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Chemistry 111 Periodic Trends
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Atomic Size Atomic size increases from top to bottom within a group and decreases from left to right across a period Group – the number of protons increase, as does the number of energy levels (+ charge draws in – charge but increase in orbitals causes larger atoms) Period – no added levels and an increase in + draws the e- closer to the nucleus
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Ions An atom that has lost or gained e- in order to have a filled outermost orbital The amount of energy required to remove an e- from its orbital is called its ionization energy It decreases from top to bottom within a group and increase from left to right across a period
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Trends in Ionization Energy
Group – the further away an e- is from its nucleus, the easier it is to remove it from its current orbital; larger atoms have smaller ionization energies Period – the number of protons increases in the nucleus but the shielding effect remains constant; added e- are attracted to the increased + charge
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Trends in Ionic Size Positive ions are always smaller than their respective atoms because they are removing e- and causing those that remain to be more attracted to the + charge which draws them into the centre Negative ions are always larger because they have gained e- and now the attraction to the nucleus is not as great
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Electronegativity It is the ability of an atom to attract e- when forming a compound Representative Elements: Group trends - decrease from top to bottom because there is greater distance from the nucleus and less attraction to + charge Period trends – values increase from left to right because of the increased positive charge and space for added e-
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