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Published byCecil Shelton Modified over 9 years ago
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BASED ON LEWIS DOT STRUCTURES 4 TYPES OF BONDING IONIC BONDING COVALENT BONDING HYDROGEN BONDING METALLIC BONDING
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H Electrons in the outer shell He 1 2 Li Be B C N O F Ne 1 2 3 4 5 6 7 8
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All Noble gases have filled outer shells. All Noble gases are HAPPY and stable. Helium has 2e- in outer shell therefore already Happy. Other Noble gases have 8 e-’s which fill their outer shells ( Octet ) Filled outer shells prevents the Noble gases from reacting with other elements. All other atoms try to get outer shells like the Noble Gases have.
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A filled outer shell is called an OCTET and is the HEAVEN condition for ions or atoms All other atoms try to reach the HAPPY condition by doing 1 of 3 options
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Ionic Bonding Gain an e- : H + 1e- H (H -1 ) (2e- in outer shell) Lose an e- : H H + + 1e- (H +1 ) (Zero e-’s in outer shell) Covalent Bonding Share e-’s : (2e- in both outer shells)
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One atom loses an e- and becomes positive(+) One atom gains an e- and becomes negative(-) Opposite charged particles attract, bond & neutralize. Usually a weak bond which can be broken by water. Free ions in water allow for flow of e-’s (electricity). Usually form crystal lattice.
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Alkalies can ONLY LOSE 1e- to become: Li Li + + 1e- If it gains or shares 1e- it would then have 1 or more e-‘s in a shell that wants 8e-‘s. This would not be stable. This is true for the rest of the Alkali Metals.
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The Alkaline Earth elements are most likely to lose 2e’s to reach a filled outer shell. Mg Mg +2 + 2e- They all become a +2 ion. Be +2, Mg +2, Ca +2 and so on. Gaining or sharing will not reach OCTET.
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The Boron Family are most likely to lose 3e’s to reach a filled outer shell. B B +3 + 3e- Therefore they prefer to be a +3 ion. B +3, Al +3, Ga +3 and so on. Gaining or sharing will not reach OCTET
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Covalent bonding is sharing of 2 e-’s between 2 nuclei No CHARGES are involved Based on the Lewis Dot Structure outer shell Strongest bonds Shared e-’s add toward the OCTET completion Electron pair is not always shared equally leading to a POLAR BOND & Molecule
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The Carbon Family can lose the outer 4e - ‘s to become C +4 ions falling to a previously filled outer shell 2 e - ’s. C C +4 + 4e - ’s The Carbon Family can gain 4e - ‘s to become C -4 and fill the outer shell with 8e - s(OCTET). C + 4e - C -4 They can share their outer 4e - ‘s with other atoms wanting to share( COVALENT BONDING) and reach OCTET in the shape of a TETRAHEDRON.
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The Nitrogen Family can gain 3e - ’ s to become N -3 ions. N 2 + 6e - 2N -3 The Nitrogen Family can share 3e - ‘s to reach the OCTET. Two e - ’s are found between N and each H. Diatomic Nitrogen requires a triple bond sharing 6 e - ’s.
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The Oxygen Family can gain 2e - ‘s to become O -2 ions. O 2 + 4e - 2O -2 The Oxygen Family can share 2e - ‘s to reach the Octet. 4e - shared is a Double bond.
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The Halogens could gain 1e - to become a negative ion. F 2 + 2e - 2 F -1 The other possibility is to share 1 non-paired electron with another atom. H + F
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Oxygen attracts e-’s more than Hydrogen. When H and O are bonded, the electrons are closer to the Oxygen than the Hydrogen. This causes a partial + near Hydrogen and a partial – near the Oxygen. This is a polar attraction between water molecule. This polarity causes molecules to attract each other requiring more energy to pull molecules apart. These attractions cause a higher Melting & Boiling Points for chemicals that have polarity & Hydrogen.
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Orderly arrangement of molecules caused by Hydrogen bonding in the solid state of water causes solid to expand and float which is unique.
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Most solid metals arrange themselves so that 1 atom constantly contacts 12 +other atoms. The e-’s become very free in this tight packing and can flow as a river of e-’s down the line. This is the definition of electricity : the flow of loosely held e-’s through a metal. High melting temperatures are usually noted.
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Ionic Bonding Roman Numeral Non-Ionic Bonding
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Always between a Metal and a Non-metal Name the as found on the periodic table Change the name of the non-metal to –ide ending For the formula, use the charges from the Common Ion Chart or Periodic Table families to determine needed subscripts. The + and – ion charges MUST to cancel to “ZERO”. Ba +2 + 2Cl - add up to zero then charges disappear BaCl 2 is called Barium Chloride using subscripts
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Na +1 + Cl -1 NaCl (1:1) Ba +2 + 2NO 3 -1 Ba(NO 3 ) 2 (1:2) Al +3 + 3I -1 AlI 3 (1:3) 2 Al +3 + 3CO 3 -2 Al 2 (CO 3 ) 3 (2:3)
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Some metals can have 2 or more common ions Fe +2, Fe +3, Cu +1, Cu +2, Pb +2, Pb +4 You must indicate which ion is being used by placing a Roman Numeral behind the symbol Elements that must use Roman Numerals are: Fe, Cu, Pb, Ni, Co, Hg, Cr, Sn
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Fe +2 = Fe II Fe +3 = Fe III Fe +2 + 2OH -1 Fe(OH) 2 Iron II Hydroxide Fe +3 + 3OH -1 Fe(OH) 3 Iron III Hydroxide
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Only used if both elements are Non-metals Use prefixes to declare number of atoms used Mono = 1(used only for second element) Di = 2, Tri = 3, Tetra = 4, Penta = 5, Hexa = 6, Septa = 7, Octa = 8, Nona = 9, Deca = 10 The “a” is sometimes dropped CO = Carbon Monoxide, CO 2 = Carbon Dioxide N 2 O 4 = DiNitrogen TetrOxide P2O5 = DiPhosphorus PentOxide
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