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CHAPTER TWO THE PHOTOVOLTAIC EFFECT 2e A G.I. Module Energie Solaire Copyright, 2006 © Ahmed S. Bouazzi المدرسة الوطنية للمهندسين بتونس
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The Photovoltaic Effect (1) The p-n Junction
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E c E v E f Electrons current Holes current The photocurrent under illumination PHOTOVOLTAIC EFFFECT (2)
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The Photovoltaic Effect (3) The photovoltage under illumination
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I-V Characteristic of a p-n junction J (A/cm 2 ) V (mV) -J-J L Illumination Dark
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Voltage (V) V co J sc Current (A/cm 2 ) (J,V) I-V Characteristic of a PV Generator The slope is 1/R
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Hole density in the n side: Electron density in the p side: Minority Carrier Concentration = 0
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G ( x, ) = ( ) ( ) exp { - ( ) x } ( ): flux of the incident light The Generation Function wavelength of the light ( ):absorption coefficient
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Holes current (n side): Electrons current (p side): Photocurrent
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p n d d+w l x h 0 n= 0 p= 0 Boundary Conditions
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Holes current (n side): Electrons current (p side): Pseudo-neutral Regions Photocurrent Derivation
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J w = q o { exp (- d) - exp [- (d+w)]} = q o exp (- d)[1 - exp (- w)] Depletion Region Photocurrent
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Absorption Coefficient
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n-side Photocurrent
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p-side Photocurrent
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For a given wavelength Quantum Response
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The Effect of the Surface Recombination Velocity
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The Effect of the Junction Depth
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The Solar Spectrum
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The total photocurrent: The Total Solar Current
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I-V Characteristic of the PV Generator
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Maximum Voltage
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Maximum Photocurrent
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Open Circuit Voltage
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The Fill Factor
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The Efficiency
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The Output Power
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The Ideal Equivalent Circuit
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The Real Equivalent Circuit
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The Real Circuit Equation
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The Fill Factor
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The Series Resistance Effect
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The Shunt Resistance Effect
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The Cell Temperature Effect
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