg cm3 = __________ m3 m3 = ________ mm3 Answers 3) 0.6kg 4) 8.9m 5) 2300ms 6) 250,000mg 7) m3 8)

19 Date SI Unit Practice Convert each of the following:
kg = __________ g cm = __________ m ml = __________ l 4. 25 mg = __________g cm = __________ mm ml = __________ l g = __________ kg mm = __________ m m = __________ mm kg = __________ mg 1000g 1 kg Example: 3.68kg * = g 3.68kg * 103 Use table 2 on pg35! However you won’t get the table for your quiz

20 What SI unit would you use to measure….
Date: SI Unit Practice What SI unit would you use to measure…. The distance from school to Sears? The height of your desk? The volume of water in a pool? The volume of water in a spoon? The temperature of this room? The length of a football field? The WIDTH of a strand of hair? The mass of an elephant? The mass of an ant?

21 SCIENTIFIC NOTATION: move decimal point the number of times ex: 1*105 indicated by the power of means larger number means smaller number Convert the following out of or into scientific notation 1) 6.5*104 = 2) 6.5*10-4 = 3) = 4) = 65000. .00065 3.5*10-4 3.5*104

22 Derived Units: it is a combination of units
Volume: mL or cm3 amount of space occupied by an object Density: D= m/v Ratio of mass to volume Speed: meters/ second

23 Density add the symbols <, >, or =to compare the blocks < =

24 Density: D= m/v Ex: A rock has a mass of 10 grams and a volume of 5 cm3. Calculate its density. Units: or 10g / 5cm3 = 2 g/cm3

25 D= m/v How can you find density from a graph? Density is the slope of the line of mass vs volume. D= m/v=slope = = y2- - y1 g X2 – x1 mL rise run Ex: 11-3 g 11-3mL = 1 g/mL

26 What mineral is more dense? A, B, or C?
- A: it has greatest slope If you put equal volumes of A and B on a balance, which would have a larger mass? - A

27

28 Density Calculations Water displacement is used to find the volume of unusual shape: measure volume of water Add an object and measure volume again Subtract the volume of object+water from volume of just water 50mL 60ml 60-50=10mL Ex 2. The mass of 10 copper coins is 30 grams. The initial volume of water is 50mL and the volume with the coins if 55mL. Calculate the density of the copper coins.

29 How would temp affect density??
Ex: 3. The density of silver is 10.0 g/cm3. If you have a sample size of grams, what is the volume of the silver? How would temp affect density?? As temperature increases, what happens to density? If density deals with mass and volume… Does temperature affect mass? Or volume?

30 Homework Quiz! Next class Use pg 42 #1,2 And 881 # 1, 2, 7, 9 to study Table on pg 35 HW: ch. 2 section 2 pg 42 answer questions 1-6 Pg 881 #1, 2, 7

31 The density of silver is 10. 0 g/cm3. If you have a sample size of 17
The density of silver is g/cm3. If you have a sample size of grams, what is the volume of the silver? If you have equal volumes of B(blue line) and C (red line). Which one has a larger mass?

32 SCIENTIFIC NOTATION: move decimal point the number of times ex: 1*105 indicated by the power of means larger number means smaller number Convert the following out of or into scientific notation 1) 6.5*104 = 2) 6.5*10-4 = 3) = 4) = 65000. .00065 3.5*10-4 3.5*104

33 Precision: The closeness of a set of measurements to each other
Accuracy: the closeness of measurements to the actual value 2 technicians measure the density of a new substance: A: 2.000, 1.999, and g/mL B: 2.5, 2.9, and 2.7 g/mL The correct value is g/mL Who is more accurate and who is more precise?

34 Value experimental – Value accepted Value accepted
Percent Error: measure of how different your value is form the real value Value experimental – Value accepted Value accepted Percent error = *100% The density of water at 4 oC is known to be 1.00 g/mL. Kayla experimentally found the density of water to be g/mL. What is her percent error? Example:

35 Significant Figures (Sig. Figs) in Measurements…
Significant Figures: all the digits in a measurement that are known with certainty plus one estimated digit

36 How we do this? Significant figures
Ch 2.3 When we make quantitative measurements, we care about how good our data is. How we do this? Significant figures Slide 1 of 6

37 Rules for Significant Figures: All nonzero numbers are significant
Zeros b/t nonzero digits are significant Zeros appearing in front of all nonzero are not significant Zeros at the end of a number and the right of a decimal point are significant Zeros at the end of a number but to the left of a decimal point, if a decimal point is there, are significant. (NOT necessarily significant if no decimal) Examples: 245 G 3 sf 40.7 L 87009 km m 0.09 kg 85.00g 2000 m 2000. m 3 5 3 1 4 6 1 4

38 a) 12,389 = _____ b) 0.452 = _____ c) 10.26 = _____ d) 23.000 = _____
When given a number, you must be able to determine the number of sig.figs. in it. a) 12,389 = _____ All non-zero #’s are significant b) = _____ Zeros before a decimal are not imp unless it is part of a whole number c) = _____ zeros in between #’s are significant d) = _____ Zeros after a decimal are significant IF THERE IS A WHOLE # e) x 107 = _____ All numbers in the coefficient of a # in scientific notation are significant f) 24,000,000 = _____ zeros w/out a decimal are NOT significant Perfect example of why sci.not. is so great…gets rid of insig 0’s g) = _____ zeros after a decimal but with no whole # are NEVER significant. Again, use sci.not.

39 Math with Sig Figs Conversions with Sig Figs: use same number of sig figs in the original measurement - the conversion factor is considered exact and does not count 100cm m 4.608 m * =460.8cm

40 Addition and Subtraction with Sig Figs: answer must have same # of sig figs as the number with the fewest digits to right of the decimal 25.1g g = Multiplication and Division with Sig Figs: answer must use same # sig figs as the # with the fewest sig figs 3.05g / 8.47mL = 27.1g 0.360g 80.0g/ 5mL = 16mL = 20mL 80.0g/ 5.0mL = 16mL

41 SCIENTIFIC NOTATION: move decimal point the number of times ex: 1*105 indicated by the power of means move to the right means move to the left 6.5*104 = 6.5*10-4 = = = 65000. .00065 3.5*10-4 3.5*104

42 Significant Figures A. State the number of significant digits in each measurement.  1)    2804 m    7)   750 m     2)   2.84 km  8)  75 m                              3)   m               4)   m       9)   75,000 m           5)   4.6 x 105 m       10)   m      6)   4.06 x 10-5 m    11)  75,000.0 m        12)  10 cm

43 Significant Figures Practice
A. State the number of significant digits in each measurement.  1)    2804 m  4   8)  75 m     2                         2)   2.84 km  3 3)   m   4            9)   75,000 m           4)   m     4  5)   4.6 x 105 m   2    10)   m    4   6)   4.06 x 10-5 m   3 11)  75,000.0 m  6      12)  10 cm 1 or 2 7)   750 m     2 or 3

44 B. Solve the following problems and report answers with appropriate number of significant digits.
1)      cm cm + 0.68 cm +12.0 cm =  2)     1.6 km m cm =   3)     g g =    4)     m - 6.0 m =   5)     m kg=   6)     1.31 cm x 2.3 cm =   7)     m x 6.201 m =  8)    20.2 cm / 7.41 s =   9)    g / g =

45 B practice 1)      cm cm + 0.68 cm +12.0 cm =  26.3 cm 2)     1.6 km m cm =   1.2 x 103 or 1203 m 3)     g g =    0.5 g 4)     m - 6.0 m =  4.4 m 5)     m kg=   can’t add m and kg 6)     1.31 cm x 2.3 cm =   3.0 cm2 7)     m x 6.201 m =  m2 8)    20.2 cm : 7.41 s =   2.73 cm/s 9)    g : g = g

46 Warm up What tool would you use to measure mass? What unit would you use to measure mass? What tool would you use to measure volume? What unit(s) would you use to measure length?

47 Name the tool and units to measure each:
Length Volume Mass Temperature Density

48 1. Linear Measurements The length, width, or height of something Tool?
ruler, meter stick, etc. Units? Meter (m) Centimeters (cm) Millimeters (mm)

49 Practice:

50 2. Volume The space matter takes up Tool?
Graduated cylinder, beaker, etc. Units? Liter (L) Milliliters (mL) cm3 MUST BE EYELEVEL TO MEASURE CORRECTLY!

51 Practice:

52 3. Mass The quantity of matter Tool? balance, scale, etc. Units? Kilograms (kg) Grams (g) We use digital scales (usually)…so just record what the scale says

53 Mass continued… Scale must read zero before you place anything on it! If you want to measure the mass of something inside a container…you must measure the empty container first. How much mass does the water have? 462.3 g 450.0 g

54 4. Temperature The amount of heat present Tool? thermometer Units? Degrees Celsius (°C)

55 5. Density? The amount of matter in a space Units? g/cm3 or g/mL Tool? scale and ruler or graduated cylinder


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