1. AP Chemistry Chapter 5 Jeopardy Jennie L. Borders

2. Round 1 – Chapter 5

3. EnergyStoichiometry q = mC  T HHHHDefinitionsCalorimetry 100 200 300 400 500

4. Energy 100 Calculate the  E for a process in which the system releases 57.5kJ of heat while doing 22.5kJ of work on the surroundings. Is the process endothermic or exothermic? -80kJ exothermic

5. Energy 200 Calculate the  E for a process in which the system absorbs 105kJ of heat from its surroundings while doing 29kJ of work on the surroundings. Is the process exothermic or endothermic? 76kJ endothermic

6. Energy 300 If two positive particles are brought closer together, then explain what would happen to the electrostatic potential energy and why. E el = kQ 1 Q 2 If both particles are d positively charged, then Q 1 and Q 2 are positive making the value of E el positive. As distance decreases, the magnitude of E el increases, so it is not a favorable process. d positively charged, then Q 1 and Q 2 are positive making the value of E el positive. As distance decreases, the magnitude of E el increases, so it is not a favorable process.

7. Energy 400 Calculate the kinetic energy in joules of a 45g golf ball moving at 61 m/s. 84J

8. Energy 500 What is the kinetic energy of an 850 lb. motorcycle moving at 66 mph? (1 kg = 2.2047 lb. 1 mi = 1.6093 km) 1.7 x 10 5 J

9. Stoichiometry 100 Calculate the  H for the production of 0.200 mol of AgCl by the following reaction: Ag + (aq) + Cl - (aq)  AgCl (s)  H = -65.5kJ -13.1kJ

10. Stoichiometry 200 For this reaction,  H for the formation of 0.632mol of O 2. 2KClO 3(s)  2KCl (s) + 3O 2(g)  H = -89.4kJ -18.8kJ

11. Stoichiometry 300 Calculate the amount of heat transferred when 2.4g of Mg reacts at constant pressure. 2Mg (s) + O 2(g)  2MgO  H = -1204kJ -59kJ

12. Stoichiometry 400 Calculate the amount of heat transferred when 45.0g of CH 3 OH is decomposed by the following reaction at constant pressure. CH 3 OH (g)  CO 2(g) + 2H 2(g)  H = 90.7kJ 128kJ

13. Stoichiometry 500 Calculate the amount of heat transferred for the formation of 6.32g O 2. CH 3 OH (l) + 3/2O 2(g)  CO 2(g) +2H 2 O (l)  H = -726.5kJ 95.66kJ

14. q = mC  T 100 Two solid objects, A and B, are placed in boiling water and allowed to come to temperature there. Each is then lifted out and placed in separate beakers containing 1000g of water at 10.0 o C. Object A increases the water temperature by 3.50 o C; B increases water temperature by 2.60 o C. Which object has the larger heat capacity and what extra piece of information do you need to figure out which has the higher specific heat capacity? Object A; mass of each object.

15. q = mC  T 200 How many kJ of heat are needed to raise the temperature of 10.00kg of liquid water from 24.6 o C to 46.2 o C? 904kJ

16. q = mC  T 300 The specific heat of iron metal is 0.450 J/gK. How many J of heat are necessary to raise the temperature of a 1.05kg block of iron from 25.0 o C and 88.5 o C? 3.00 x 10 4 J

17. q = mC  T 400 The specific heat of ethylene glycol is 2.42 J/gK. How many J of heat are needed to raise the temperature of 62.0g of ethylene glycol from 13.1 o C to 40.5 o C? 4.11 x 10 3 J

18. q = mC  T 500 What is the molar heat capacity of water? 75.31 J/mol o C

19.  H 100 Calculate the  H for 3H 2(g) + O 3(g)  3H 2 O (g) using the following information: 2H 2(g) + O 2(g)  2H 2 O (g)  H = -483.6 kJ 3O 2(g)  2O 3(g)  H = 284.6 kJ -867.7kJ

20.  H 200 Calculate the  H for C 2 H 4(g) + 6F 2(g)  2CF 4(g) + 4HF (g) using the following information: H 2(g) + F 2(g)  2HF (g)  H = -537kJ C (s) + 2F 2(g)  CF 4(g)  H = -680kJ 2C (s) + 2H 2(g)  C 2 H 4(g)  H = 523kJ -2486.3kJ

21.  H 300 Calculate the  H for N 2 O (g) + NO 2(g)  3NO (g) using the following information: N 2(g) + O 2(g)  2NO (g)  H = 180.7kJ 2NO (g) + O 2(g)  2NO 2(g)  H = -113.1kJ 2N 2 O (g)  2N 2(g) + O 2(g)  H = -163.2kJ 155.65kJ

22.  H 400 Calculate the  H for the following reaction using information from Appendix C. SiCl 4(l) + 2H 2 O (l)  SiO 2(s) + 4HCl (g) -68.34kJ

23.  H 500 When C 10 H 8(s) is combusted it yields CO 2(g), H 2 O (l), and 5154 kJ/mol. What is the standard enthalpy of formation for C 10 H 8. CO 2(g)  H f o = -393.5 kJ/mol H 2 O (l)  H f o = -285.83 kJ/mol 75.68kJ

24. Definitions 100 What is the internal energy of a system? Total kinetic and potential energy

25. Definitions 200 What is a closed system? A system in which heat can be transferred between the system and the surroundings but not mass.

26. Definitions 300 What is a state function? A property that only depends on the initial and final states, not on the path taken.

27. Definitions 400 For a given process at constant pressure,  H is negative. Is the process exothermic or endothermic? exothermic

28. Definitions 500 By what means can the internal energy of a closed system increase? Increase in heat of the system or work done on the system.

29. Calorimetry 100 A 2.200g sample of C 6 H 4 O 2 is burned in a bomb calorimeter whose total heat capacity is 7.854 kJ/ o C. The temperature of the calorimeter increases from 23.44 o C to 30.57 o C. What is the heat of combustion per mole of C 6 H 4 O 2 ? -2740.2 kJ/mol

30. Calorimetry 200 A 1.800g sample of C 6 H 5 OH was burned in a bomb calorimeter whose total heat capacity is 11.66kJ/ o C. The temperature of the calorimeter plus contents increased from 21.36 o C to 26.37 o C. What is the heat of combustion per mole of C 6 H 5 OH? -3074.74kJ

31. Calorimetry 300 A 2.500g sample of glucose is burned in a bomb calorimeter. The heat of combustion of glucose is - 15.57kJ/mol. The temperature of the calorimeter increases from 20.55 o C to 23.25 o C. What is the total heat capacity of the calorimeter? 14.42 kJ/ o C

32. Calorimetry 400 What a 9.55g sample of solid NaOH dissolves in 100.0g of water in a coffee-cup calorimeter, the temperature rises from 23.6 o C to 47.4 o C. Calculate  H in kJ/mol of NaOH for the solution process. -45.61 kJ/mol

33. Calorimetry 500 When a 3.88g sample of solid NH 4 NO 3 dissolves in 60.0g of water in a coffee-cup calorimeter, the temperature drops from 23.0 o C to 18.4 o C. Calculate  H in kJ/mol of NH 4 NO 3 for the solution process. 25.36 kJ/mol