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Amide & imide used as binding materials for electrical motors, transformers and electric appliances Polyamine amide Lithium-Imide batteries.

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Presentation on theme: "Amide & imide used as binding materials for electrical motors, transformers and electric appliances Polyamine amide Lithium-Imide batteries."— Presentation transcript:

1 Amide & imide used as binding materials for electrical motors, transformers and electric appliances Polyamine amide Lithium-Imide batteries

2 phthalimidesulphanilamide urea structure Solid fine powder white Solid fine powder white Solid white Granules State and color odorlessodor Inflammable Luminous smoky Inflammable Luminous smoky Inflammable Non luminos No smoky Dry heat test meltingSolidificationApperance change Ammonia odorOdor change Violet fumesNo changeFlame color No residueWhite residueresidue

3 Na2CO3NaOHHCLL.PH2O neutral---No change solubleUrea ?-soluble Not done Insolublesulphanilamide acidicWeak effervescent Soluble under heat (cution) insolubleNot done insolublephthalimide Acid base characte r

4 sulphanilamide Acid test: Sulph.+10 %NaOH → soluble + conc. Hcl → NOT ppt. Not true acid Base test: Sulph.+dil HcL → soluble + 30%NaOH → NOT PPT. Not true base Amphoteric

5 phthilimidesulphanilamideurea No changeOn coldSoda lime Ammonia odorOn hot No changeOn cold30% NaOH Ammonia odorOn hot No reactionOn cold & on hot fecl3 No reactionOn cold &on hot H2SO4 Preliminary test

6 General and specific test urea Biuret reaction: In dry test tube put few granules of urea then heat on flame until melt and solidify to give white residue. After that cool test tube + 10% NaOH drop by drop to dissolve it and give clear solution then add+ cupper sulphate → purple color

7 Urea oxalate formation: Saturated solution of urea + 1ml oxalic acid → urea oxalate as white crystalline ppt. (shiny). Urea nitrate formation: Saturated solution of urea + Conc. Nitric acid → urea nitrate as white ppt.

8 sulphanilamide Amphoteric property Acid and base test. Azo dye test: 1-Sulph. + dil Hcl to dissolve it +NaNO2 → Put in ice 2-phenol +10 % NaOH → put in ice After 5 minutes pour 1 on 2 → red orange dye.

9 phthalimide Phthaline test: Phth. + phenol + Conc. H2SO4 heat until fusions after cooling pour it in beaker contain 10 ml of 10% NaOH → unstable pink color. Fluorescence test: Phth. + resercinol +Conc. H2SO4 heat until fusion then cooling and pour it in beaker contain 10 ml 10% NaOH → reddish brown color give green fluorescence

10 IR location Amid stretching band at 1690 cm-1


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