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Vaporization
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Vaporization Evaporation in an open container. Condensation rate will probably never be as high as evaporation rate.
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Vaporization
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Vaporization Evaporation in a closed container. Condensation rate will eventually equal evaporation rate.
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Vaporization
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What factors affect the rate of evaporation?
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How Temperature Affects Evaporation Rate
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What factors affect the rate of evaporation?
Temperature Surface area Strength of intermolecular attractive forces
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What factors affect equilibrium vapor pressure?
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What factors affect equilibrium vapor pressure?
Temperature Strength of intermolecular attractive forces
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Boiling
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Boiling
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An Exponential Equation for Pressure
P = β exp(-ΔHvap /RT) ln P = ln β + ln exp(-ΔHvap / RT) ln P = ln β - ΔHvap / RT ln P = ln β - (ΔHvap / R) (1 / T) Y = b + mX Plot ln P against 1 / T. Slope = -ΔHvap/R ΔHvap = -R . Slope where R = J / K mol
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The 2-Point Clausius-Clapeyron Equation
ln P = ln β - (ΔHvap / R) (1 / T) ln P2 = ln β - (ΔHvap / R) ( 1 / T2) Ln P1 = ln β - (ΔHvap / R) (1 / T1) ln P2 - ln P1 = (ΔHvap / R) (1 / T / T2) Ln (P2 / P1) = (ΔHvap / R) (1 / T1 - 1 / T2)
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