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Unit 4: Chemical Bonds
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Vocabulary Electron configuration Crystal lattice Molecule
Electron dot diagram Covalent bond Polarity Electron transfer Binary compound Valence electron Chemical formula Ionic bond Extrapolate Cation Oxidation Anion Polyatomic ion **Cannot be printed directly from Quizlet
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Purpose: Understand the meaning of a stable electron configuration & represent atoms using electron dot diagrams. Purpose on top of ISN 90. Notes/Practice on ISN 91. (Lewis Structure Handout) Homework on ISN 90: Write your own step-by-step rules for making an e- dot diagram. WKBK 93 Create
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Lewis Structures (Electron Dot Diagrams)
Find your element on the periodic table. Determine the number of valence electrons. This is how many electrons you will draw.
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Lewis Structures Find out which group (column) your element is in.
This will tell you the number of valence electrons your element has. You will only draw the valence electrons.
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Groups - Review Group 8 = 8 electrons Group 1 = 1 electron
Except for He, it has 2 electrons Group 2 = 2 electrons Each column is called a “group” 3, 4, 5, 6, 7 Each element in a group has the same number of electrons in their outer orbital, also known as “shells”. The electrons in the outer shell are called “valence electrons”
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C Lewis Structures Write the element symbol.
Carbon is in the 4th group, so it has 4 valence electrons. Starting at the right, draw 4 electrons, or dots, counter-clockwise around the element symbol. C
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C Lewis Structures Check your work.
Using your periodic table, check that Carbon is in the 4th group. You should have 4 total electrons, or dots, drawn in for Carbon. C
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C Lewis Structures On your worksheet, try these elements on your own:
P Ca Ar Cl Al C
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H Lewis Structures On your worksheet, try these elements on your own:
P Ca Ar Cl Al H
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P Lewis Structures On your worksheet, try these elements on your own:
Ca Ar Cl Al P
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Ca Lewis Structures On your worksheet, try these elements on your own:
P Ca Ar Cl Al Ca
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Ar Lewis Structures On your worksheet, try these elements on your own:
P Ca Ar Cl Al Ar
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Cl Lewis Structures On your worksheet, try these elements on your own:
P Ca Ar Cl Al Cl
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Al Lewis Structures On your worksheet, try these elements on your own:
P Ca Ar Cl Al Al
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Notes/Practice on ISN 93. Ionic or Covalent Bond handout.
Purpose: Understand how atoms obtain a stable electron configuration by transferring or sharing electrons & differentiate molecules based on the type of bonds within. Purpose on top of ISN 92. Notes/Practice on ISN 93. Ionic or Covalent Bond handout. Homework on ISN 92: Write your own rule for determining whether an element grouping will have an ionic bond or a covalent bond. WKBK 123 Determine
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H2O Chemical Formula 1 oxygen atom 2 hydrogen atoms Shows:
1) elements in the compound 2) ratio of their atoms H2O 1 oxygen atom 2 hydrogen atoms
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Strong attractive force between atoms or ions in a molecule or compound.
Formed by: transferring e- (losing or gaining) sharing e-
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Ne Octet Rule most atoms form bonds in order to have 8 valence e-
full outer energy level like the Noble Gases! Ne Stability is the driving force behind bond formation!
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Transferring e- Sharing e-
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Comparison Chart IONIC COVALENT transferred from metal to nonmetal
shared between nonmetals Electrons Melting Point high low Soluble in Water yes usually not yes (solution or liquid) Conduct Electricity no crystal lattice of ions, crystalline solids molecules, odorous liquids & gases Other Properties
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Pop Quiz Show the Lewis structure for the following elements: Mg O Ar
Al What type of bond is formed between the following compound/molecules? NaF SO3 KI FeCl3 H2O
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Purpose: Explore the transfer of electrons & characteristics of ionic bonding & ionic structure.
Purpose on top of ISN 94. Notes/Practice on ISN 95. Homework on ISN 94: WKBK 98 all Write your own rules for remembering the difference between cation and anion.
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Attraction between 2 oppositely charged ions
Ions - charged atoms formed by transferring e- from a metal to a nonmetal
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Cation- positive charge because of lost electron(s)
Anion- negatively charged ion because of gained electron(s)
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ions form a 3-D crystal lattice
NaCl
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Purpose: Understand how electrons are shared by exploring the formation of covalent bonds & the characteristics of covalent bonds & molecules. Covalent Bonding Activity: Write the symbols for each element. Use beans to create the Lewis structures for each. Each type of atom has a different color. Rearrange the electrons (beans) to show the sharing of electrons. Draw circles to show the sharing of electrons. Draw the bond structure using symbols & lines. Use 1 line for each pair of electrons that is shared. Write the chemical formula for each molecule. Use a colored pencil to draw where the bean was when you remove it. Purpose on top of ISN 96 Notes/Practice on ISN 97. Write Activity instructions here also. Homework on ISN 96: Write a short (2-3 sentence) summary of what you learned from the activity. Covalent Bonding video
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Attraction between neutral atoms
formed by sharing e- between two nonmetals Covalent Bonding Animation
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covalent bonds result in discrete molecules
NH3 H2O Cl2
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Beans & Covalent Bonds Activity
These molecules will be done on ISN 80. Make sure you leave plenty of room between each molecule. Hydrogen + Hydrogen Hydrogen + Oxygen Chlorine + Chlorine Oxygen + Oxygen Carbon + Oxygen Carbon + Hydrogen
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Purpose: Explore the nature of covalent bonds by examining the polarity & non-polarity of simple covalent compounds. Purpose on top of ISN 98 Notes/Practice on ISN 99. Draw the pictures of the types of bonds. Homework on ISN 98: WKBK 109 all & top of 110.
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Nonpolar Covalent Bond
e- are shared equally usually identical atoms
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+ - Polar Covalent Bond
e- are shared unequally between 2 different atoms results in partial opposite charges + -
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Nonpolar Polar Ionic View Bonding Animations.
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Purpose: Name simple binary covalent compounds by looking at the chemical formula. Purpose: Name binary covalent compounds & write their formula using prefixes. Purpose on top of ISN 100. Notes/Practice on ISN 101. Homework on ISN 100: WKBK p. 112 all & p. 113 Write
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Naming Binary Compounds
Yes Metal Present? No Yes Type III Use Greek Prefixes Does the metal form more than one cation? No Yes Type II Determine the charge of the cation; use a Roman numeral after the cation name. Type I Use the element name for the cation. Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 98
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A. Molecular Names Write the names of both elements.
Change the final ending to -ide. Add prefixes to indicate subscripts. Only use mono- prefix with oxide.
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Prefixes – Binary Molecular Compounds
Greek Prefixes for Two Nonmetals Number Indicated Prefixes 1 mono- 2 di- 3 tri- 4 tetra- 5 penta- 6 hexa- 7 hepta- 8 octa- 9 nona- 10 deca-
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A. Molecular Names CCl4 N2O carbon tetrachloride SF6
dinitrogen monoxide sulfur hexafluoride
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B. Molecular Formulas Write the more metallic element first.
Add subscripts according to prefixes.
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B. Molecular Formulas phosphorus trichloride dinitrogen pentoxide PCl3
dihydrogen monoxide PCl3 N2O5 H2O
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Binary Molecular Compounds
N2O dinitrogen monoxide N2O dinitrogen trioxide N2O dinitrogen pentoxide ICl iodine monochloride ICl iodine trichloride SO sulfur dioxide SO sulfur trioxide Technical Note: Iodine trichloride is actually a dimer with the formula I2Cl6
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B. Molecular Formulas The Seven Diatomic Elements
Br2 I2 N2 Cl2 H2 O2 F2
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Binary Compounds Containing Two Nonmetals (Type III Compounds)
As2S3 ________________ diarsenic trisulfide ________________ sulfur dioxide P2O5 ____________________ ________________ carbon dioxide N2O5 ____________________ H2O ____________________ SO2 diphosphorus pentoxide CO2 dinitrogen pentoxide dihydrogen monoxide
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Purpose: Name simple binary ionic compounds by looking at the chemical formula. Purpose: Extrapolate the chemical formula of binary ionic compounds from the names by using the oxidation states of the ions. Purpose on top of ISN 102. Notes/Practice on ISN 103. Homework on ISN 102: Worksheet
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Naming Binary Compounds
Yes Metal Present? No Yes Type III Use Greek Prefixes Does the metal form more than one cation? No Yes Type II Determine the charge of the cation; use a Roman numeral after the cation name. Type I Use the element name for the cation. Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 98
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A. Oxidation Number The charge on an ion.
Indicates the # of e- gained/lost to become stable. 1+ 2+ 3+ 4+ 3- 2- 1-
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B. Ionic Names Write the names of both elements, cation first. Change the anion’s ending to -ide.
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B. Ionic Names NaBr CaO sodium bromide BaCl2 Calcium oxide
barium chloride
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C. Ionic Formulas Write each ion. Put the cation first.
Overall charge must equal zero. If charges cancel, just write the symbols. If not, crisscross the charges to find subscripts.
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C. Ionic Formulas potassium chloride magnesium nitride K+ Cl- KCl
copper(II) chloride K+ Cl- KCl Mg2+ N-3 Mg3N2 Cu2+ Cl- CuCl2
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C. Ionic Formulas calcium oxide aluminum chloride Ca2+ O2- CaO
iron(III) oxide Ca2+ O2- CaO Al3+ Cl-1 AlCl3 Fe3+ O2- Fe2O3
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Purpose: Name the compound & write the formula for ionic compounds containing polyatomic ions.
Purpose on top of ISN 104. Notes/Practice on ISN 105. Attach list of common polyatomic ions & WKST 57 Chart on this page also. Homework on ISN 104: WKST 58 WKBK all
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Ionic Names Write the names of both elements, cation first. Change the anion’s ending to -ide. Write the names of polyatomic ions. For ions with variable oxidation #’s, write the ox. # in parentheses using Roman numerals. Overall charge = 0.
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Ionic Names NaBr Na2CO3 sodium bromide FeCl3 sodium carbonate
iron(III) chloride
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Ionic Formulas Write each ion. Put the cation first.
Overall charge must equal zero. If charges cancel, just write the symbols. If not, crisscross the charges to find subscripts. Use parentheses when more than one polyatomic ion is needed. Roman numerals indicate the oxidation #.
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Ionic Formulas potassium chloride magnesium nitrate K+ Cl- KCl
copper(II) chloride K+ Cl- KCl Mg2+ NO3- Mg(NO3)2 Cu2+ Cl- CuCl2
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Ionic Formulas calcium oxide aluminum chlorate Ca2+ O2- CaO
iron(III) oxide Ca2+ O2- CaO Al3+ ClO3- Al(ClO3)3 Fe3+ O2- Fe2O3
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