1. Performance evaluation of isoprene in ozone modeling of Houston Mark Estes, Clint Harper, Jim Smith, Weining Zhao, and Dick Karp Texas Commission on Environmental Quality Presentation for the CMAS Conference, October 2008 mestes@tceq.state.tx.us

2. Acknowledgements TCEQ Air Modeling Team: Doug Boyer, Pete Breitenbach, Bright Dornblaser, Barry Exum, Marvin Jones, Chris Kite, Jim MacKay, Jocelyn Mellberg, Ron Thomas, Zarena Post, Steve Davis. TCEQ Monitoring Operations

3. Questions of interest At the isoprene monitors used to evaluate performance, what is the long-term behavior? How does the model behave during similar time periods? How much geographic variation is observed in these patterns, and does the modeled variation match observed variation?

5. Methods: Biogenics modeling Emissions model: GloBEIS v3.1 biogenic emissions model (Yarwood et al., Guenther et al.) at 2km maximum resolution. Land cover data: University of Texas Center for Space Research (UT-CSR) land cover data (Feldman et al., 2007), 30 meter native resolution. Vegetation data: Houston Green Urban Forest Survey (Smith et al., 2005) Met data: interpolated temperature data for local networks, and GOES-derived photosynthetically active solar radiation data (Byun et al., 2005)

6. Methods: Photochemical grid modeling CAMx v4.51, run at 4km and flexi-nested to 2km. MM5 v3.7.3, with ETA PBL scheme, UH GOES- derived sea surface temperatures, UT-CSR land cover data, NOAH LSM, 4km maximum resolution, analysis nudging on outer grids, obs nudging with profiler data in 4km grid, TKE Kv scheme. Carbon Bond 05 chemical mechanism (Luecken et al., 2008). TCEQ emissions inventory, version bcYYMMM.reg8_pscfv2

7. Episodes of interest May 19 – June 3, 2005 June 17 – June 30, 2005 July 26 – August 8, 2005 May 31 – June 15, 2006 August 15 – September 15, 2006 (TexAQS II field study intensive) September 16 – October 11, 2006 (TexAQS II field study intensive) Total number of days of interest: 96

8. Example for Aug 16, 2006: Total isoprene emissions, 1924 tons/day for whole domain; 610 tons/day in Houston nonattainment area.

9. Auto GC locations

11. Suburban/ex-urban monitoring site

12. Rural monitoring site

13. Industrial monitoring site

22. Finding Temporal patterns: Modeled isoprene matches the diurnal and seasonal patterns of the measurements, but doesn’t always match the magnitude. Spatial patterns: Modeled isoprene appears to be correlated with the measured spatial patterns, but doesn’t always match the magnitude.

23. Geographic analyses Isoprene performance varies by site. Is the geographic distribution of trees correct?

24. Are the trees in the right places? Calculate the difference between the elevations estimated by the Shuttle Radar Tomography Mission (Feb 11-22, 2000) and the elevation of the ground surface using the National Elevation Database (USGS). The difference can represent the height of the tree canopy. Calculate the Normalized Difference Vegetation Index (a vegetative greeness index) for a Landsat image of approximately the same age (1999). This tells where the vegetation is located. Identify all areas with both high NDVI and height of 4 to 80 meters. Calculate the number of “tree pixels” within each 4km grid cell. Contrast the locations of these areas to the areas identified by the UT-CSR landcover data as forested. Plot isoprene emissions per grid cell vs. number of tree pixels per grid cell.

25. UT-CSR Land Cover—all categories displayed

26. UT-CSR Land Cover—only forested categories displayed

27. Areas with tree canopy: NDVI between x and y, and canopy height between 4m and 80m

29. Current state of these analyses Photos by Bohne, U. Vermont

30. Future work Further comparisons between modeled isoprene and TexAQS II observations (aircraft data, RHB ship data, Moody Tower data) C. Warneke analysis comparing PTRMS data aboard NOAA P3 aircraft to the biogenic emissions models GloBEIS, MEGAN, and the latest version of BEIS. Hyperspectral satellite data analysis to distinguish tree species? Aerial photography to assist in species identification?