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Published byPoppy French Modified over 9 years ago
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Stereochemistry
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Any chemistry which involves orientation in space
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Symmetry Referring to anything that can be divided on some plane into identical parts
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Symmetry In molecules, planes of symmetry can be determined along any bond axis
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Symmetric Compounds Compounds with at least one plane of symmetry
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Name the Following C C C C-C-C-C-C-C-C C-C
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Asymmetric Compounds Compounds with no plane of symmetry
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Symmetric Compounds The mirror images of symmetric compounds are identical
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Symmetric Compounds All completely symmetric compounds are non-polar
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Asymmetric Compounds The mirror images of asymmetric compounds are not identical. They are optical isomers
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Asymmetric Compounds Asymmetric compounds can be polar if the bonds are polar
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Polarity of Hydrocarbons Hydrocarbons are non-polar
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Optical Isomers Mirror images of asymmetric compounds are optical isomers or stereoisomers
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Stereoisomerism of C A carbon center must be bound to 4 different things to be asymmetric
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Stereoisomerism of C Any carbon center bound to 3 or less things has at least one plane of symmetry
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Stereoisomerism of C Use modeling
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Stereoisomerism of Carbon Chains The constituents on two adjacent carbons spend more time in the staggered position
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Stereoisomerism of Carbon Chains Use modeling to show aligned & staggered positions
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Diffusion Movement down an energy gradient
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Thermochemistry Compounds will eventually move to the lowest possible energy state (the most stable state)
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Thermochemistry of Organic Compounds Stability is sometimes determined by how the compound interferes with its surroundings
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Thermochemistry of Organic Compounds To increase stability, organic compounds tend to curl up
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Thermochemistry of Organic Compounds Organic compounds ring structures are more stable than their corresponding straight chain structures
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Drill: Name:
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Draw an optical isomer of: H 3 C-CH 2 H 3 C-C-CH 2 -CH 2 -CH 3 H
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Draw & Name at least 5 isomers of C 6 H 14
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