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Published byAlexia Bradley Modified over 9 years ago
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Aldehydes (p. 33) Organic compounds that have a carbonyl group (C=O) attached to the beginning (1 st Carbon) or end (last Carbon) of a parent carbon chain. General form: OO R-C-H H-C-R Naming: Drop the “e” from the alkane name and add “al”
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Example O C-C-H Ethane Ethanal
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Name: O C O C-C-C-C 2-methyl-1,4-butanedial (you are supposed to keep the “e”)
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Ketones Organic compounds in which the carbonyl group is attached to carbons within the parent carbon chain (not at the beginning or end). General form: O R-C-R’ Naming: Drop the “e” from the alkane name and add “one”. Give the position # for the carbonyl.
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Example: O C-C-C 2-propanone
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Example: C O O C-C-C-C-C-C 5-methyl-2,3-hexanedione
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Carboxylic Acids (p. 34) Carboxyl group: O or O C-OH HO-C Organic compounds that contain a carboxyl functional group. Can only be on the ends.
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Carboxylic Acids (p. 44) O General formula: R-C-OH Naming: o If one carboxyl group Drop the “e” from the alkane name and add “-oic acid”. (No number needed for the carboxyl group)
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Example: O C-C-C-C-C-C-OH hexanoic acid
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Example: C O C-C-C-C-C-C-OH 5-methyl hexanoic acid
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o If more that one carboxyl group. One on each end of the parent chain. -dioic acid.
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Example: O HO-C-C-C-C-OH 1,4-butanedioic acid
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Example: O C-C O HO-C-C-C-C-C-C-OH 2-ethyl-1,6-hexanedioic acid
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Draw: 4-ethyl-5-methyl-4-propyl octanedial C O C C O C-C-C-C-C-C-C-C C-C-C
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Draw: 6-chloro-4,4-dimethyl- 2,3-hexanedione O O C Cl C-C-C-C-C-C C
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Draw: 4-bromo-2-ethyl-4-iodopentanoic acid Br O C-C-C-C-C-OH I C C
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